882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 09/29/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 882, DURAGLOSS HD LIQUID METAL POLISH Product code : Part #882 16oz, 883 Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 4 H227 Skin Irrit. 2 H315 Eye Dam. 1 H318 STOT RE 1 H372 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H227 - Combustible liquid H315 - Causes skin irritation H318 - Causes serious eye damage H372 - Causes damage to organs through prolonged or repeated exposure Precautionary statements (GHS-US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P260 - Do not breathe fume, gas, spray, vapors P264 - Wash hands, forearms and face, clothing thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear eye protection, face shield, protective clothing, protective gloves P302+P352 - If on skin: Wash with plenty of eye protection, face protection, protective clothing, protective gloves P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor, a POISON CENTER P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P370+P378 - In case of fire: Use extinguishing powder, foam, carbon dioxide (CO2) to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents/container to an approved waste disposal plant, an authorized waste collection point 882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/29/2015 EN (English US) 2/7 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) solvent naphtha(petroleum), medium aliph. (CAS No) 64742-88-7 9 - 10 STOT RE 1, H372 Asp. Tox. 1, H304 hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (CAS No) 64742-47-8 8 - 9 Flam. Liq. 4, H227 Asp. Tox. 1, H304 ammonium hydroxide, 5%<=conc<10%, aqueous solution (CAS No) 1336-21-6 1 - 3 Skin Corr. 1B, H314 Aquatic Acute 1, H400 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/29/2015 EN (English US) 3/7 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Hygiene measures : Wash ... thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/? equipment. Storage conditions : Store in a well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 882, DURAGLOSS HD LIQUID METAL POLISH ACGIH Not applicable OSHA Not applicable ammonium hydroxide, 5%<=conc<10%, aqueous solution (1336-21-6) ACGIH ACGIH TWA (ppm) 25 ppm ACGIH ACGIH STEL (ppm) 25 ppm OSHA Not applicable solvent naphtha(petroleum), medium aliph. (64742-88-7) ACGIH Not applicable OSHA Not applicable hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. 882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/29/2015 EN (English US) 4/7 Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Creamy white Odor : Sweet Odor threshold : No data available pH : 10 - 11 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No Data Freezing point : No data available Boiling point : 370 - 550 ?F @ 760 mmHg Flash point : 108 ?F Auto-ignition temperature : 420 ?F Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 1 mm Hg Relative vapor density at 20 ?C : No data available Relative density : 1 @ 68.0 F Solubility : Water: < 0.01 Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified solvent naphtha(petroleum), medium aliph. (64742-88-7) LD50 oral rat > 5000 mg/kg body weight (Rat; Equivalent or similar to OECD 420; Experimental value) LD50 dermal rabbit > 2000 mg/kg body weight (Rabbit; Experimental value; Equivalent or similar to OECD 402) 882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/29/2015 EN (English US) 5/7 hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) LD50 dermal rabbit > 5000 mg/kg body weight (Rabbit; Literature) Skin corrosion/irritation : Causes skin irritation. pH: 10 - 11 Serious eye damage/irritation : Causes serious eye damage. pH: 10 - 11 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Causes damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. SECTION 12: Ecological information 12.1. Toxicity solvent naphtha(petroleum), medium aliph. (64742-88-7) LC50 fish 1 2 - 5 mg/l (LL50; OECD 203: Fish, Acute Toxicity Test; 96 h; Oncorhynchus mykiss; Semi- static system; Fresh water; Experimental value) EC50 Daphnia 1 1.4 mg/l (EL50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) Threshold limit algae 1 1 - 3,EL50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella subcapitata; Static system; Fresh water; Experimental value hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) LC50 fish 1 > 100 mg/l (Pisces) EC50 Daphnia 1 > 100 mg/l (Invertebrata) Threshold limit algae 1 > 100 mg/l (Algae) 12.2. Persistence and degradability 882, DURAGLOSS HD LIQUID METAL POLISH Persistence and degradability Not established. ammonium hydroxide, 5%<=conc<10%, aqueous solution (1336-21-6) Persistence and degradability Readily biodegradable in water. Ozonation in water. Biodegradable in the soil. No (test)data on mobility of the components available. Ozonation in the air. solvent naphtha(petroleum), medium aliph. (64742-88-7) Persistence and degradability Readily biodegradable in water. Adsorbs into the soil. hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) Persistence and degradability Readily biodegradable in water. Adsorbs into the soil. 12.3. Bioaccumulative potential 882, DURAGLOSS HD LIQUID METAL POLISH Bioaccumulative potential Not established. ammonium hydroxide, 5%<=conc<10%, aqueous solution (1336-21-6) Log Pow -1.3 882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/29/2015 EN (English US) 6/7 ammonium hydroxide, 5%<=conc<10%, aqueous solution (1336-21-6) Bioaccumulative potential Bioaccumulation: not applicable. solvent naphtha(petroleum), medium aliph. (64742-88-7) Bioaccumulative potential No bioaccumulation data available. hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) Log Pow 6 - 8.2 Bioaccumulative potential High potential for bioaccumulation (Log Kow > 5). 12.4. Mobility in soil hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) Surface tension 0.026 N/m (20 ?C) 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to ... Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 882, DURAGLOSS HD LIQUID METAL POLISH Not listed on the United States TSCA (Toxic Substances Control Act) inventory hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics (64742-47-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available 882, DURAGLOSS HD LIQUID METAL POLISH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/29/2015 EN (English US) 7/7 Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations \ \ \ 15.3. US State regulations SECTION 16: Other information Revision date : 05/28/2015 Other information : None. Full text of H-phrases: ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Asp. Tox. 1 Aspiration hazard Category 1 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Flam. Liq. 4 Flammable liquids Category 4 ------ Skin Corr. 1B Skin corrosion/irritation Category 1B ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 ------ H227 Combustible liquid ------ H304 May be fatal if swallowed and enters airways ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H372 Causes damage to organs through prolonged or repeated exposure ------ H400 Very toxic to aquatic life SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product