Streak Proof Product Code: C0603, C2003 Page 1 of 10 SAFETY DATA SHEET Not classified. Physical hazards Health hazards Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. Mixtures CAS number %Chemical name Common name and synonyms 111-76-22-Butoxyethanol 2.5 - 10 67-63-0Isopropyl Alcohol 1 - 2.5 74-98-6Propane 1 - 2.5 7664-41-7Anhydrous Ammonia 90 - 100 0.1 - 1 Other components below reportable levels *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Inhalation If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle? Streak Proof? PRODUCT TYPE: Glass Cleaner PRODUCT CODE: C0603, C2003 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 (800) 876-0222 EMERGENCY (585) 275-3232 SECTION 2 HAZARDS IDENTIFICATION SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS SECTION 4 FIRST AID MEASURES Streak Proof Product Code: C0603, C2003 Page 2 of 10 In the unlikely event of swallowing contact a physician or poison control center. Direct contact with eyes may cause temporary irritation. Provide general supportive measures and treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Extremely flammable aerosol. Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.Environmental precautions Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). SECTION 5 FIRE FIGHTING MEASURES SECTION 6 ACCIDENTAL RELEASE MEASURES SECTION 7 HANDLING AND STORAGE Streak Proof Product Code: C0603, C2003 Page 3 of 10 Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 240 mg/m32-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 35 mg/m3Anhydrous Ammonia (CAS 7664-41-7) 50 ppm PEL 980 mg/m3Isopropyl Alcohol (CAS 67-63-0) 400 ppm PEL 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppm2-Butoxyethanol (CAS 111-76-2) STEL 35 ppmAnhydrous Ammonia (CAS 7664-41-7) TWA 25 ppm STEL 400 ppmIsopropyl Alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 24 mg/m32-Butoxyethanol (CAS 111-76-2) 5 ppm STEL 27 mg/m3Anhydrous Ammonia (CAS 7664-41-7) 35 ppm TWA 18 mg/m3 25 ppm STEL 1225 mg/m3Isopropyl Alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm TWA 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *2-Butoxyethanol (CAS 111-76-2) 40 mg/l Acetone Urine *Isopropyl Alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Streak Proof Product Code: C0603, C2003 Page 4 of 10 US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Appearance Physical state Liquid. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 195.27 ?F (90.7 ?C) estimated Flash point -245.2 ?F (-154.0 ?C) estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Flammability class Flammable IB estimated SECTION 9 PHYSICAL and CHEMICAL PROPERTIES Streak Proof Product Code: C0603, C2003 Page 5 of 10 Heat of combustion 3.29 kJ/g estimated Specific gravity 0.926 estimated The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products No hazardous decomposition products are known. Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Test ResultsComponents Species 2-Butoxyethanol (CAS 111-76-2) LD50 Guinea pig Dermal Acute 6411 mg/kg 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Mouse Inhalation 750 ppm, 7 Hours Rabbit 400 ppm, 7 Hours Rat 450 ppm, 4 Hours LD100 Rabbit Oral 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Mouse 1230 mg/kg Rat 530 - 2800 mg/kg Anhydrous Ammonia (CAS 7664-41-7) LC50 Mouse Inhalation Acute 4230 ppm, If <1L: Consumer Commodity Hours SECTION 10 STABILITY and REACTIVITY DATA SECTION 11 TOXICOLOGICAL INFORMATION Streak Proof Product Code: C0603, C2003 Page 6 of 10 Test ResultsComponents Species Rat 7939 mg/m3 4000 ppm, If <1L: Consumer Commodity Hours LD50 Rat Oral 350 mg/kg Isopropyl Alcohol (CAS 67-63-0) LD50 Rabbit Dermal Acute 16.4 ml/kg, 24 Hours LC50 Rat Inhalation > 10000 ppm, 6 Hours LD50 Rat Oral 5.84 g/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) This product is not expected to cause reproductive or developmental effects. Not classified. Not classified. Not available. Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. SECTION 12 ECOLOGICAL INFORMATION Streak Proof Product Code: C0603, C2003 Page 7 of 10 Components Test ResultsSpecies 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina) Anhydrous Ammonia (CAS 7664-41-7) Aquatic LC50Fish 0.43 - 0.47 mg/l, 96 hoursChinook salmon (Oncorhynchus tshawytscha) Isopropyl Alcohol (CAS 67-63-0) Aquatic IC50Algae 1000.0001 mg/L, 72 HoursAlgae EC50Crustacea 13299 mg/L, 48 HoursDaphnia * Estimates for product may be based on additional component data not shown. LC50Fish > 1400 mg/l, 96 hoursBluegill (Lepomis macrochirus) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Isopropyl Alcohol 0.05 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging DOT UN1950UN number Aerosols, flammable, (each not exceeding 1 L capacity)UN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. SECTION 13 DISPOSAL CONSIDERATIONS SECTION 14 TRANSPORT INFORMATION Streak Proof Product Code: C0603, C2003 Page 8 of 10 IATA UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Environmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only LTD QTYPackaging Exceptions IMDG UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Marine pollutant Environmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user LTD QTYPackaging Exceptions Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. SECTION 15 REGULATORY INFORMATION Streak Proof Product Code: C0603, C2003 Page 9 of 10 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Anhydrous Ammonia (CAS 7664-41-7) Listed. SARA 304 Emergency release notification Anhydrous Ammonia (CAS 7664-41-7) 100 LBS OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Anhydrous Ammonia 7664-41-7 100 500 lbs SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. Anhydrous Ammonia 7664-41-7 0.1 - 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Anhydrous Ammonia (CAS 7664-41-7) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Anhydrous Ammonia (CAS 7664-41-7) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Anhydrous Ammonia (CAS 7664-41-7) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Anhydrous Ammonia (CAS 7664-41-7) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. Rhode Island RTK Anhydrous Ammonia (CAS 7664-41-7) Isopropyl Alcohol (CAS 67-63-0) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) Streak Proof Product Code: C0603, C2003 Page 10 of 10 Country(s) or region Inventory name On inventory (yes/no)* YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). SECTION 16 OTHER INFORMATION Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 6/9/94 UPDATED: 8/23/16 PRODUCT #: C0603, C2003 Slide 1 Slide 2 Slide 3 Slide 4 Slide 5 Slide 6 Slide 7 Slide 8 Slide 9 Slide 10