831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 06/15/2016 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 831, DURAGLOSS METAL CLEANER & BRIGHTNER Product code : Part# 831 22oz, 832 Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H315 - Causes skin irritation H318 - Causes serious eye damage Precautionary statements (GHS-US) : P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - If on skin: Wash with plenty of water/? P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor/? P321 - Specific treatment (see ... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2016 EN (English US) 2/7 Name Product identifier % Classification (GHS-US) oxalic acid (CAS No) 144-62-7 1 - 3 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 2-(2-butoxyethoxy)ethanol (CAS No) 112-34-5 1 - 2 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. If not breathing give artificial respiration. Get immediate medical advice/attention. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Take off immediately all contaminated clothing and wash it before reuse. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Rinse immediately with plenty of water for 15 minutes. If eye irritation persists: Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry chemical powder. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Water can be used to keep exposed containers cool, to protect;. Wear normal protective equipment (full bunker gear) and possitive-pressure self contained breathing appartus. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Complete protective clothing. Wear respiratory protection. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective goggles. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. 831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2016 EN (English US) 3/7 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Containers may be hazardous when emptied. Since emptied containers retain product residues, all hazard precautions given in the data sheet should be observed. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep away from heat, sparks, and flames. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 831, DURAGLOSS METAL CLEANER & BRIGHTNER ACGIH Not applicable OSHA Not applicable 2-(2-butoxyethoxy)ethanol (112-34-5) ACGIH ACGIH TWA (ppm) 10 ppm ACGIH ACGIH STEL (ppm) 10 ppm OSHA Not applicable oxalic acid (144-62-7) ACGIH ACGIH TWA (mg/m?) 1 mg/m? ACGIH ACGIH STEL (mg/m?) 2 mg/m? OSHA Not applicable 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : protective gloves. Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of inadequate ventilation wear respiratory protection. Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Purple. Color : Purple Odor : Acid Odor threshold : No data available pH : 2 - 3 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No Data Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F 831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2016 EN (English US) 4/7 Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 140 @ 130 F Relative vapor density at 20 ?C : No data available Relative density : 1 H20>1 Relative density of saturated gas/air mixture : 1 Solubility : Soluble in water. Water: Solubility in water of component(s) of the mixture : ? : ? : 10 g/100ml Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2-(2-butoxyethoxy)ethanol (112-34-5) LD50 dermal rabbit 2764 mg/kg body weight (Rabbit; Experimental value; Equivalent or similar to OECD 402) ATE US (dermal) 2764.000 mg/kg body weight oxalic acid (144-62-7) ATE US (oral) 500.000 mg/kg body weight ATE US (dermal) 1100.000 mg/kg body weight Skin corrosion/irritation : Causes skin irritation. pH: 2 - 3 Serious eye damage/irritation : Causes serious eye damage. pH: 2 - 3 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified 831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2016 EN (English US) 5/7 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity 2-(2-butoxyethoxy)ethanol (112-34-5) LC50 fish 1 1300 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 1 4950 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 100 mg/l (96 h; Desmodesmus subspicatus) oxalic acid (144-62-7) LC50 fish 1 34.1 mg/l (96 h; Pimephales promelas) LC50 other aquatic organisms 1 100 - 1000 mg/l (96 h) EC50 Daphnia 1 137 mg/l (48 h; Daphnia magna) LC50 fish 2 160 mg/l (48 h; Leuciscus idus) TLM fish 1 4000 mg/l (24 h; Lepomis macrochirus) Threshold limit other aquatic organisms 1 100 - 1000,96 h Threshold limit algae 1 80 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 790 mg/l (168 h; Scenedesmus quadricauda) 12.2. Persistence and degradability 831, DURAGLOSS METAL CLEANER & BRIGHTNER Persistence and degradability Not established. 2-(2-butoxyethoxy)ethanol (112-34-5) Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air. oxalic acid (144-62-7) Persistence and degradability Readily biodegradable in water. Readily biodegradable in water in anaerobic conditions. Photolysis in water. Biodegradable in the soil. Photolysis in the air. Biochemical oxygen demand (BOD) 0.14 g O?/g substance Chemical oxygen demand (COD) 0.18 g O?/g substance ThOD 0.18 g O?/g substance 12.3. Bioaccumulative potential 831, DURAGLOSS METAL CLEANER & BRIGHTNER Bioaccumulative potential Not established. 2-(2-butoxyethoxy)ethanol (112-34-5) Log Pow 1 (Test data; Equivalent or similar to OECD 107; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). oxalic acid (144-62-7) Log Pow -2.22 - -1.74 (Estimated value) Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil 2-(2-butoxyethoxy)ethanol (112-34-5) Surface tension 0.0069 N/m (20 ?C) 831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2016 EN (English US) 6/7 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 831, DURAGLOSS METAL CLEANER & BRIGHTNER Not listed on the United States TSCA (Toxic Substances Control Act) inventory 2-(2-butoxyethoxy)ethanol (112-34-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory oxalic acid (144-62-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations \ \ 15.3. US State regulations oxalic acid (144-62-7) U.S. - New Jersey - Right to Know Hazardous Substance List 831, DURAGLOSS METAL CLEANER & BRIGHTNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2016 EN (English US) 7/7 SECTION 16: Other information Revision date : 05/28/2015 Other information : None. Full text of H-phrases: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product