Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 1111 of of of of 10101010 Safety Data Sheet Section 1 ? Identification of the Mixture and of the Company Product IdentificationProduct IdentificationProduct IdentificationProduct Identification Primary Identifier(s) Used on the LabelPrimary Identifier(s) Used on the LabelPrimary Identifier(s) Used on the LabelPrimary Identifier(s) Used on the Label Berryman B-12 CHEMTOOL GAS TREATMENT CARBURETOR CLEANER Berryman B-12 CHEMTOOL FUEL INJECTOR CLEANER Product Synonym(s)Product Synonym(s)Product Synonym(s)Product Synonym(s) blend ?3A-5M? Product Number(s)Product Number(s)Product Number(s)Product Number(s) 0112 and 1112 Relevant Identified Uses and Uses Advised AgainstRelevant Identified Uses and Uses Advised AgainstRelevant Identified Uses and Uses Advised AgainstRelevant Identified Uses and Uses Advised Against Recommended UsesRecommended UsesRecommended UsesRecommended Uses gasoline fuel additive Uses Advised AgainstUses Advised AgainstUses Advised AgainstUses Advised Against not for use in diesel fuels Manufacturer/Supplier DetailsManufacturer/Supplier DetailsManufacturer/Supplier DetailsManufacturer/Supplier Details Berryman Products, Inc. 3800 E Randol Mill Rd Arlington, TX 76011 (800) 433-1704 (USA/Canada) (817) 640-2376 (international) www.BerrymanProducts.com Emergency 24Emergency 24Emergency 24Emergency 24----Hour Telephone Number(s) Hour Telephone Number(s) Hour Telephone Number(s) Hour Telephone Number(s) ???? InfoTrac, Inc.InfoTrac, Inc.InfoTrac, Inc.InfoTrac, Inc. (800) 535-5053 (USA/Canada) (352) 323-3500 (international) Section 2 ? Hazards Identification Classification of the Substance or Mixture (29 CFR 1910.1200)Classification of the Substance or Mixture (29 CFR 1910.1200)Classification of the Substance or Mixture (29 CFR 1910.1200)Classification of the Substance or Mixture (29 CFR 1910.1200) Physical HazardsPhysical HazardsPhysical HazardsPhysical Hazards Flammable Liquid ? Category 2 Health HazardsHealth HazardsHealth HazardsHealth Hazards Skin Irritant ? Category 2 Eye Irritant ? Category 2A Carcinogen ? Category 2 Specific Target Organ Toxicity - Single Exposure ? Category 3 (respiratory tract irritant and narcotic effects) Aspiration Hazard ? Category 1 Environmental Hazard - Chronic ? Category 2 Allocation of Label ElementsAllocation of Label ElementsAllocation of Label ElementsAllocation of Label Elements Chemical IdentityChemical IdentityChemical IdentityChemical Identity Berryman B-12 CHEMTOOL GAS TREATMENT CARBURETOR CLEANER Berryman B-12 CHEMTOOL FUEL INJECTOR CLEANER PictogramsPictogramsPictogramsPictograms Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 2222 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Signal WordSignal WordSignal WordSignal Word DANGER Hazard StatementsHazard StatementsHazard StatementsHazard Statements H225 ? Highly flammable liquid and vapor. H304 ? May be fatal if swallowed and enters airways. H315 ? Causes skin irritation. H319 ? Causes serious eye irritation. H321 ? Specific treatment (see supplemental first aid instructions this label/document). H335 ? May cause respiratory irritation. H336 ? May cause drowsiness or dizziness. H351 ? Suspected of causing cancer. H411 ? Toxic to aquatic life with long-lasting effects. Prevention Precautionary StatementsPrevention Precautionary StatementsPrevention Precautionary StatementsPrevention Precautionary Statements P101 ? Keep out of reach of children. P102 ? Read label before use. P201 ? Obtain special instructions before use. P202 ? Do not handle until all safety precautions have been read and understood. P210 ? Keep away from heat, sparks, open flames, and hot surfaces. No smoking. P235 ? Keep cool. P240 ? Ground/bond container and receiving equipment. Special precautions may be necessary for non-conductive containers. P241 ? Use explosion-proof electrical, ventilation, and lighting equipment. P242 ? Use only non-sparking tools, such as brass or bronze. P243 ? Take precautionary measures against static discharge. P261 ? Avoid breathing fumes, gas, mist, vapor, or spray. P264 ? Wash thoroughly after handling. P271 ? Use only outdoors or in a well-ventilated area. P273 ? Avoid release to the environment. P280 ? Wear protective gloves, protective clothing, and eye or face protection. Response Precautionary StatementsResponse Precautionary StatementsResponse Precautionary StatementsResponse Precautionary Statements P312 ? Call POISON CONTROL CENTER, hospital emergency room, or doctor if you feel unwell. P321 ? Specific treatment available in this document in ?Section 4 ? First Aid Measures.? P331 ? Do NOT induce vomiting. P391 ? Collect spillage. P301/P310 ? IF SWALLOWED: Immediately call POISON CONTROL CENTER, hospital emergency room, or doctor. P303/P361/P353 ? IF ON SKIN (OR HAIR): Immediately take off all contaminated clothing. Rinse skin with soap or water or shower. P304/P340 ? IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305/P351/P338 ? IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308/P313 ? If exposed or concerned, get medical advice/attention. P332/P313 ? If skin irritation occurs, get medical advice/attention. P337/P313 ? If eye irritation persists, get medical advice/attention. P362/364 ? Take off contaminated clothing and launder