Diesel Cetane Boost Liquid. GHS product identifier Product type Emergency telephone number (with hours of operation) : : : Code : ACB Manufacturer : R Diesel Cetane Boost SAFETY DATA SHEET Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada Diesel Fuel Additive. : AMSOIL INC. Bordner, Ladner, Gervais Scotia Plaza, 40 King St W Toronto, ON, Canada M5H 3Y4 Tel: +1 416-367-6547 Section 1. Identification Date Version : : 04/15/2017 8 AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 CHEMTREC: Within USA and Canada: 1-800-424-9300; Outside USA and Canada: +1 703-741-5970 (collect calls accepted) (24/7) Identified uses : Initial Supplier (Canada) FLAMMABLE LIQUIDS - Category 4 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhalation) - Category 4 AQUATIC HAZARD (LONG-TERM) - Category 2 Classification of the substance or mixture : Signal word : Warning Hazard statements : Hazard pictograms : Precautionary statements GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification Combustible liquid. Harmful if swallowed, in contact with skin or if inhaled. Toxic to aquatic life with long lasting effects. 1/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Prevention : Response : Storage : Disposal : Hazards not otherwise classified (HNOC) Physical hazards not otherwise classified (PHNOC) : None known. Health hazards not otherwise classified (HHNOC) : None known. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from flames and hot surfaces. - No smoking. Use only outdoors or in a well- ventilated area. Avoid release to the environment. Avoid breathing vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Collect spillage. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. Store in a well-ventilated place. Keep cool. Dispose of contents and container in accordance with all local, regional, national and international regulations. Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : ACB CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Section 3. Composition/information on ingredients 2-Ethylhexyl nitrate 80 - 100 27247-96-7 Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs. Eye contact : Description of necessary first aid measures Section 4. First aid measures 2/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact Inhalation Ingestion : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : Harmful if inhaled. Harmful if swallowed.:Ingestion Skin contact : Harmful in contact with skin. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary 3/12 04/15/2017:Date of issue Diesel Cetane Boost ACB See toxicological information (Section 11) Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Combustible liquid. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : : Do not use water jet or water-based fire extinguishers. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 5. Fire-fighting measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 6. Accidental release measures 4/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Spill Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Avoid contact with used product. Do not reuse container. : Precautions for safe handling Section 7. Handling and storage Control parameters United States Occupational exposure limits Section 8. Exposure controls/personal protection Under conditions which may generate mists, the following exposure limits are recommended: ACGIH TLV TWA: 5 mg/m? ; STEL: 10 mg/m?. None known. Occupational exposure limits Canada 5/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. None. Physical state Melting point Liquid. <-45?C (<-49?F) Pungent.Odor pH Clear to light straw.Color Flash point Closed cup: 65?C (149?F) [Pensky-Martens.] Not available. Not available.Odor threshold : : : : : : : Appearance Boiling point : Not available. Section 9. Physical and chemical properties 6/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Vapor pressure Relative density Vapor density Solubility 0.96 Not available. 0.027 kPa (0.2 mm Hg) [room temperature] Not available. Evaporation rate Not available. Auto-ignition temperature 130?C (266?F) 5.24 Viscosity Kinematic: 0.018 cm2/s (1.8 cSt) (20oC) Kinematic: 0.0102 cm2/s (1.02 cSt) (40oC) Partition coefficient: n- octanol/water : : : : : : : : Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Solubility in water : 12.6 g/l Volatility Not available.: Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Unstable at temperatures greater than 100?C/212?F.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Acute toxicity Irritation/Corrosion Sensitization Information on toxicological effects There is no data available. There is no data available. There is no data available. Section 11. Toxicological information 7/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Carcinogenicity Information on the likely routes of exposure Inhalation : Harmful if inhaled. Harmful if swallowed.:Ingestion Skin contact : Harmful in contact with skin. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Numerical measures of toxicity Acute toxicity estimates Aspiration hazard : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. There is no data available. There is no data available. There is no data available. 8/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Route ATE value Oral 505.1 mg/kg Dermal 1111.1 mg/kg Inhalation (vapors) 11.11 mg/L LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toxicity Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil There is no data available. There is no data available. Diesel Cetane Boost 5.24 - high 2-Ethylhexyl nitrate 5.24 - high Section 12. Ecological information The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 13. Disposal considerations 9/12 04/15/2017:Date of issue Diesel Cetane Boost ACB COMBUSTIBLE LIQUID, N.O. S. (2-Ethylhexyl nitrate). Marine pollutant (2-Ethylhexyl nitrate) - III ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Ethylhexyl nitrate). Marine pollutant (2-Ethylhexyl nitrate) 9 III ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Ethylhexyl nitrate) UN3082 9 III NA1993 UN3082 Non-bulk packages (less than or equal to 119 gal) of combustible liquids, that are marine pollutants, are not regulated as hazardous materials, unless transported by vessel. This product is not regulated as a marine pollutant when transported on inland waterways in sizes of ?5 L or ?5 kg or by road, rail, or inland air in non-bulk sizes, provided the packagings meet the general provisions of ?? 173. 24 and 173.24a. Remarks Limited Quantity Exemption This product is not regulated as a dangerous good when transported in sizes of ?5 L or ?5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8. Remarks Limited Quantity Exemption This product is not regulated as a dangerous good when transported in sizes of ?5 L or ?5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6. 1.1 and 5.0.2.8. Remarks Limited Quantity Exemption DOT IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Yes. Yes. Yes. AERG : 128, 171 Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : TDG Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.43-2. 45 (Class 9), 2.7 (Marine pollutant mark). Non-bulk packages of this product are not regulated as dangerous goods when transported by road or rail. Remarks Limited Quantity Exemption Yes. UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Ethylhexyl nitrate) 9 III Section 14. Transport information 10/12 04/15/2017:Date of issue Diesel Cetane Boost ACB U.S. Federal regulations None of the components are listed. No products were found. Massachusetts : : SARA 313 California Prop. 65 : Not listed : Not listed : Not listed : Not listed : Not listed New York : None of the components are listed. New Jersey : None of the components are listed. Pennsylvania : None of the components are listed. State regulations SARA 302/304 SARA 304 RQ : 1000000 lbs / 454000 kg [124931.4 gal / 472916.7 L] Composition/information on ingredients Name EHS (lbs) (lbs)(gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification : Fire hazard Immediate (acute) health hazard Name Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Nitric acid Yes. 1000 85.7 1000 85.7 2-Ethylhexyl nitrate Yes. No. No. Yes. No. Clean Water Act (CWA) 311: Nitric acid Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) No products were found. Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. DEA List II Chemicals (Essential Chemicals) 11/12 04/15/2017:Date of issue Diesel Cetane Boost ACB Canadian lists None of the components are listed.Canadian NPRI : Canada inventory : CEPA Toxic substances : None of the components are listed. Canada All components are listed or exempted. History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 8 04/15/2017 07/15/2015 AMSOIL INC. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information 12/12 04/15/2017:Date of issue