AMSOIL Injector Oil Liquid. GHS product identifier Product type Emergency telephone number (with hours of operation) : : : Code : AIO Manufacturer : R AMSOIL Injector Oil SAFETY DATA SHEET Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada Lubricating Oil. Not to be misted. : AMSOIL INC. Bordner, Ladner, Gervais Scotia Plaza, 40 King St W Toronto, ON, Canada M5H 3Y4 Tel: +1 416-367-6547 Section 1. Identification Date Version : : 04/15/2017 4 AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 CHEMTREC: Within USA and Canada: 1-800-424-9300; Outside USA and Canada: +1 703-741-5970 (collect calls accepted) (24/7) Identified uses : Initial Supplier (Canada) FLAMMABLE LIQUIDS - Category 4 CARCINOGENICITY - Category 2 Classification of the substance or mixture : Signal word : Warning Hazard statements : Hazard pictograms : Precautionary statements Prevention : Response : GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification Combustible liquid. Suspected of causing cancer. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from flames and hot surfaces. - No smoking. IF exposed or concerned: Get medical attention. 1/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Storage : Disposal : Hazards not otherwise classified (HNOC) Physical hazards not otherwise classified (PHNOC) : None known. Health hazards not otherwise classified (HHNOC) : None known. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents and container in accordance with all local, regional, national and international regulations. Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : AIO CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Section 3. Composition/information on ingredients Hydrogenated Base Oil (64742-47-8) 15 - 25 64742-47-8 Hydrogenated Base Oil (64742-48-9) 15 - 25 64742-48-9 Synthetic Ester 10 - 15 - Hydrocarbyl amine 5 - 10 - Cumene 0.1 - 1 98-82-8 *HMIRA registration number : 10945 *HMIRA filing date : 2017-01-05 Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 20 minutes. Get medical attention. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Maintain an open airway. Get medical attention if symptoms occur. Eye contact Skin contact Inhalation : : : Description of necessary first aid measures Section 4. First aid measures 2/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. Ingestion : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical No specific data. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : : Do not use water jet or water-based fire extinguishers. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 5. Fire-fighting measures 3/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Environmental precautions Personal precautions, protective equipment and emergency procedures : : Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Spill Section 6. Accidental release measures Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Avoid contact with used product. Do not reuse container. : Precautions for safe handling Section 7. Handling and storage 4/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Control parameters United States Cumene ACGIH TLV (United States, 3/2015). TWA: 50 ppm 8 hours. NIOSH REL (United States, 10/2013). Absorbed through skin. TWA: 50 ppm 10 hours. TWA: 245 mg/m? 10 hours. OSHA PEL (United States, 2/2013). Absorbed through skin. TWA: 50 ppm 8 hours. TWA: 245 mg/m? 8 hours. Ingredient name Exposure limits Occupational exposure limits Section 8. Exposure controls/personal protection Under conditions which may generate mists, the following additional exposure limits are recommended: ACGIH TLV TWA: 5 mg/m? ; STEL: 10 mg/m?. Occupational exposure limits Cumene CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 50 ppm 8 hours. 8 hrs OEL: 246 mg/m? 8 hours. CA British Columbia Provincial (Canada, 5/2015). TWA: 25 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). TWAEV: 50 ppm 8 hours. TWAEV: 246 mg/m? 8 hours. CA Saskatchewan Provincial (Canada). STEL: 74 ppm 15 minutes. TWA: 50 ppm 8 hours. Ingredient name Exposure limits Canada 5/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. -57?C (-70.6?F) 0.8639 Not available. Not available. Not available. Mild hydrocarbon.Odor pH Blue.Color Evaporation rate Not available. Flash point Open cup: 86?C (186.8?F) [Cleveland.] Not available. Not available. Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Section 9. Physical and chemical properties 6/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Auto-ignition temperature Not available. Viscosity Kinematic: 0.066 cm2/s (6.6 cSt) (100oC) Kinematic: 0.329 cm2/s (32.9 cSt) (40oC) : : Decomposition temperature : Not available. Volatility Not available.: Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Acute toxicity Product/ingredient name Result Species Dose Exposure Carcinogenicity Irritation/Corrosion Product/ingredient name Result Score Exposure Observation Sensitization Species Specific target organ toxicity (single exposure) Information on toxicological effects Hydrogenated Base Oil (64742-48-9) LD50 Oral Rat >6 g/kg - Cumene LC50 Inhalation Vapor Rat 39000 mg/m? 4 hours LD50 Oral Rat 1400 mg/kg - Cumene Eyes - Mild irritant Rabbit - 24 hours 500 mg - Eyes - Mild irritant Rabbit - 86 mg - Skin - Mild irritant Rabbit - 24 hours 10 mg - There is no data available. Section 11. Toxicological information Classification Cumene - 2B Reasonably anticipated to be a human carcinogen. Product/ingredient name NTPIARCOSHA 7/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Name Category Numerical measures of toxicity Aspiration hazard Name Result : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. Hydrogenated Base Oil (64742-47-8) ASPIRATION HAZARD - Category 1 Hydrogenated Base Oil (64742-48-9) ASPIRATION HAZARD - Category 1 Cumene ASPIRATION HAZARD - Category 1 Target organs Cumene Category 3 Respiratory tract irritation 8/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Acute toxicity estimates There is no data available. Mobility There is no data available.: LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toxicity Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil Hydrogenated Base Oil (64742-47-8) Acute LC50 2200 ?g/l Fresh water Fish - Lepomis macrochirus 4 days Cumene Acute EC50 2600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 7400 ?g/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 10600 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 2700 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours There is no data available. Hydrogenated Base Oil (64742-48-9) - 10 to 2500 high Cumene 3.55 94.69 low Section 12. Ecological information The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 13. Disposal considerations 9/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO COMBUSTIBLE LIQUID, N.O. S. (Hydrogenated Base Oil (64742-48-9), Hydrogenated Base Oil (64742-47-8)) - III - - - - Not regulated. - - NA1993 Not regulated. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials. - - DOT IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. No. AERG : 128 Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : TDG - No. Not regulated. - - - Section 14. Transport information U.S. Federal regulations : : Listed : Not listed : Not listed Clean Water Act (CWA) 311: Toluene; Benzene; Ethylbenzene; Naphthalene; Xylene Clean Water Act (CWA) 307: Toluene; Benzene; Ethylbenzene; Naphthalene Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. 10/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO None of the components are listed. WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Massachusetts : SARA 313 Cumene Yes. No. No. No. Ethylbenzene Yes. No. 41 ?g/day (ingestion) 54 ?g/day (inhalation) No. Toluene No. Yes. No. 7000 ?g/day (ingestion) Benzene Yes. Yes. 6.4 ?g/day (ingestion) 13 ?g/day (inhalation) 24 ?g/day (ingestion) 49 ?g/day (inhalation) Naphthalene Yes. No. Yes. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level California Prop. 65 : Not listed : Not listed New York : The following components are listed: Cumene New Jersey : The following components are listed: Cumene Pennsylvania : The following components are listed: Hydrogenated Base Oil (64742-47-8); Cumene State regulations SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : Fire hazard Delayed (chronic) health hazard Name Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients No products were found. Hydrogenated Base Oil (64742-47-8) Yes. No. No. No. No. Hydrogenated Base Oil (64742-48-9) Yes. No. No. No. No. Hydrocarbyl Amine No. No. No. Yes. No. Cumene Yes. No. No. Yes. Yes. Canadian lists The following components are listed: Hydrogenated Base Oil (64742-47-8); Hydrogenated Base Oil (64742-48-9) Canadian NPRI : CEPA Toxic substances : None of the components are listed. Canada DEA List I Chemicals (Precursor Chemicals) No products were found. DEA List II Chemicals (Essential Chemicals) 11/12 04/15/2017:Date of issue AMSOIL Injector Oil AIO Canada inventory : All components are listed or exempted. History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 4 04/15/2017 11/15/2016 AMSOIL INC. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information 12/12 04/15/2017:Date of issue