before reuse. P370/P378 ? In case of fire, use water fog, dry chemical, alcohol-resistant foam, or carbon dioxide to extinguish. Storage Precautionary StatementsStorage Precautionary StatementsStorage Precautionary StatementsStorage Precautionary Statements P405 ? Store locked-up. P403/P233 ? Store in a well-ventilated place. Keep container tightly closed. Disposal Precautionary StatementsDisposal Precautionary StatementsDisposal Precautionary StatementsDisposal Precautionary Statements P501 ? Dispose of contents/container in accordance with local, regional, national, and international regulations, as applicable. Hazards Not Otherwise Hazards Not Otherwise Hazards Not Otherwise Hazards Not Otherwise ClassifiedClassifiedClassifiedClassified none known Ingredients of unknown acute toxicityIngredients of unknown acute toxicityIngredients of unknown acute toxicityIngredients of unknown acute toxicity none Section 3 ? Composition/Information on Ingredients ComponentComponentComponentComponent CAS RNCAS RNCAS RNCAS RN WeightWeightWeightWeight Xylenes (mixed isomers) 1330-20-7 40-50% Petroleum Distillates 64742-88-7 25-35% Ethylbenzene 100-41-4 10-12% n-Propanol 71-23-8 8-15% Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 3333 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Section 4 ? First Aid Measures Description of First Aid MeasuresDescription of First Aid MeasuresDescription of First Aid MeasuresDescription of First Aid Measures IngestionIngestionIngestionIngestion Immediately call poison control center, hospital emergency room, or doctor. Do NOT induce vomiting. Drink 1-2 glasses of milk or water. Eye ContactEye ContactEye ContactEye Contact Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Skin Skin Skin Skin ContactContactContactContact Immediately take off all contaminated clothing. Rinse skin with soap and water or shower. InhalationInhalationInhalationInhalation Remove person to fresh air and keep comfortable. If experiencing respiratory symptoms or if breathing is difficult, administer oxygen and call poison control center, hospital emergency room, or doctor. Most Important Symptoms and EffectsMost Important Symptoms and EffectsMost Important Symptoms and EffectsMost Important Symptoms and Effects Acute/ImmediateAcute/ImmediateAcute/ImmediateAcute/Immediate respiratory tract irritation; headache and lightheadedness; narcotic effects, including dizziness, drowsiness, and loss of coordination; nausea and vomiting DelayedDelayedDelayedDelayed drying, cracking, or defatting of the skin Indications of Need for Immediate Medical Attention and Specific Treatment RequiredIndications of Need for Immediate Medical Attention and Specific Treatment RequiredIndications of Need for Immediate Medical Attention and Specific Treatment RequiredIndications of Need for Immediate Medical Attention and Specific Treatment Required Indications of Need for Immediate Medical Attention Indications of Need for Immediate Medical Attention Indications of Need for Immediate Medical Attention Indications of Need for Immediate Medical Attention In the event of shortness of breath, difficulty breathing, or spontaneous vomiting, seek immediate medical attention. Specific Treatment and Notes to PhysicianSpecific Treatment and Notes to PhysicianSpecific Treatment and Notes to PhysicianSpecific Treatment and Notes to Physician If performing lavage, endotracheal and/or esophageal control is recommended. If spontaneous vomiting occurs, keep head below hips to avoid aspiration. Section 5 ? Firefighting Measures Fire Extinguishing MediaFire Extinguishing MediaFire Extinguishing MediaFire Extinguishing Media Support for CombustionSupport for CombustionSupport for CombustionSupport for Combustion Product supports combustion. Suitable Extinguishing MediaSuitable Extinguishing MediaSuitable Extinguishing MediaSuitable Extinguishing Media water fog, dry chemical, alcohol-resistant foam, or carbon dioxide Unsuitable Extinguishing MediaUnsuitable Extinguishing MediaUnsuitable Extinguishing MediaUnsuitable Extinguishing Media water jet/spray (may cause product to float to surface and reignite) Special Hazards/ConsiderationsSpecial Hazards/ConsiderationsSpecial Hazards/ConsiderationsSpecial Hazards/Considerations Combustion ProductsCombustion ProductsCombustion ProductsCombustion Products Combustion in the presence of air may yield hydrocarbons, organic oxygenates, amines, and oxides of carbon and nitrogen. Special Protective Equipment and Precautions for FirefightersSpecial Protective Equipment and Precautions for FirefightersSpecial Protective Equipment and Precautions for FirefightersSpecial Protective Equipment and Precautions for Firefighters Special Protective EquipmentSpecial Protective EquipmentSpecial Protective EquipmentSpecial Protective Equipment Firefighters should employ SCBA and full protective gear, including shield, as product may vent, rupture, or explode violently at elevated temperatures. Precautions and ProceduresPrecautions and ProceduresPrecautions and ProceduresPrecautions and Procedures Highly flammable liquid and vapor. Vapors heavier than air. Remove product from area if safe to do so. Use water spray to cool nearby containers. Additional InformationAdditional InformationAdditional InformationAdditional Information National