Heavy Duty Metal Protector Aerosol. GHS product identifier Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : Code : AMH Supplier's details : Identified uses R Heavy Duty Metal Protector SAFETY DATA SHEET Conforms to HCS 2012 - United States AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 CHEMTREC: Within USA and Canada: 1-800-424-9300 Outside USA and Canada: +1 703-741-5970 (collect calls accepted) (24/7) Corrosion inhibitor. Date Version : : 07/15/2016 6 FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Liquefied gas SKIN IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. Hazard pictograms : GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification 1/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Precautionary statements Prevention : Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Avoid breathing vapor. Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn, even after use. Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Hydrogenated Base Oil (64742-47-8) 25 - 40 64742-47-8 Hydrogenated Base Oil (64742-49-0) 15 - 25 64742-49-0 Hydrogenated Base Oil (64742-52-5) 1 - 5 64742-52-5 Ingredient name CAS number% Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : AMH CAS number/other identifiers : Mixture There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. United States Section 3. Composition/information on ingredients Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Eye contact : Description of necessary first aid measures Section 4. First aid measures 2/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention if symptoms occur. Skin contact Inhalation Ingestion : : : Protection of first-aiders : It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: nausea or vomiting Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 3/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 5. Fire-fighting measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 6. Accidental release measures 4/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Methods and materials for containment and cleaning up Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Section 7. Handling and storage Hydrogenated Base Oil (64742-47-8) ACGIH TLV (United States, 3/2015). Absorbed through skin. TWA: 200 mg/m?, (as total hydrocarbon vapor) 8 hours. Hydrogenated Base Oil (64742-49-0) None. Hydrogenated Base Oil (64742-52-5) ACGIH TLV (United States, 3/2015). TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist OSHA PEL (United States, 2/2013). TWA: 5 mg/m? 8 hours. Ingredient name Exposure limits Control parameters Occupational exposure limits Section 8. Exposure controls/personal protection 5/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical state Melting point / Pour point Liquid. [Aerosol.] Not available. Solvent.Odor pH Amber.Color Evaporation rate Not available. Flash point Not available. Not available. Not available.Odor threshold : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Section 9. Physical and chemical properties 6/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Vapor pressure Relative density Vapor density Solubility Not available. Not available. Not available. Insoluble Auto-ignition temperature Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : : : Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 9.14 kJ/g Aerosol product Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Acute toxicity Hydrogenated Base Oil (64742-52-5) LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure Mutagenicity Irritation/Corrosion Sensitization Information on toxicological effects Section 11. Toxicological information There is no data available. There is no data available. 7/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Carcinogenicity Teratogenicity Reproductive toxicity Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Hydrogenated Base Oil (64742-49-0) Category 3 Not applicable. Narcotic effects Name Category Aspiration hazard Name Result Hydrogenated Base Oil (64742-47-8) ASPIRATION HAZARD - Category 1 Hydrogenated Base Oil (64742-49-0) ASPIRATION HAZARD - Category 1 Hydrogenated Base Oil (64742-52-5) ASPIRATION HAZARD - Category 1 Route of exposure Target organs : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects There is no data available. There is no data available. Classification Hydrogenated Base Oil (64742-47-8) - - - A3 - - Product/ingredient name ACGIH EPA NIOSHNTPIARCOSHA There is no data available. There is no data available. 8/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion Adverse symptoms may include the following: nausea or vomiting Adverse symptoms may include the following: irritation redness : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Acute toxicity estimates Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. LogPow BCF Potential Bioaccumulative potential Product/ingredient name Hydrogenated Base Oil (64742-49-0) 2.2 to 5.2 10 to 2500 high Toxicity Hydrogenated Base Oil (64742-47-8) Acute LC50 2200 ?g/l Fresh water Fish - Lepomis macrochirus 4 days Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil There is no data available. Section 12. Ecological information 9/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH Other adverse effects : No known significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 13. Disposal considerations Aerosols, flammable (each not exceeding 1 L capacity) 2.1 - Aerosols, flammable (each not exceeding 1 L capacity) 2.1 - Aerosols, flammable (each not exceeding 1 L capacity) UN1950 2.1 - UN1950 UN1950 Remarks Limited quantity Emergency schedules (EmS) F-D, S-U Remarks Limited quantity Remarks Limited quantity IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code No. No. No. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : AERG : 126 DOT Classification Section 14. Transport information 10/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH U.S. Federal regulations The following components are listed: Propane; Butane No products were found. Clean Air Act (CAA) 112 regulated flammable substances: Propane; Butane Massachusetts : : SARA 313 California Prop. 65 Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed New York : None of the components are listed. New Jersey : The following components are listed: Propane; Butane Pennsylvania : The following components are listed: Hydrogenated Base Oil (64742-47-8); Propane; Butane; Hydrogenated Base Oil (64742-52-5) State regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : Fire hazard Sudden release of pressure Immediate (acute) health hazard Hydrogenated Base Oil (64742-47-8) ?25 - ?50 Yes. No. No. No. No. Hydrogenated Base Oil (64742-49-0) ?10 - <25 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Section 15. Regulatory information No products were found. 11/12 07/15/2016:Date of issue Heavy Duty Metal Protector AMH History Procedure used to derive the classification Classification Justification FLAMMABLE AEROSOLS - Category 1 On basis of test data GASES UNDER PRESSURE - Liquefied gas Expert judgment SKIN IRRITATION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method ASPIRATION HAZARD - Category 1 Expert judgment AQUATIC HAZARD (LONG-TERM) - Category 3 Calculation method Section 16. Other information Date of issue mm/dd/yyyy Prepared by : Date of previous issue Version : : : 6 07/15/2016 09/15/2014 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. AMSOIL INC. 12/12 07/15/2016:Date of issue