Signature Series Max-Duty Synthetic Diesel Oil Liquid. GHS product identifier Product type Emergency telephone number (with hours of operation) : : : Code : DEO Manufacturer : R Signature Series Max-Duty Synthetic Diesel Oil SAFETY DATA SHEET Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada Diesel Engine Oil. Not to be misted. : AMSOIL INC. Bordner, Ladner, Gervais Scotia Plaza, 40 King St W Toronto, ON, Canada M5H 3Y4 Tel: +1 416-367-6547 Section 1. Identification Date Version : : 10/01/2016 7 AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 CHEMTREC: Within USA and Canada: 1-800-424-9300; Outside USA and Canada: +1 703-741-5970 (collect calls accepted) (24/7) Identified uses : Initial Supplier (Canada) AQUATIC HAZARD (ACUTE) - Category 3 AQUATIC HAZARD (LONG-TERM) - Category 3 Classification of the substance or mixture : Signal word : No signal word. Hazard statements : Precautionary statements Prevention : Response : Storage : Disposal : GHS label elements OSHA/HCS status : This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified (HNOC) Physical hazards not otherwise classified (PHNOC) : None known. Section 2. Hazards identification Harmful to aquatic life with long lasting effects. Avoid release to the environment. Not applicable. Not applicable. Dispose of contents and container in accordance with all local, regional, national and international regulations. 1/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO Health hazards not otherwise classified (HHNOC) : None known. Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : DEO CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Section 3. Composition/information on ingredients bis(Nonylphenyl)amine 1 - 5 36878-20-3 Benzenesulfonic acid, mono-C16-24-alkyl derivs., calcium salts 1 - 5 70024-69-0 Alcohols, C12-16, ethoxylated 0.1 - 1 68551-12-2 Alkylated phenol 0 - 0.1 121158-58-5 Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Maintain an open airway. Get medical attention if symptoms occur. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Potential acute health effects Section 4. First aid measures 2/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO Protection of first-aiders : No special protection is required. Notes to physician : Treat symptomatically. Specific treatments : No specific treatment. No known significant effects or critical hazards.:Ingestion Over-exposure signs/symptoms Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary No special protection is required. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 5. Fire-fighting measures Personal precautions, protective equipment and emergency procedures : Put on appropriate personal protective equipment.For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 6. Accidental release measures 3/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Spill Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Avoid contact with used product. Do not reuse container. : Precautions for safe handling Section 7. Handling and storage Control parameters United States Occupational exposure limits Section 8. Exposure controls/personal protection Under conditions which may generate mists, the following exposure limits are recommended: ACGIH TLV TWA: 5 mg/m? ; STEL: 10 mg/m?. None known. Occupational exposure limits None. Canada 4/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO Hand protection Not required under normal conditions of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical state Melting point Vapor pressure Vapor density Liquid. -43?C (-45.4?F) Not available. Not available. Mild hydrocarbon.Odor pH Brown.Color Evaporation rate Not available. Flash point Open cup: 218?C (424.4?F) [Cleveland.] Not available. Not available.Odor threshold : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Section 9. Physical and chemical properties 5/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO Relative density Solubility 0.854 Not available. Auto-ignition temperature Not available. Not available. Viscosity Kinematic: 0.154 cm2/s (15.4 cSt) (100oC) Kinematic: 0.945 cm2/s (94.5 cSt) (40oC) Partition coefficient: n- octanol/water : : : : : Decomposition temperature : Not available. Volatility Not available.: Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Acute toxicity Carcinogenicity Irritation/Corrosion Product/ingredient name Result Score Exposure Observation Sensitization Species Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Information on toxicological effects There is no data available. Alcohols, C12-16, ethoxylated Eyes - Moderate irritant Rabbit - 24 hours 100 ?L - There is no data available. There is no data available. There is no data available. There is no data available. Section 11. Toxicological information 6/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Acute toxicity estimates Aspiration hazard : Eye contact. Inhalation. Ingestion. Potential acute health effects Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. There is no data available. 7/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toxicity Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil There is no data available. There is no data available. bis(Nonylphenyl)amine 3.64 to 7.02 1730 high Alkylated phenol 6.1 1601 high Section 12. Ecological information The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 13. Disposal considerations 8/10 10/01/2016:Date of issue Signature Series Max-Duty Synthetic Diesel Oil DEO - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. No. AERG : Not applicable Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : TDG - No. Not regulated. - - - U.S. Federal regulations : : Not listed : Not listed : Not listed : Not listed : Not listed SARA 302/304 Composition/information on ingredients No products were found. Clean Water Act (CWA) 307: Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis (phosphorodithioate); Zinc Dialkyldithiophosphate Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. DEA List II Chemicals (Essential Chemicals) 9/10 10/01/2016:Date of issue Section 14. Transport information Signature Series Max-Duty Synthetic Diesel Oil DEO None of the components are listed. No products were found. Massachusetts : SARA 313 California Prop. 65 New York : None of the components are listed. New Jersey : None of the components are listed. Pennsylvania : None of the components are listed. State regulations SARA 304 RQ : Not applicable. SARA 311/312 Classification : Not applicable. Name Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Benzenesulfonic acid, mono-C16-24-alkyl derivs., calcium salts No. No. No. Yes. No. Alcohols, C12-16, ethoxylated No. No. No. Yes. No. Alkylated phenol No. No. No. Yes. Yes. Canadian lists None of the components are listed.Canadian NPRI : Canada inventory : CEPA Toxic substances : None of the components are listed. Canada No products were found. All components are listed or exempted. History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 7 10/01/2016 03/01/2016 AMSOIL INC. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information 10/10 10/01/2016:Date of issue