Fire Protection National Fire Protection National Fire Protection National Fire Protection Association (NFPA)Association (NFPA)Association (NFPA)Association (NFPA) flammable liquid classification IB Section 6 ? Accidental Release Measures Personal and Environmental PrecautionsPersonal and Environmental PrecautionsPersonal and Environmental PrecautionsPersonal and Environmental Precautions Personal PrecautionsPersonal PrecautionsPersonal PrecautionsPersonal Precautions Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Take precautionary measures against static discharge. Ground/bond container and receiving equipment. Special precautions may be necessary for non-conductive containers. Use explosion-proof electrical, ventilation, and lighting equipment. Use only non-sparking tools, such as brass or bronze. Avoid breathing fumes, gas, mist, vapor, or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, and eye or face protection. Environmental PrecautionsEnvironmental PrecautionsEnvironmental PrecautionsEnvironmental Precautions Avoid release to the environment. Prevent contamination of ground water. Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 4444 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Materials and Methods for ContainmentMaterials and Methods for ContainmentMaterials and Methods for ContainmentMaterials and Methods for Containment Small SpillsSmall SpillsSmall SpillsSmall Spills Use socks/absorbent mini-booms or other inert barrier if necessary to contain small spills. Large SpillsLarge SpillsLarge SpillsLarge Spills Use large socks/absorbent booms or other inert barrier to form dam/dike in order to contain large spills and prevent further loss. Materials and Methods for CleanupMaterials and Methods for CleanupMaterials and Methods for CleanupMaterials and Methods for Cleanup Small SpillsSmall SpillsSmall SpillsSmall Spills Remove source from area if safe to do so. Use granular sorbent, gel sorbent, vermiculite, cat litter, dirt/earth, pads/rolls, or pillows to absorb spilled material. Other useful supplies may include a mop and mop bucket. Remediate affected area as necessary. Large SpillsLarge SpillsLarge SpillsLarge Spills Keep upwind from spill. Remove source from area if safe to do so. Use a mop and mop bucket or explosion-proof transfer equipment to recover spilled material. Use granular sorbent, gel sorbent, vermiculite, cat litter, dirt/earth, pads/rolls, or pillows to absorb residual material. Remediate affected area as necessary. Section 7 ? Handling and Storage Precautions for Safe HandlingPrecautions for Safe HandlingPrecautions for Safe HandlingPrecautions for Safe Handling Personal PrecautionsPersonal PrecautionsPersonal PrecautionsPersonal Precautions Do not handle until all safety precautions have been read and understood. Avoid breathing fumes, gas, mist, vapor, or spray. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, and eye or face protection. Wash thoroughly after handling. EnvEnvEnvEnvironmental Precautionsironmental Precautionsironmental Precautionsironmental Precautions Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Take precautionary measures against static discharge. Ground/bond container and receiving equipment. Special precautions may be necessary for non-conductive containers. Use explosion-proof electrical, ventilation, and lighting equipment. Use only non-sparking tools, such as brass or bronze. Avoid release to the environment. Conditions and Considerations for Safe StorageConditions and Considerations for Safe StorageConditions and Considerations for Safe StorageConditions and Considerations for Safe Storage Highly flammable liquid and vapor. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Keep out of reach of children. Store locked-up and in accordance with NFPA flammable liquid classification IB recommendations. Section 8 ? Exposure Controls/Personal Protection ComponentComponentComponentComponent CAS RNCAS RNCAS RNCAS RN OSHA PELOSHA PELOSHA PELOSHA PEL ACGIH TLVACGIH TLVACGIH TLVACGIH TLV Xylenes (mixed isomers) 1330-20-7 100 ppm 100 ppm Petroleum Distillates (Stoddard Solvent) 64742-88-7 500 ppm 500 ppm Ethylbenzene 100-41-4 100 ppm 100 ppm n-Propanol 71-23-8 100 ppm 100 ppm Exposure ControlsExposure ControlsExposure ControlsExposure Controls Appropriate Engineering ControlsAppropriate Engineering ControlsAppropriate Engineering ControlsAppropriate Engineering Controls If practical, use outside with adequate ventilation to minimize exposure. PPE OverviewPPE OverviewPPE OverviewPPE Overview Hand ProtectionHand ProtectionHand ProtectionHand Protection Use of chemical-resistant gloves (butyl rubber, EVAL, neoprene, nitrile/Buna-N, PVA, PVC, or Viton) is recommended. Eye ProtectionEye ProtectionEye ProtectionEye Protection Use of safety glasses with wrap-around lens or goggles is recommended. Respiratory ProtectionRespiratory ProtectionRespiratory ProtectionRespiratory Protection If necessary, use respiratory protection sufficient to reduce exposure to permissible limits. Additional ProtectionAdditional ProtectionAdditional ProtectionAdditional Protection For industrial settings, access to a chemical safety shower with eye wash station is strongly recommended. Section 9 ? Physical and Chemical Properties Information on Basic Physical and