851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 05/28/2015 09/11/2017 EN (English US) Page 1 SECTION 1: Identification 1.1. Identification Product form : Mixture Product name : 851, DURAGLOSS ALUMINUM WHEEL CLEANER Product code : Part# 851 22oz, 852 8oz, 853 Gal, 85355 55 Gal 1.2. Recommended use and restrictions on use No additional information available 1.3. Supplier Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 1A H314 Causes severe skin burns and eye damage Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage Precautionary statements (GHS-US) : P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor/? P321 - Specific treatment (see ... on this label) P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/container to ... 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures 851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/11/2017 EN (English US) 2/7 Name Product identifier % GHS-US classification phosphoric acid, conc>=25%, aqueous solutions (CAS No) 7664-38-2 12 - 16 Skin Corr. 1B, H314 2-(2-butoxyethoxy)ethanol (CAS No) 112-34-5 1 - 2 Eye Irrit. 2A, H319 ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (CAS No) 1341-49-7 1 - 2 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. If not breathing give artificial respiration. Get immediate medical advice/attention. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. First-aid measures after skin contact : Take off contaminated clothing. Wash with plenty of soap and water. Rinse skin with water/shower. Get medical advice/attention. Remove/Take off immediately all contaminated clothing. Immediately call a poison center or doctor/physician. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Rinse immediately with plenty of water for 15 minutes. Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries : Causes severe skin burns and eye damage. 4.3. Immediate medical attention and special treatment, if necessary No additional information available SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Carbon dioxide. Dry chemical powder. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Reactivity : Corrosive vapors. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Water can be used to keep exposed containers cool, to protect. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire- fighting water from entering environment. Protection during firefighting : Complete protective clothing. Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective clothing. Protective goggles. Emergency procedures : Stop spill at source, prevent from spreading. If runoff ocurrs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, material to containers for disposal. Close container tightly and dispose of properly. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Protective gloves. Safety glasses. Self-contained breathing apparatus. Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/11/2017 EN (English US) 3/7 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Containers may be hazardous when emptied. Since emptied containers retain product residues, all hazard precautions given in the data sheet should be observed. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact during pregnancy/while nursing. Hygiene measures : Wash ... thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Store in a well-ventilated place. Keep away from heat, sparks, and flames. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 851, DURAGLOSS ALUMINUM WHEEL CLEANER DNEL DNEL ? phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) Not applicable 2-(2-butoxyethoxy)ethanol (112-34-5) ACGIH ACGIH TWA (ppm) 10 ppm ACGIH ACGIH STEL (ppm) 10 ppm ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) ACGIH ACGIH TWA (mg/m?) 2.5 mg/m? 8.2. Appropriate engineering controls No additional information available 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves Eye protection: Chemical goggles or face shield Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask 851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/11/2017 EN (English US) 4/7 Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Clear Liquid Odor : Butyl Odor threshold : No data available pH : 1 - 2 Melting point : No Data Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Non flammable. Vapor pressure : 140 @ 130.0 F Relative vapor density at 20 ?C : No data available Relative density : 1 H20= >1 Solubility : Soluble in water. Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : >= 95 cP Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosion limits : No data available Explosive properties : No data available Oxidizing properties : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Corrosive vapors. 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapors. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/11/2017 EN (English US) 5/7 2-(2-butoxyethoxy)ethanol (112-34-5) LD50 dermal rabbit 2764 mg/kg body weight (Rabbit; Experimental value; Equivalent or similar to OECD 402) ATE US (dermal) 2764 mg/kg body weight ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) ATE US (oral) 100 mg/kg body weight Skin corrosion/irritation : Causes severe skin burns and eye damage. pH: 1 - 2 Serious eye damage/irritation : Not classified pH: 1 - 2 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity ? single exposure : Not classified Specific target organ toxicity ? repeated exposure : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries : Causes severe skin burns and eye damage. SECTION 12: Ecological information 12.1. Toxicity 2-(2-butoxyethoxy)ethanol (112-34-5) LC50 fish 1 1300 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 1 4950 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 100 mg/l (96 h; Desmodesmus subspicatus) ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) LC50 fish 1 > 2.3 mg/l (Pisces) 12.2. Persistence and degradability 851, DURAGLOSS ALUMINUM WHEEL CLEANER Persistence and degradability Not established. phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the components available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable 2-(2-butoxyethoxy)ethanol (112-34-5) Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air. ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) Persistence and degradability Biodegradability in soil: no data available. 12.3. Bioaccumulative potential 851, DURAGLOSS ALUMINUM WHEEL CLEANER Bioaccumulative potential Not established. phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) Bioaccumulative potential Not bioaccumulative. 851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/11/2017 EN (English US) 6/7 2-(2-butoxyethoxy)ethanol (112-34-5) Log Pow 1 (Test data; Equivalent or similar to OECD 107; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) Bioaccumulative potential No bioaccumulation data available. 12.4. Mobility in soil 2-(2-butoxyethoxy)ethanol (112-34-5) Surface tension 0.0069 N/m (20 ?C) 12.5. Other adverse effects Effect on the global warming : No known effects from this product. GWPmix comment : No known effects from this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Disposal methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to ... Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not applicable TDG Not applicable Transport by sea Not applicable Air transport Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations 851, DURAGLOSS ALUMINUM WHEEL CLEANER Not listed on the United States TSCA (Toxic Substances Control Act) inventory 2-(2-butoxyethoxy)ethanol (112-34-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available 851, DURAGLOSS ALUMINUM WHEEL CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/11/2017 EN (English US) 7/7 National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Other information : None. Full text of H-phrases: H301 Toxic if swallowed H314 Causes severe skin burns and eye damage H319 Causes serious eye irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product