_____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 1 of 9 Techron Fuel Injector Cleaner SDS : 35580 Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Techron Fuel Injector Cleaner Product Use: Fuel Additive Product Number(s): 266349 Company Identification Chevron Products Company a division of Chevron U.S.A. Inc. 6001 Bollinger Canyon Rd. San Ramon, CA 94583 United States of America www.chevronlubricants.com Transportation Emergency Response CHEMTREC: (800) 424-9300 or (703) 527-3887 Health Emergency Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or (510) 231-0623 Product Information email : This email address is being protected from spambots. You need JavaScript enabled to view it. Product Information: 1 (800) 582-3835, This email address is being protected from spambots. You need JavaScript enabled to view it. SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION: Flammable liquid: Category 3. Aspiration toxicant: Category 1. Skin Sensitizer: Category 1. Target organ toxicant (central nervous system): Category 3. Acute aquatic toxicant: Category 2. Chronic aquatic toxicant: Category 2. Signal Word: Danger Physical Hazards: Flammable liquid and vapor. Health Hazards: May be fatal if swallowed and enters airways. May cause allergic skin reaction. May cause drowsiness or dizziness. Environmental Hazards: Toxic to aquatic life. Toxic to aquatic life with long lasting effects. _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 2 of 9 Techron Fuel Injector Cleaner SDS : 35580 PRECAUTIONARY STATEMENTS: General: Keep out of reach of children. Read label before use. Prevention: Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF ON SKIN (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. IF SWALLOWED: Immediately call a poison center or doctor/physician. Do NOT induce vomiting. Call a poison center or doctor/physician if you feel unwell. In case of fire: Use media specified in the SDS to extinguish. Specific treatment (see Notes to Physician on this label). Collect spillage. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER AMOUNT Distillates (petroleum), hydrotreated light 64742-47-8 0< 80 %wt/wt Stoddard solvent 8052-41-3 0< 50 %wt/wt 01154100-5179P Trade secret 3 - 7 %wt/wt 1,2,4-trimethylbenzene 95-63-6 1 - 5 %wt/wt 01154100-5323P Trade Secret 0.1 - 1 %wt/wt SECTION 4 FIRST AID MEASURES Description of first aid measures Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical attention if any symptoms develop. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person. Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if breathing difficulties continue or if any other symptoms develop. Most important symptoms and effects, both acute and delayed _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 3 of 9 Techron Fuel Injector Cleaner SDS : 35580 IMMEDIATE SYMPTOMS AND HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Skin contact may cause drying or defatting of the skin. Contact with the skin may cause an allergic skin reaction. Symptoms may include pain, itching, discoloration, swelling, and blistering. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: Because of its low viscosity, this material can directly enter the lungs, if swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death. Inhalation: The vapor or fumes from this material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and difficulty breathing. Excessive or prolonged breathing of this material may cause central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness, coma or death. DELAYED OR OTHER SYMPTOMS AND HEALTH EFFECTS: Not classified. Indication of any immediate medical attention and special treatment needed Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light hydrocarbon liquid, which may cause pneumonitis. SECTION 5 FIRE FIGHTING MEASURES See Section 7 for proper handling and storage. EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this material is released into the work area, evacuate the area immediately. Monitor area with combustible gas indicator. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. All equipment used when handling the product must be grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities as appropriate or required. SECTION 7 HANDLING AND STORAGE Precautionary Measures: Do not get in eyes, on skin, or on clothing. Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive force. Invisible vapor spreads easily and can be set _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 4 of 9 Techron Fuel Injector Cleaner SDS : 35580 on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises above 29C (85F). Do not taste or swallow. Do not breathe vapor or fumes. Keep out of the reach of children. Wash thoroughly after handling. General Storage Information:DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use. General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may include gloves, apron, boots, and complete facial protection depending on operations conducted. Suggested materials for protective gloves include: Chlorinated Polyethylene (or Chlorosulfonated Polyethylene), Nitrile Rubber, Polyurethane, Viton. Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits: Component Agency TWA STEL Ceiling Notation 1,2,4-trimethylbenzene ACGIH 25 ppm -- -- -- _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 5 of 9 Techron Fuel Injector Cleaner SDS : 35580 (weight) Distillates (petroleum), hydrotreated light ACGIH 200 mg/m3 -- -- Skin A3 Total hydrocabon vapor Stoddard solvent ACGIH 100 ppm (weight) -- -- -- Stoddard solvent OSHA Z-1 2900 mg/m3 -- -- -- Consult local authorities for appropriate values. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Attention: the data below are typical values and do not constitute a specification. Color: Colorless to yellow Physical State: Liquid Odor: Petroleum odor Odor Threshold: No data available pH: Not Applicable Vapor Pressure: 2 mmHg (Typical) @ 20 ?C (68 ?F) Vapor Density (Air = 1): <1 Initial Boiling Point: 157.2?C (315?F) (Min) Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable Specific Gravity: 0.8 @ 10?C (50?F) Viscosity: 1.2 mm2/s @ 25?C (77?F) (Typical) Evaporation Rate: No data available Decomposition temperature: No Data Available Octanol/Water Partition Coefficient: No data available FLAMMABLE PROPERTIES: Flammability (solid, gas): No Data Available Flashpoint: (Pensky-Martens Closed Cup) 41 ?C (105 ?F) (Min) Autoignition: 240 ?C (464 ?F) Flammability (Explosive) Limits (% by volume in air): Lower: 2.3 Upper: 14.4 SECTION 10 STABILITY AND REACTIVITY Reactivity: This material is not expected to react. Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 6 of 9 Techron Fuel Injector Cleaner SDS : 35580 Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product components. Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product components. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product components. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components. Acute Toxicity Estimate: Not Determined Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material. Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for components or a similar material. ADDITIONAL TOXICOLOGY INFORMATION: This product contains Stoddard solvent, a mixture of straight and branched-chain paraffins, naphthenes and aromatic hydrocarbons. Based on studies of Stoddard solvent sample 85-01 sponsored by the American Petroleum Institute, the acute dermal LD50 was found to be >3.0 g/kg and the acute oral LD50 was found to >5.0 g/kg. Acute inhalation toxicity tests showed a no observable effect level for inhalation of Stoddard solvent at 4.0 mg/l, with eye irritation and slight loss of coordination at 8 mg/l, and tremors, CNS depression and death within 7.5 hours of exposure to 10 mg/l. In a 28-day dermal study sponsored by the API, moderate skin irritation occurred at 200 mg/kg, with moderate to severe irritation above 1000 mg/kg. The API also determined the primary dermal irritation index to be 4.5, and the primary eye irritation index to be 0.0 at 24 hours. In human sensory response tests, exposure to Stoddard solvent at 0.60 mg/l caused mild eye and nose irritation after 30 minutes, with increased blink rate and eye irritation at 2.4 mg/l, and eye irritation and tearing at 2.7 mg/l. No significant effects on psychomotor performance were noted. COMPONENT: Light Aromatic Solvent Naphtha (CAS 64742-95-6, also described as High-Flash Aromatic Naphtha, Type I, as defined by ASTM D-3734). GENETIC TOXICITY: No evidence of genetic toxicity was observed in the following tests: Salmonella typhimurium reverse mutation assay (Ames test), in vitro Chinese Hamster Ovary (CHO) cell HGPRT mutation assay, in vitro Chinese Hamster Ovary (CHO) cell chromosomal aberration assay, in vitro Chinese Hamster Ovary (CHO) cell sister chromatid exchange assay, and in vivo rat bone marrow chromosome aberration assay. SUBCHRONIC TOXICITY: In a 13-week rat inhalation study using dose levels of 0, 100, 500, and 1500 ppm for 6 hours/day, 5 days/week, no target organ toxicity including neurotoxicity was observed at any dose level. Slight general systemic toxicity (decreased body weight gain) was observed at 1500 ppm. DEVELOPMENTAL TOXICITY: In a mouse inhalation study using dose levels of 0, 100, 500, and 1500 ppm for 6 hours/day on gestation days 6-15, no signs of maternal toxicity or developmental toxicity were _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 7 of 9 Techron Fuel Injector Cleaner SDS : 35580 observed at 100 ppm. At 500 ppm, maternal toxicity (decreased body weight gain) and developmental toxicity (decreased fetal body weight) were observed. Severe maternal toxicity (44% mortality, decreased body weight gain, clinical signs of toxicity) and developmental toxicity (decreased number of live fetuses per litter, increased post-implantation losses per dam, decreased fetal body weights, delayed ossification, cleft palate) were observed at 1500 ppm. In a rat inhalation study using dose levels of 600, 1000, and 2000 mg/m3 for 24 hours/day on gestation days 7-15, signs of maternal toxicity (decreased body weight gain) were observed at all dose levels. At 600 mg/m3, no signs of fetal or developmental toxicity were observed. Signs of fetal toxicity (decreased male fetal body weight) and developmental toxicity (delayed ossification) were observed at 1000 and 2000 mg/m3. REPRODUCTIVE TOXICITY: In a rat 3-generation inhalation study using dose levels of 0, 100, 500, and 1500 ppm for 6 hours/day, 5 days/week, no signs of general systemic or reproductive toxicity were observed at 100 ppm. At 500 ppm, slight parental toxicity (decreased body weight gain) and postnatal toxicity (decreased pup body weight) were observed, but reproductive parameters were not affected. Severe parental toxicity (mortality, decreased body weight gain, clinical signs of toxicity) and postnatal toxicity (decreased pup body weight) were observed at 1500 ppm, but reproductive parameters were not affected. SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY This material is expected to be toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. The product has not been tested. The statement has been derived from the properties of the individual components. MOBILITY No data available. PERSISTENCE AND DEGRADABILITY This material is not expected to be readily biodegradable. The product has not been tested. The statement has been derived from the properties of the individual components. POTENTIAL TO BIOACCUMULATE Bioconcentration Factor: No data available. Octanol/Water Partition Coefficient: No data available SECTION 13 DISPOSAL CONSIDERATIONS Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by international, country, or local laws and regulations. SECTION 14 TRANSPORT INFORMATION The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. DOT Shipping Description: UN1268, PETROLEUM DISTILLATES, N.O.S., COMBUSTIBLE LIQUID, III NOTE: NON-BULK PACKAGES ARE NOT REGULATED IN THE U.S.A. SEE 49 CFR 173.150 (f) FOR SPECIAL PROVISIONS FOR VESSEL AND AIRCRAFT. _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 8 of 9 Techron Fuel Injector Cleaner SDS : 35580 IMO/IMDG Shipping Description: UN1268, PETROLEUM DISTILLATES, N.O.S. (STODDARD SOLVENT), 3, III, FLASH POINT SEE SECTION 5 OR 9, MARINE POLLUTANT (STODDARD SOLVENT) ICAO/IATA Shipping Description: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, MARINE POLLUTANT (STODDARD SOLVENT) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES 2. Delayed (Chronic) Health Effects: NO 3. Fire Hazard: YES 4. Sudden Release of Pressure Hazard: NO 5. Reactivity Hazard: NO REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 03=EPCRA 313 01-2A=IARC Group 2A 04=CA Proposition 65 01-2B=IARC Group 2B 05=MA RTK 02=NTP Carcinogen 06=NJ RTK 07=PA RTK The following components of this material are found on the regulatory lists indicated. 1,2,4-trimethylbenzene 03, 05, 06, 07 Distillates (petroleum), hydrotreated light 05, 06, 07 Stoddard solvent 05, 06, 07 CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada), EINECS (European Union), ENCS (Japan), KECI (Korea), PICCS (Philippines), TSCA (United States). NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL SECTION 16 OTHER INFORMATION NFPA RATINGS: Health: 1 Flammability: 2 Reactivity: 0 HMIS RATINGS: Health: 2 Flammability: 2 Reactivity: 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating _____________________________________________________________________ Revision Number: 2 Revision Date: AUGUST 11, 2014 9 of 9 Techron Fuel Injector Cleaner SDS : 35580 Association (for HMIS ratings). LABEL RECOMMENDATION: Label Category : FUEL ADDITIVE 3 - ADD3 REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16 Revision Date: AUGUST 11, 2014 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit GHS - Globally Harmonized System CAS - Chemical Abstract Service Number ACGIH - American Conference of Governmental Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods Code API - American Petroleum Institute SDS - Safety Data Sheet HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA) DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA) IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency SCBA - Self-Contained Breathing Apparatus Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001 Bollinger Canyon Road San Ramon, CA 94583. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.