Chemical PropertiesInformation on Basic Physical and Chemical PropertiesInformation on Basic Physical and Chemical PropertiesInformation on Basic Physical and Chemical Properties Physical StatePhysical StatePhysical StatePhysical State liquid AppearanceAppearanceAppearanceAppearance clear, colorless OdorOdorOdorOdor mild, solvent Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 5555 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Odor ThresholdOdor ThresholdOdor ThresholdOdor Threshold 0.6 ppm pHpHpHpH not relevant Freezing PointFreezing PointFreezing PointFreezing Point < -15?F Boiling RangeBoiling RangeBoiling RangeBoiling Range 207 - 410?F Flash Point and MethodFlash Point and MethodFlash Point and MethodFlash Point and Method 70?F by closed-cup tester Explosion Limits in AirExplosion Limits in AirExplosion Limits in AirExplosion Limits in Air 1.0 - 7.6% by volume (composite) Evaporation RateEvaporation RateEvaporation RateEvaporation Rate 0.6 (n-Butyl Acetate=1.0) Vapor Pressure, as suppliedVapor Pressure, as suppliedVapor Pressure, as suppliedVapor Pressure, as supplied 5.8 mm of Hg at 68?F Vapor DensityVapor DensityVapor DensityVapor Density >1.0 Specific GravitySpecific GravitySpecific GravitySpecific Gravity 0.827 at 68?F DensityDensityDensityDensity 6.89 lb/gal at 68?F Water SolubilityWater SolubilityWater SolubilityWater Solubility not soluble nnnn----Octanol/Water Partition Coefficient (log POctanol/Water Partition Coefficient (log POctanol/Water Partition Coefficient (log POctanol/Water Partition Coefficient (log Powowowow)))) 3.5 (composite) ViscosityViscosityViscosityViscosity 1.0 cSt at 68?F VolatilityVolatilityVolatilityVolatility 95 - 99% by weight AutoAutoAutoAuto----ignition temperatureignition temperatureignition temperatureignition temperature 740?F (composite) Decomposition temperatureDecomposition temperatureDecomposition temperatureDecomposition temperature unknown Section 10 ? Stability and Reactivity Chemical Stability under Normal Conditions of UseChemical Stability under Normal Conditions of UseChemical Stability under Normal Conditions of UseChemical Stability under Normal Conditions of Use Chemical StabilityChemical StabilityChemical StabilityChemical Stability Stable under normal conditions of use. Conditions Affording InstabilityConditions Affording InstabilityConditions Affording InstabilityConditions Affording Instability none known ReactivityReactivityReactivityReactivity not expected Possibility of Hazardous ReactionsPossibility of Hazardous ReactionsPossibility of Hazardous ReactionsPossibility of Hazardous Reactions none known Conditions to AvoidConditions to AvoidConditions to AvoidConditions to Avoid Keep away from heat, sparks, open flames, and hot surfaces. No smoking. If practical, avoid temperatures exceeding flash point. Incompatible MaterialsIncompatible MaterialsIncompatible MaterialsIncompatible Materials strong acids; oxidizers; reducing agents Hazardous Decomposition ProductsHazardous Decomposition ProductsHazardous Decomposition ProductsHazardous Decomposition Products none known Section 11 ? Toxicological Information Likely Routes of ExposureLikely Routes of ExposureLikely Routes of ExposureLikely Routes of Exposure ingestion, skin contact, eye contact, inhalation Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 6666 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Symptoms Related to Physical, Chemical, and Toxicological CharacteristicsSymptoms Related to Physical, Chemical, and Toxicological CharacteristicsSymptoms Related to Physical, Chemical, and Toxicological CharacteristicsSymptoms Related to Physical, Chemical, and Toxicological Characteristics IngestionIngestionIngestionIngestion Large QuantityLarge QuantityLarge QuantityLarge Quantity gastrointestinal disturbances, including upset stomach, cramping, nausea, vomiting, and diarrhea Small Quantity/Incidental ContactSmall Quantity/Incidental ContactSmall Quantity/Incidental ContactSmall Quantity/Incidental Contact gastrointestinal disturbances, including upset stomach and cramping Skin ContactSkin ContactSkin ContactSkin Contact moderate irritation Eye ContactEye ContactEye ContactEye Contact blurred vision, severe eye irritation InhalationInhalationInhalationInhalation respiratory tract irritation; headache, lightheadedness; narcotic effects, including dizziness, drowsiness, and loss of coordination; nausea and vomiting Immediate, Immediate, Immediate, Immediate, Delayed, and Chronic Delayed, and Chronic Delayed, and Chronic Delayed, and Chronic EffectsEffectsEffectsEffects SSSSHORTHORTHORTHORT----TTTTERM ERM ERM ERM EEEEXPOSURXPOSURXPOSURXPOSUREEEE Potential Immediate EffectsPotential Immediate EffectsPotential Immediate EffectsPotential Immediate Effects IngestionIngestionIngestionIngestion drying, burning, or irritation of the mouth and throat, gastrointestinal disturbances, nausea and vomiting Skin ContactSkin ContactSkin ContactSkin Contact drying of the skin Eye ContactEye ContactEye ContactEye Contact blurred vision, temporary corneal damage InhalationInhalationInhalationInhalation shortness of breath or difficulty breathing, headache, dizziness, nausea and vomiting, drowsiness, fatigue, loss of consciousness, death Potential Delayed EffectsPotential Delayed EffectsPotential Delayed