860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 09/24/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Product code : 860 32oz, 861 Gal, 865 5Gal, 8630 30Gal, 8655 55Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Corr. 1B H314 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage Precautionary statements (GHS-US) : P260 - Do not breathe vapors P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear eye protection, protective clothing, protective gloves P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor, a POISON CENTER P321 - Specific treatment (see hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation on this label) P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/24/2015 EN (English US) 2/7 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) phosphoric acid, conc>=25%, aqueous solutions (CAS No) 7664-38-2 15 - 20 Skin Corr. 1B, H314 ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (CAS No) 1341-49-7 2 - 3 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 butyl glycolether (CAS No) 111-76-2 1 - 2 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. If not breathing give artificial respiration. Get medical advice/attention. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove clothing while washing. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Foam. Dry chemical powder. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Non combustible. Not flammable. 5.3. Advice for firefighters Firefighting instructions : Water can be used to keep exposed containers cool, to protect;. Wear normal protective equipment (full bunker gear) and possitive-pressure self contained breathing appartus. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective clothing. Protective goggles. Emergency procedures : If runoff ocurrs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, material to containers for disposal. Close container tightly and dispose of properly. Evacuate unnecessary personnel. 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/24/2015 EN (English US) 3/7 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Notify authorities if product enters sewers or public waters. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Transfer contaminated absorbent, soil and othe material to containers for disposal. Close container tightly and dispose of properly. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Containers may be hazardous when emptied. Since emptied containers retain product residues, all hazard precautions given in the data sheet should be observed. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep away from heat, sparks, and flames. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER ACGIH Not applicable OSHA Not applicable butyl glycolether (111-76-2) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 20 ppm OSHA Not applicable phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) ACGIH Not applicable OSHA Not applicable ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) ACGIH ACGIH TWA (mg/m?) 2.5 mg/m? OSHA Not applicable 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/24/2015 EN (English US) 4/7 Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Liquid. Color : Clear Liquid Odor : Butyl Odor threshold : No data available pH : 1 - 2 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No Data Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 140 @ 130.0 F Relative vapor density at 20 ?C : No data available Relative density : 1 H20= >1 Solubility : Soluble in water. Water: Solubility in water of component(s) of the mixture : ? : ? : Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide. fume. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/24/2015 EN (English US) 5/7 butyl glycolether (111-76-2) LD50 oral rat 1746 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rat > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LC50 inhalation rat (mg/l) 2.2 mg/l/4h (Rat; Experimental value) LC50 inhalation rat (ppm) 450 ppm/4h (Rat; Experimental value) ATE US (oral) 1746.000 mg/kg body weight ATE US (dermal) 1100.000 mg/kg body weight ATE US (gases) 450.000 ppmV/4h ATE US (vapors) 2.200 mg/l/4h ATE US (dust, mist) 2.200 mg/l/4h ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) ATE US (oral) 100.000 mg/kg body weight Skin corrosion/irritation : Causes severe skin burns and eye damage. pH: 1 - 2 Serious eye damage/irritation : Not classified pH: 1 - 2 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified butyl glycolether (111-76-2) IARC group 3 - Not classifiable Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity butyl glycolether (111-76-2) LC50 fish 1 1474 ppm (96 h; Oncorhynchus mykiss) EC50 Daphnia 1 1550 mg/l (48 h; Daphnia magna) Threshold limit algae 1 911 mg/l (72 h; Pseudokirchneriella subcapitata) Threshold limit algae 2 88 mg/l (72 h; Pseudokirchneriella subcapitata) ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) LC50 fish 1 > 2.3 mg/l (Pisces) 12.2. Persistence and degradability 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Persistence and degradability Not established. butyl glycolether (111-76-2) Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air. phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the components available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/24/2015 EN (English US) 6/7 phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) ThOD Not applicable BOD (% of ThOD) Not applicable ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) Persistence and degradability Biodegradability in soil: no data available. 12.3. Bioaccumulative potential 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Bioaccumulative potential Not established. butyl glycolether (111-76-2) Log Pow 0.81 (Test data; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). phosphoric acid, conc>=25%, aqueous solutions (7664-38-2) Bioaccumulative potential Not bioaccumulative. ammonium hydrogen difluoride, 0.1%<=conc<1%, aqueous solutions (1341-49-7) Bioaccumulative potential No bioaccumulation data available. 12.4. Mobility in soil butyl glycolether (111-76-2) Surface tension 0.065 N/m (20 ?C; 003) 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Not listed on the United States TSCA (Toxic Substances Control Act) inventory butyl glycolether (111-76-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory 860, DURAGLOSS HD ALUMINUM CLEANER & BRIGHTENER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/24/2015 EN (English US) 7/7 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations \ \ \ 15.3. US State regulations butyl glycolether (111-76-2) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 05/28/2015 Other information : None. Full text of H-phrases: ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 4 Flammable liquids Category 4 ------ Skin Corr. 1B Skin corrosion/irritation Category 1B ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ H227 Combustible liquid ------ H301 Toxic if swallowed ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product