Synthetic Multi?Purpose Grease Solid. GHS product identifier Product type Emergency telephone number (with hours of operation) : : : Code : GLC Manufacturer : R Synthetic Multi?Purpose Grease SAFETY DATA SHEET Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada Lubricating Grease. : AMSOIL INC. Bordner, Ladner, Gervais Scotia Plaza, 40 King St W Toronto, ON, Canada M5H 3Y4 Tel: +1 416-367-6547 Section 1. Identification Date Version : : 06/15/2016 6 AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 CHEMTREC: Within USA and Canada: 1-800-424-9300; Outside USA and Canada: +1 703-741-5970 (collect calls accepted) (24/7) Identified uses : Initial Supplier (Canada) SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard statements : Hazard pictograms : Precautionary statements Prevention : GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification Causes serious eye damage. Causes skin irritation. Wear protective gloves. Wear eye or face protection. Wash hands thoroughly after handling. 1/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC Response : Storage : Disposal : Hazards not otherwise classified (HNOC) Physical hazards not otherwise classified (PHNOC) : None known. Health hazards not otherwise classified (HHNOC) : None known. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Not applicable. Not applicable. Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : GLC CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Section 3. Composition/information on ingredients Calcium Dodecylbenzenesulphonate ?5 - ?10 26264-06-2 Diboron calcium tetraoxide ?5 - ?10 13701-64-9 Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Maintain an open airway. Get medical attention if symptoms occur. Eye contact Inhalation : : Description of necessary first aid measures Section 4. First aid measures 2/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Skin contact Ingestion : : Protection of first-aiders : If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat symptomatically. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : Causes skin irritation. Causes serious eye damage.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No known significant effects or critical hazards. Adverse symptoms may include the following: stomach pains Adverse symptoms may include the following: pain or irritation redness blistering may occur : : : Eye contact : Adverse symptoms may include the following: pain watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Use an extinguishing agent suitable for the surrounding fire. Extinguishing media None known. Suitable extinguishing media : Unsuitable extinguishing media : Section 5. Fire-fighting measures 3/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC No special protection is required. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides No specific fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Environmental precautions Personal precautions, protective equipment and emergency procedures : : Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Spill Section 6. Accidental release measures Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Avoid contact with used product. Do not reuse container. : Precautions for safe handling Section 7. Handling and storage 4/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. United States Occupational exposure limits Section 8. Exposure controls/personal protection Under conditions which may generate mists, the following exposure limits are recommended: ACGIH TLV TWA: 5 mg/m? ; STEL: 10 mg/m?. None known. Occupational exposure limits None. Canada 5/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC Physical state Melting point Vapor pressure Relative density Vapor density Solubility Grease. Not available. 1 Not available. Not available. Not soluble in water. Mild (Faint). Odor pH Red.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not available. Not available. Not available. Viscosity Kinematic (40?C (104?F)): >0.21 cm2/s (>21 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Volatility Not available.: Section 9. Physical and chemical properties Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity 6/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC Acute toxicity Product/ingredient name Result Species Dose Exposure Carcinogenicity Irritation/Corrosion Sensitization Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : Causes skin irritation. Causes serious eye damage.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No known significant effects or critical hazards. Adverse symptoms may include the following: stomach pains Adverse symptoms may include the following: pain or irritation redness blistering may occur : : : Eye contact : Adverse symptoms may include the following: pain watering redness Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Name Category Aspiration hazard Route of exposure Target organs Information on toxicological effects : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Calcium Dodecylbenzenesulphonate LD50 Oral Rat 1300 mg/kg - There is no data available. There is no data available. There is no data available. Diboron calcium tetraoxide Category 3 Not applicable. Respiratory tract irritation There is no data available. There is no data available. Section 11. Toxicological information 7/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Route ATE value Acute toxicity estimates Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. Oral 26000 mg/kg Mobility There is no data available.: Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Toxicity Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil There is no data available. There is no data available. There is no data available. Section 12. Ecological information 8/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 13. Disposal considerations ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. RQ (Calcium Dodecylbenzenesulphonate) 9 III - - - - Not regulated. - - UN3077 Not regulated. Non-bulk packages of this product are not regulated as hazardous materials in package sizes less than the product reportable quantity, unless transported by inland waterway. The marine pollutant mark is not required when transported on inland waterways in sizes of ?5 L or ?5 kg. Reportable quantity 20000 lbs / 9080 kg Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) - - DOT IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Yes. No. No. TDG - No. Not regulated. - - - Section 14. Transport information 9/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC transportation requirements. Remarks Limited quantity AERG : 171 Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : DOT-RQ Details Calcium Dodecylbenzenesulphonate 1000 lbs / 454 kg: U.S. Federal regulations : SARA 313 : Not listed : Not listed : Not listed : Not listed : Not listed SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : Immediate (acute) health hazard Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients No products were found. Calcium Dodecylbenzenesulphonate ?5 - ?10 No. No. No. Yes. No. Diboron calcium tetraoxide ?5 - ?10 No. No. No. Yes. No. Clean Water Act (CWA) 311: Calcium Dodecylbenzenesulphonate Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. DEA List II Chemicals (Essential Chemicals) 10/11 06/15/2016:Date of issue Synthetic Multi?Purpose Grease GLC The following components are listed: Calcium Dodecylbenzenesulphonate No products were found. Massachusetts : California Prop. 65 New York : The following components are listed: Calcium Dodecylbenzenesulphonate New Jersey : The following components are listed: Calcium Dodecylbenzenesulphonate Pennsylvania : The following components are listed: Calcium Dodecylbenzenesulphonate State regulations Canadian lists None of the components are listed.Canadian NPRI : Canada inventory : CEPA Toxic substances : None of the components are listed. Canada No products were found. All components are listed or exempted. History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 6 06/15/2016 06/15/2014 AMSOIL INC. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information 11/11 06/15/2016:Date of issue