EffectsPotential Delayed Effects IngestionIngestionIngestionIngestion aspiration pneumonitis, cyanosis, coma, death Skin ContactSkin ContactSkin ContactSkin Contact defatting of the skin, drying and cracking of the skin, aggravation of pre-existing skin conditions Eye ContactEye ContactEye ContactEye Contact none known InhalationInhalationInhalationInhalation nausea and vomiting, fatigue, loss of consciousness LLLLONGONGONGONG----TTTTERM ERM ERM ERM EEEEXPOSURXPOSURXPOSURXPOSUREEEE Potential Immediate EffectsPotential Immediate EffectsPotential Immediate EffectsPotential Immediate Effects none known Potential Delayed EffectsPotential Delayed EffectsPotential Delayed EffectsPotential Delayed Effects none known Potential Chronic Health EffectsPotential Chronic Health EffectsPotential Chronic Health EffectsPotential Chronic Health Effects CarcinogenicityCarcinogenicityCarcinogenicityCarcinogenicity International Agency for Research on Cancer (IARC) Monographs International Agency for Research on Cancer (IARC) Monographs International Agency for Research on Cancer (IARC) Monographs International Agency for Research on Cancer (IARC) Monographs Group 2B ? Possible Human Carcinogen (Ethylbenzene) National Toxicology Program (NTP) Report on Carcinogens National Toxicology Program (NTP) Report on Carcinogens National Toxicology Program (NTP) Report on Carcinogens National Toxicology Program (NTP) Report on Carcinogens not listed Occupational SafeOccupational SafeOccupational SafeOccupational Safety & Health Administration (OSHA)ty & Health Administration (OSHA)ty & Health Administration (OSHA)ty & Health Administration (OSHA) not listed Mutagenicity / Genetic ToxicityMutagenicity / Genetic ToxicityMutagenicity / Genetic ToxicityMutagenicity / Genetic Toxicity not suspected of being a human mutagen / genetic toxicant TeratogenicityTeratogenicityTeratogenicityTeratogenicity not suspected of being a human teratogen Developmental EffectsDevelopmental EffectsDevelopmental EffectsDevelopmental Effects not suspected of being a developmental toxicant Fertility EffectsFertility EffectsFertility EffectsFertility Effects not suspected of being a reproductive/fertility toxicant Effects on LactationEffects on LactationEffects on LactationEffects on Lactation not suspected of affecting lactation SSSSPECIFIC PECIFIC PECIFIC PECIFIC TTTTARGET ARGET ARGET ARGET OOOORGANRGANRGANRGAN TTTTOXICITY OXICITY OXICITY OXICITY (STOT)(STOT)(STOT)(STOT) Single ExposureSingle ExposureSingle ExposureSingle Exposure central nervous system (narcotic effects); respiratory tract (irritation) Repeated ExposureRepeated ExposureRepeated ExposureRepeated Exposure none known Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 7777 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Numerical Measures of Acute ToxicityNumerical Measures of Acute ToxicityNumerical Measures of Acute ToxicityNumerical Measures of Acute Toxicity Oral (Rat)Oral (Rat)Oral (Rat)Oral (Rat) LD50: 3700 mg/kg (derived) Dermal (Rabbit)Dermal (Rabbit)Dermal (Rabbit)Dermal (Rabbit) LD50: 4250 mg/kg (derived) Inhalation (Rat)Inhalation (Rat)Inhalation (Rat)Inhalation (Rat) LC50: 23 mg/L (derived) Additional Toxicological InformationAdditional Toxicological InformationAdditional Toxicological InformationAdditional Toxicological Information Skin Irritation/Corrosion (Rabbit)Skin Irritation/Corrosion (Rabbit)Skin Irritation/Corrosion (Rabbit)Skin Irritation/Corrosion (Rabbit) skin irritant Serious Eye Damage/Irritation (Rabbit)Serious Eye Damage/Irritation (Rabbit)Serious Eye Damage/Irritation (Rabbit)Serious Eye Damage/Irritation (Rabbit) severe eye irritant Respiratory SensitizationRespiratory SensitizationRespiratory SensitizationRespiratory Sensitization does not cause respiratory sensitization Skin SensitizationSkin SensitizationSkin SensitizationSkin Sensitization does not cause skin sensitization Aspiration HazardAspiration HazardAspiration HazardAspiration Hazard known aspiration hazard Section 12 ? Ecological Information General Ecological Assessment/OverviewGeneral Ecological Assessment/OverviewGeneral Ecological Assessment/OverviewGeneral Ecological Assessment/Overview Toxic to aquatic life with long-lasting effects. Mobile in soils which may lead to contamination of groundwater. Aquatic ToxicityAquatic ToxicityAquatic ToxicityAquatic Toxicity Vertebrates (FishVertebrates (FishVertebrates (FishVertebrates (Fish)))) Acute ToxicityAcute ToxicityAcute ToxicityAcute Toxicity LC50: 7.3 mg/L (derived) Chronic ToxicityChronic ToxicityChronic ToxicityChronic Toxicity NOEC: not available Invertebrates (WaterInvertebrates (WaterInvertebrates (WaterInvertebrates (Water Flea)Flea)Flea)Flea) Acute ToxicityAcute ToxicityAcute ToxicityAcute Toxicity LC50: 1.5 mg/L (derived) Chronic ToxicityChronic ToxicityChronic ToxicityChronic Toxicity NOEC: not available Aquatic Plants (Freshwater Algae)Aquatic Plants (Freshwater Algae)Aquatic Plants (Freshwater Algae)Aquatic Plants (Freshwater Algae) Acute ToxicityAcute ToxicityAcute ToxicityAcute Toxicity EC50: 3.0 mg/L (derived) Chronic ToxicityChronic ToxicityChronic ToxicityChronic Toxicity NOEC: not available Terrestrial ToxicityTerrestrial ToxicityTerrestrial ToxicityTerrestrial Toxicity Invertebrate (Earthworm)Invertebrate (Earthworm)Invertebrate (Earthworm)Invertebrate (Earthworm) LC50: not available Persistence and DegradabilityPersistence and DegradabilityPersistence and DegradabilityPersistence and Degradability PersistencePersistencePersistencePersistence not expected to be persistent DegradabilityDegradabilityDegradabilityDegradability non-rapidly degradable Bioaccumulative PotentialBioaccumulative PotentialBioaccumulative PotentialBioaccumulative Potential Bioaccumulation Potential AssessmentBioaccumulation Potential AssessmentBioaccumulation Potential AssessmentBioaccumulation Potential Assessment does not bioaccumulate Bioaccumulation FactorBioaccumulation FactorBioaccumulation FactorBioaccumulation Factor 180 (Xylenes) Mobility in SoilsMobility in SoilsMobility in SoilsMobility in Soils Mobility in Soils AssessmentMobility in Soils AssessmentMobility in Soils AssessmentMobility in Soils Assessment mobile in soils?may contaminate groundwater Soil Organic Carbon/Water Partition Coefficient (log KSoil Organic Carbon/Water Partition Coefficient (log KSoil Organic Carbon/Water Partition Coefficient (log KSoil Organic Carbon/Water Partition Coefficient (log KOCOCOCOC)))) 4.5 (composite) Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 8888 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Results of PBT and vPvB AssessmentResults of PBT and vPvB AssessmentResults of PBT and vPvB AssessmentResults of PBT and vPvB Assessment not a persistent, bioaccumulative toxic chemical (PBT) not very persistent or very bioaccumulative (vPvB) Other Adverse EffectsOther Adverse EffectsOther Adverse EffectsOther Adverse Effects none known Section 13 ? Disposal Considerations General Assessment/OverviewGeneral Assessment/OverviewGeneral Assessment/OverviewGeneral Assessment/Overview Dispose of waste in accordance with all applicable regulations. Toxic to aquatic life with long-lasting effects?do not pour into waterways. Highly flammable liquid and vapor and aggressive solvents, which may dissolve PVC pipes and fittings?do not pour down drain. RCRA Hazardous Waste CodeRCRA Hazardous Waste CodeRCRA Hazardous Waste CodeRCRA Hazardous Waste Code(s) (40 CFR 261.20(s) (40 CFR 261.20(s) (40 CFR 261.20(s) (40 CFR 261.20----33)33)33)33) Based on this material as-supplied, used or unwanted product may be subject to RCRA regulations and classified as F003 ? spent non-halogenated solvent mixture containing acetone, methanol, and/or xylene Section 14 ? Transportation Information Transportation by Ground Transportation by Ground Transportation by Ground Transportation by Ground ???? US Department of TransportationUS Department of TransportationUS Department of TransportationUS Department of Transportation Shipping DescriptionShipping DescriptionShipping DescriptionShipping Description UN1993, Flammable Liquids, n.o.s., (contains Xyenes, Ethylbenzene, and n-Propanol), 3, PG II Exemption EligibilityExemption EligibilityExemption EligibilityExemption Eligibility When shipped by ground, this product may be eligible for a ?Limited Quantity? exception per ?49 CFR 173.150. Transportation by Air Transportation by Air Transportation by Air Transportation by Air ???? ICAO/IATAICAO/IATAICAO/IATAICAO/IATA Shipping DescriptionShipping DescriptionShipping DescriptionShipping Description UN1993, Flammable Liquids, n.o.s., (contains Xyenes, Ethylbenzene, and n-Propanol), 3, PG II Exemption EligibilityExemption EligibilityExemption EligibilityExemption Eligibility When shipped by air, this product may be eligible for a ?Limited Quantity? exception. Transportation by Water Transportation by Water Transportation by Water Transportation by Water ???? IMO/IMDGIMO/IMDGIMO/IMDGIMO/IMDG Shipping DescriptionShipping DescriptionShipping DescriptionShipping Description UN1993, Flammable Liquids, n.o.s., (contains Xyenes, Ethylbenzene, and n-Propanol), 3, PG II Exemption EligibilityExemption EligibilityExemption EligibilityExemption Eligibility When shipped by water, this product may be eligible for a ?Limited Quantity? exception. Section 15 ? Regulatory Information Safety, Health, and Environmental Regulations/LegislationSafety, Health, and Environmental Regulations/LegislationSafety, Health, and Environmental Regulations/LegislationSafety, Health, and Environmental Regulations/Legislation UUUUNITED NITED NITED NITED SSSSTATES TATES TATES TATES ???? SSSSELECTELECTELECTELECT FFFFEDERAL EDERAL EDERAL EDERAL RRRREGULATIONSEGULATIONSEGULATIONSEGULATIONS Environmental Protection Agency (EPA)Environmental Protection Agency (EPA)Environmental Protection Agency (EPA)Environmental Protection Agency (EPA) Toxic Substances Control Act (TSCA) (15 USC 2601, et seq.)Toxic Substances Control Act (TSCA) (15 USC 2601, et seq.)Toxic Substances Control Act (TSCA) (15 USC 2601, et seq.)Toxic Substances Control Act (TSCA) (15 USC 2601, et seq.) All chemicals known to be present in this product are either listed on the TSCA inventory or are not required to be. SARA Title III (42 USC 9601, et seq.)SARA Title III (42 USC 9601, et seq.)SARA Title III (42 USC 9601, et seq.)SARA Title III (42 USC 9601, et seq.) Section 302 Section 302 Section 302 Section 302 ???? Extremely Hazardous Extremely Hazardous Extremely Hazardous Extremely Hazardous Substances (40 CFR 355)Substances (40 CFR 355)Substances (40 CFR 355)Substances (40 CFR 355) none