AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil Liquid. GHS product identifier Product type Emergency telephone number (with hours of operation) : : : Code : AMO Manufacturer : R AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil SAFETY DATA SHEET Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada Lubricating Oil. Not to be misted. : AMSOIL INC. Bordner, Ladner, Gervais Scotia Plaza, 40 King St W Toronto, ON, Canada M5H 3Y4 Tel: +1 416-367-6547 Section 1. Identification Date Version : : 11/15/2016 7 AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 CHEMTREC: Within USA and Canada: 1-800-424-9300; Outside USA and Canada: +1 703-741-5970 (collect calls accepted) (24/7) Identified uses : Initial Supplier (Canada) AQUATIC HAZARD (ACUTE) - Category 3 AQUATIC HAZARD (LONG-TERM) - Category 3 Classification of the substance or mixture : Signal word : No signal word. Hazard statements : Precautionary statements Prevention : Response : Storage : Disposal : GHS label elements OSHA/HCS status : This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified (HNOC) Physical hazards not otherwise classified (PHNOC) : None known. Section 2. Hazards identification Harmful to aquatic life with long lasting effects. Avoid release to the environment. Not applicable. Not applicable. Dispose of contents and container in accordance with all local, regional, national and international regulations. 1/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Health hazards not otherwise classified (HHNOC) : None known. Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : AMO CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Section 3. Composition/information on ingredients bis(Nonylphenyl)amine 1 - 5 36878-20-3 Zinc Dialkyldithiophosphate 1 - 5 84605-29-8 Diphenylamine 0.1 - 1 122-39-4 Alkylated phenol 0 - 0.1 121158-58-5 Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Eye contact Skin contact Inhalation : : : Description of necessary first aid measures Section 4. First aid measures 2/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : None known. Suitable extinguishing media : Unsuitable extinguishing media : Section 5. Fire-fighting measures 3/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Environmental precautions Personal precautions, protective equipment and emergency procedures : : Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Spill Section 6. Accidental release measures Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Avoid contact with used product. Do not reuse container. : Precautions for safe handling Section 7. Handling and storage 4/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Skin protection United States Diphenylamine ACGIH TLV (United States, 3/2015). TWA: 10 mg/m? 8 hours. NIOSH REL (United States, 10/2013). TWA: 10 mg/m? 10 hours. Ingredient name Exposure limits Occupational exposure limits Section 8. Exposure controls/personal protection Under conditions which may generate mists, the following additional exposure limits are recommended: ACGIH TLV TWA: 5 mg/m? ; STEL: 10 mg/m?. Occupational exposure limits None. Canada 5/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. -42?C (-43.6?F) 0.8586 Not available. Not available. Not available. Mild hydrocarbon.Odor pH Brown.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Open cup: 226?C (438.8?F) [Cleveland.] Not available. Not available. Viscosity Kinematic: 0.146 cm2/s (14.6 cSt) (100oC) Kinematic: 0.959 cm2/s (95.9 cSt) (40oC) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Volatility Not available.: Section 9. Physical and chemical properties 6/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Acute toxicity Product/ingredient name Result Species Dose Exposure Carcinogenicity Irritation/Corrosion Sensitization Information on the likely routes of exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Name Category Aspiration hazard Information on toxicological effects : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Zinc Dialkyldithiophosphate LD50 Oral Rat 3.2 g/kg - Diphenylamine LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 1120 mg/kg - There is no data available. There is no data available. There is no data available. There is no data available. There is no data available. Section 11. Toxicological information Target organs Diphenylamine Category 2 Not determined 7/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Acute toxicity estimates Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. Toxicity Product/ingredient name SpeciesResult Exposure Diphenylamine Acute EC50 2.17 mg/L Fresh water Algae - Pseudokirchneriella subcapitata - Exponential growth phase 72 hours Acute EC50 0.31 mg/L Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2.2 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours Chronic NOEC 0.37 mg/L Fresh water Algae - Pseudokirchneriella subcapitata - Exponential growth phase 72 hours Section 12. Ecological information 8/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO Mobility There is no data available.: LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil There is no data available. bis(Nonylphenyl)amine 3.64 to 7.02 1730 high Zinc Dialkyldithiophosphate 0.56 - low Diphenylamine 3.5 151.36 low Alkylated phenol 6.1 1601 high The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 13. Disposal considerations - - - - - - - Not regulated. - - Not regulated. Not regulated. DOT IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group TDG Not regulated. - - - Section 14. Transport information 9/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO - - -Additional information Environmental hazards No. No. No. AERG : Not applicable Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : - No. U.S. Federal regulations : SARA 313 : Not listed : Not listed : Not listed : Not listed : Not listed SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : Not applicable. Name Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients No products were found. Zinc Dialkyldithiophosphate No. No. No. Yes. No. Diphenylamine No. No. No. Yes. Yes. Alkylated phenol No. No. No. Yes. Yes. Clean Water Act (CWA) 307: Zinc Dialkyldithiophosphate Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. DEA List II Chemicals (Essential Chemicals) 10/11 11/15/2016:Date of issue AMSOIL Premium Protection Synthetic SAE 10W-40 Motor Oil AMO None of the components are listed. No products were found. Massachusetts : California Prop. 65 New York : None of the components are listed. New Jersey : The following components are listed: Zinc Dialkyldithiophosphate Pennsylvania : None of the components are listed. State regulations Canadian lists The following components are listed: Zinc DialkyldithiophosphateCanadian NPRI : Canada inventory : CEPA Toxic substances : None of the components are listed. Canada Product name CAS number % Zinc Dialkyldithiophosphate 84605-29-8 1 - 5 Zinc Dialkyldithiophosphate 84605-29-8 1 - 5 Form R - Reporting requirements Supplier notification SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. All components are listed or exempted. History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 7 11/15/2016 05/30/2016 AMSOIL INC. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information 11/11 11/15/2016:Date of issue