Section 304 Section 304 Section 304 Section 304 ???? Emergency Release Notification (40 CFR 302.4)Emergency Release Notification (40 CFR 302.4)Emergency Release Notification (40 CFR 302.4)Emergency Release Notification (40 CFR 302.4) Xylenes, Ethylbenzene Section 311/312 Section 311/312 Section 311/312 Section 311/312 ???? Hazard Categorization (40 CFR 370.40)Hazard Categorization (40 CFR 370.40)Hazard Categorization (40 CFR 370.40)Hazard Categorization (40 CFR 370.40) acute toxicity, chronic toxicity, fire hazard Section 313 Section 313 Section 313 Section 313 ???? Toxic Chemicals (40 CFR 372.6Toxic Chemicals (40 CFR 372.6Toxic Chemicals (40 CFR 372.6Toxic Chemicals (40 CFR 372.65)5)5)5) Xylenes, Ethylbenzene Clean Air Act (42 USC chClean Air Act (42 USC chClean Air Act (42 USC chClean Air Act (42 USC ch. . . . 85 ?85 ?85 ?85 ??7401740174017401,,,, et seq.et seq.et seq.et seq.)))) Section 112 Section 112 Section 112 Section 112 ???? Hazardous Air PollutantsHazardous Air PollutantsHazardous Air PollutantsHazardous Air Pollutants Xylenes, Ethylbenzene Regulation of Fuels and Fuel AdditivesRegulation of Fuels and Fuel AdditivesRegulation of Fuels and Fuel AdditivesRegulation of Fuels and Fuel Additives This product complies with the requirements of ?40 CFR 80 and must be used in a manner consistent with the directions on the product label. Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 9999 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Occupational Safety & Health Administration (OSHA)Occupational Safety & Health Administration (OSHA)Occupational Safety & Health Administration (OSHA)Occupational Safety & Health Administration (OSHA) Hazard Communication StandardHazard Communication StandardHazard Communication StandardHazard Communication Standard This safety data sheet (SDS) is provided for compliance with applicable regulations of the Hazard Communication Standard of 2012 (HCS/HAZCOM 2012) found in ?29 CFR 1910.1200. Federal law requires persons receiving this document to study it carefully, become aware of the hazards of this product, and notify all employees, visitors, agents, and contractors of the information contained herein. Consumer Product Safety CommissionConsumer Product Safety CommissionConsumer Product Safety CommissionConsumer Product Safety Commission Federal Hazardous Substances ActFederal Hazardous Substances ActFederal Hazardous Substances ActFederal Hazardous Substances Act This product is regulated under the Federal Hazardous Substances Act, is subject to the labeling requirements of 16 CFR 1500, and must include at minimum the following cautionary statements: DANGER: Flammable. Harmful or fatal if swallowed. Vapor harmful. Eye and skin irritant. Keep out of the reach of children. UUUUNITED NITED NITED NITED SSSSTATES TATES TATES TATES ???? SSSSELECTELECTELECTELECT RRRREGIONAL EGIONAL EGIONAL EGIONAL CCCCONSIDERATIONSONSIDERATIONSONSIDERATIONSONSIDERATIONS Ozone Transport Commission (OTC) Ozone Transport Commission (OTC) Ozone Transport Commission (OTC) Ozone Transport Commission (OTC) ???? Model Rule VOC Limit and CategoryModel Rule VOC Limit and CategoryModel Rule VOC Limit and CategoryModel Rule VOC Limit and Category not regulated as a fuel additive Lake Michigan Air Directors Consortium (LADCO) Lake Michigan Air Directors Consortium (LADCO) Lake Michigan Air Directors Consortium (LADCO) Lake Michigan Air Directors Consortium (LADCO) ???? Model Rule VOC Limit and CategoryModel Rule VOC Limit and CategoryModel Rule VOC Limit and CategoryModel Rule VOC Limit and Category not regulated as a fuel additive UUUUNITED NITED NITED NITED SSSSTATES TATES TATES TATES ???? SSSSELECTELECTELECTELECT SSSSTATE TATE TATE TATE RRRREGULATIONSEGULATIONSEGULATIONSEGULATIONS CaliforniaCaliforniaCaliforniaCalifornia Office of Environmental Health Hazard Assessment (OEHHA)Office of Environmental Health Hazard Assessment (OEHHA)Office of Environmental Health Hazard Assessment (OEHHA)Office of Environmental Health Hazard Assessment (OEHHA) Proposition 65 Proposition 65 Proposition 65 Proposition 65 ???? Safe Drinking Water and Toxic Enforcement Act of 1986Safe Drinking Water and Toxic Enforcement Act of 1986Safe Drinking Water and Toxic Enforcement Act of 1986Safe Drinking Water and Toxic Enforcement Act of 1986 This product is subject to the labeling requirements of Proposition 65 ? Safe Drinking Water and Toxic Enforcement Act of 1986 and must bear the cautionary statement: WARNING! This product contains a chemical known to the State of California to cause cancer. Air Resources Board (ARB/CARB)Air Resources Board (ARB/CARB)Air Resources Board (ARB/CARB)Air Resources Board (ARB/CARB) Regulation for Reducing Emissions from Consumer Products Regulation for Reducing Emissions from Consumer Products Regulation for Reducing Emissions from Consumer Products Regulation for Reducing Emissions from Consumer Products ???? VOCVOCVOCVOC Limit and CategoryLimit and CategoryLimit and CategoryLimit and Category not regulated as a fuel additive MassachusettsMassachusettsMassachusettsMassachusetts ?R?R?R?Rightightightight----totototo----KnowKnowKnowKnow? ? ? ? Legislation Legislation Legislation Legislation ???? Substance List (105 CMR 670.000)Substance List (105 CMR 670.000)Substance List (105 CMR 670.000)Substance List (105 CMR 670.000) Xylene, Ethylbenzene, n-Propanol New JerseyNew JerseyNew JerseyNew Jersey ?R?R?R?Rightightightight----totototo----KnowKnowKnowKnow? ? ? ? Legislation Legislation Legislation Legislation ???? Hazardous Substance List (34:5AHazardous Substance List (34:5AHazardous Substance List (34:5AHazardous Substance List (34:5A----1111,,,, et seq.)et seq.)et seq.)et seq.) Xylenes, Ethylbenzene, n-Propanol PennsylvaniaPennsylvaniaPennsylvaniaPennsylvania ?R?R?R?Rightightightight----totototo----KnowKnowKnowKnow? ? ? ? Legislation Legislation Legislation Legislation ???? Hazardous Substance List (Chapter 323)Hazardous Substance List (Chapter 323)Hazardous Substance List (Chapter 323)Hazardous Substance List (Chapter 323) Dimethylbenzene, Ethylbenzene, 1-Propanol IIIINTERNATIONAL NTERNATIONAL NTERNATIONAL NTERNATIONAL ???? SSSSELECTELECTELECTELECT RRRREGULATIONSEGULATIONSEGULATIONSEGULATIONS CanadaCanadaCanadaCanada Environment Canada Environment Canada Environment Canada Environment Canada ???? Domestic Substances List (DSL)Domestic Substances List (DSL)Domestic Substances List (DSL)Domestic Substances List (DSL) All chemicals known to be present in this product are listed on the DSL. ChinaChinaChinaChina Ministry of Environmental Protection Ministry of Environmental Protection Ministry of Environmental Protection Ministry of Environmental Protection ???? Inventory of Existing Chemical Substances Produced or Imported in China (IECSC)Inventory of Existing Chemical Substances Produced or Imported in China (IECSC)Inventory of Existing Chemical Substances Produced or Imported in China (IECSC)Inventory of Existing Chemical Substances Produced or Imported in China (IECSC) All chemicals known to be present in this product are listed on the IECSC. European UnionEuropean UnionEuropean UnionEuropean Union European Chemical Agency European Chemical Agency European Chemical Agency European Chemical Agency ???? European Inventory of Existing Chemical Substances (EINECS)European Inventory of Existing Chemical Substances (EINECS)European Inventory of Existing Chemical Substances (EINECS)European Inventory of Existing Chemical Substances (EINECS) All chemicals known to be present in this product are listed on the EINECS. Chemical Safety AssessmentChemical Safety AssessmentChemical Safety AssessmentChemical Safety Assessment has not been conducted on product, as-supplied Section 16 ? Other Information Hazardous Materials Information System (HMIS)Hazardous Materials Information System (HMIS)Hazardous Materials Information System (HMIS)Hazardous Materials Information System (HMIS) HealthHealthHealthHealth 2222 FlammabilityFlammabilityFlammabilityFlammability 3333 ReactivityReactivityReactivityReactivity 0000 Protective EquipmentProtective EquipmentProtective EquipmentProtective Equipment BBBB Hazard IndexHazard IndexHazard IndexHazard Index Least Least Least Least ---- 0000 SlightSlightSlightSlight ---- 1111 ModerateModerateModerateModerate ---- 2222 HighHighHighHigh ---- 3333 ExtremeExtremeExtremeExtreme ---- 4444 Safety Data Sheet Safety Data Sheet Safety Data Sheet Safety Data Sheet ???? Page Page Page Page 10101010 of of of of 10101010 Berryman Products, Berryman Products, Berryman Products, Berryman Products, Inc. Inc. Inc. Inc. ???? part part part part #s #s #s #s 0112 0112 0112 0112 and and and and 1112111211121112 Index of AbbreviationsIndex of AbbreviationsIndex of AbbreviationsIndex of Abbreviations ACGIH ? American Council of Governmental and Industrial Hygienists CAS RN ? Chemical Abstracts Service Registry Number EC50 ? Median Effective Concentration IATA ? International Air Transport Association ICAO ? International Civil Aviation Organization IMDG ? International Maritime Dangerous Goods IMO ? International Maritime Organization LC50 ? Median Lethal Concentration LD50 ? Median Lethal Dose N/A ? Not Applicable NE ? Not Established NOEC ? No Observable Exposure Concentration PEL ? Permissible Exposure Limit (as required by OSHA) TLV ? Threshold Limit Value (as recommended by ACGIH) VOC ? Volatile Organic Compound Relevant Dates and ApplicabilityRelevant Dates and ApplicabilityRelevant Dates and ApplicabilityRelevant Dates and Applicability Date of IssuanceDate of IssuanceDate of IssuanceDate of Issuance May 28, 2015 Date of Previous RevisionDate of Previous RevisionDate of Previous RevisionDate of Previous Revision not applicable?initial Safety Data Sheet Primary Revision Change(s)Primary Revision Change(s)Primary Revision Change(s)Primary Revision Change(s) not applicable Document ApplicabilityDocument ApplicabilityDocument ApplicabilityDocument Applicability This safety data sheet only applies to part numbers 0112 and 1112 manufactured on or after January 1, 2015. Document AuthorDocument AuthorDocument AuthorDocument Author Dan Nowlan Legal DisclaimerLegal DisclaimerLegal DisclaimerLegal Disclaimer The information contained in this document is, to the best of Berryman Products, Inc.?s knowledge, complete and accurate but is not warranted. All materials may present unknown hazards and should be used with caution. It is the responsibility of the user to evaluate the information in a prudent manner and to use it in a manner consistent with its intended purpose. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances.