PS?HTR?ST?43?E_Lead?Acid?Battery? SDS?US? 1?of?11?Version?#:?05? Issue?Date:?04/01/2015? Revision?Date:?03/16/2017? ? ? ? ? ?1.?IDENTIFICATION? ? ? Product?Name:?Lead?Acid?Battery? Synonyms:?SLI?Battery? Product?Use:?Vehicle?Electrical?System? Manufacturer/Supplier:?Walmart?Inc.? Address: 702 SW 8th Street, Bentonville, AR 72716? 888?405?3513? ?Part?#:?W36R?650,?W56?590? Emergency?number:?INFOTRAC: 1-800-535-505? ? NOTE:?The?Johnson?Controls?sealed?cell/battery?is?considered?an?article?as?defined?by?29?CFR?1910.1200?(OSHA?Hazard? Communication?Standard).?The?information?contained?in?this?SDS?is?supplied?at?the?customer?s?request?for? information?only.? ? ?2.?HAZARD(S)?IDENTIFICATION? ? ? Health? Environmental? Physical? Acute?Toxicity?(Oral,?dermal,? inhalation)? Category?4? Aquatic?Chronic?1? Aquatic?Acute?1? Explosive?Chemical,?Division?1.3? Skin?corrosion/irritation? Category?1A? Eye?Damage? Category?1? Reproductive? Category?1A? Carcinogenicity?(lead)? Category?1B? Carcinogenicity?(acid?mist)? Category?1A? Specific?target?organ?toxicity? (repeated?exposure)? Category?2? ? Label?Elements:? Health? Environmental? Physical? ? ? ? ? ? ? Hazard?Statements? DANGER!? Causes?severe?skin?burns?and?eye?damage.?Causes? serious?eye?damage.? May?damage?fertility?or?the?unborn?child?if? ingested?or?inhaled.? May?cause?cancer?if?ingested?or?inhaled.? Causes?damage?to?central?nervous?system,?blood? and?kidneys?through?prolonged?or?repeated? exposure.? Precautionary?Statements? Wash?thoroughly?after?handling.? Do?not?eat,?drink?or?smoke?when?using?this?product.? Wear?protective?gloves/protective?clothing,?eye?protection/face?protection.? Avoid?breathing?dust/fume/gas/mist/vapors/spray.? Use?only?outdoors?or?in?a?well?ventilated?area.? Causes?skin?irritation,?serious?eye?damage.? Contact?with?internal?components?may?cause?irritation?or?severe?burns.?Avoid? contact?with?internal?acid.? Irritating?to?eyes,?respiratory?system,?and?skin.? EVERSTART?MAXX,?PLATINUM,?PLUS?&?VALUE?BATTERY? SDS PS?HTR?ST?43?E_Lead?Acid?Battery? SDS?US? 2?of?11?Version?#:?05? Issue?Date:?04/01/2015? Revision?Date:?03/16/2017? ? May?form?explosive?air/gas?mixture?during? charging.? Extremely?flammable?gas?(hydrogen).? Explosive,?fire,?blast?or?projection?hazard.? 3.?COMPOSITION?/?INFORMATION?ON?INGREDIENTS? ? INGREDIENTS?(Chemical/Common?Names):? CAS?No.:? %?by?Wt:? Lead? 7439?92?1? 34? Lead?Oxide? 1309?60?0? 31? Sulfuric?Acid? 7664?93?9? 34? Lead?Sulfate? 7446?14?2? <1? ? Composition?Comments? All?concentrations?are?in?percent?by?weight.? ? ?4.?FIRST?AID?MEASURES? ? ? Note:?Under?normal?conditions?of?battery?use,?internal?components?will?not?present?a?health?hazard.?The?following?information? is?provided?for?battery?electrolyte?(acid)?and?lead?for?exposures?that?may?occur?during?battery?production?or?container? breakage?or?under?extreme?heat?conditions?such?as?fire.? Inhalation? Sulfuric?Acid:?Remove?to?fresh?air?immediately.?If?not?breathing,?give?artificial?respiration.?If?breathing?is? difficult,?give?oxygen.?Consult?a?physician.? Lead:?Remove?from?exposure,?gargle,?wash?nose?and?lips;?consult?physician.? Skin?contact? Sulfuric?Acid:?Flush?with?large?amounts?of?water?for?at?least?15?minutes;?remove?contaminated?clothing? completely,?including?shoes.?If?symptoms?persist,?seek?medical?attention.?Wash?contaminated?clothing? before?reuse.?Discard?contaminated?shoes.? Lead:?Wash?immediately?with?soap?and?water.? Eye?contact? Sulfuric?Acid?and?Lead:?Flush?immediately?with?large?amounts?of?water?for?at?least?15?minutes?while?lifting? lids;?Seek?immediate?medical?attention?if?eyes?have?been?exposed?directly?to?acid.? Ingestion? Sulfuric?Acid:?Give?large?quantities?of?water;?Do?NOT?induce?vomiting?or?aspiration?into?the?lungs?may? occur?and?can?cause?permanent?injury?or?death;?consult?physician.? Lead:?Consult?physician?immediately.? ? ?5.?FIRE?FIGHTING?MEASURES? ? ? Flash?Point? Not?applicable?unless?individual?components?exposed.? Auto?ignition? Temperature? No?data?available.? Flammable?Limits? LEL?=?4.1%?(Hydrogen?Gas?in?air)?;?UEL?=?74.2%? Extinguishing? Media? CO2;?foam;?dry?chemical.?Do?not?use?carbon?dioxide?directly?on?cells.?Avoid?breathing?vapors.?Use? appropriate?media?for?surrounding?fire.? Special?Fire?Fighting? Procedures? Use?positive?pressure,?self?contained?breathing?apparatus.?Beware?of?acid?splatter?during?water? application?and?wear?acid?resistant?clothing,?gloves,?face?and?eye?protection.?If?batteries?are?on?charge,? shut?off?power?to?the?charging?equipment,?but?note?that?strings?of?series?connected?batteries?may?still? pose?risk?of?electric?shock?even?when?charging?equipment?is?shut?down.? Unusual?Fire?and? Explosion?Hazard? Highly?flammable?hydrogen?gas?is?generated?during?charging?and?operation?of?batteries.?If?ignited?by? burning?cigarette,?naked?flame?or?spark,?may?cause?battery?explosion?with?dispersion?of?casing?fragments? and?corrosive?liquid?electrolyte.?Carefully?follow?manufacturer's?instructions?for?installation?and?service.? Keep?away?all?sources?of?gas?ignition?and?do?not?allow?metallic?articles?to?simultaneously?contact?the? negative?and?positive?terminals?of?a?battery.?Follow?manufacturer's?instructions?for?installation?and? service.? PS?HTR?ST?43?E_Lead?Acid?Battery? SDS?US? 3?of?11?Version?#:?05? Issue?Date:?04/01/2015? Revision?Date:?03/16/2017? ? ?6:?ACCIDENTAL?RELEASE?MEASURES? ? ? Protective? Measures?to?be? Taken?if?Material?is? Released?or?Spilled? Stop?flow?of?material,?contain/absorb?small?spills?with?dry?sand,?earth,?and?vermiculite.?Do?not?use? combustible?materials.?If?possible,?carefully?neutralize?spilled?electrolyte?with?soda?ash,?sodium? bicarbonate,?lime,?etc.?Wear?acid?resistant?clothing,?boots,?gloves,?and?face?shield.?Do?not?allow?discharge? of?un?neutralized?acid?to?sewer.?Acid?must?be?managed?in?accordance?with?approved?local,?state,?and? federal?requirements.?Consult?state?environmental?agency?and/or?federal?EPA.? Waste?Disposal? Method? Dispose?of?as?a?hazardous?waste.?Dispose?of?in?accordance?with?applicable?local,?state?and?federal? regulations.? ? ?7.?HANDLING?AND?STORAGE? ? ? Handling? Unless?involved?in?recycling?operations,?do?not?breach?the?casing?or?empty?the?contents?of?the?battery.? Handle?carefully?and?avoid?tipping,?which?may?allow?electrolyte?leakage.?There?may?be?increasing?risk?of? electric?shock?from?strings?of?connected?batteries.?Keep?containers?tightly?closed?when?not?in?use.?If? battery?case?is?broken,?avoid?contact?with?internal?components.?Keep?vent?caps?on?and?cover?terminals?to? prevent?short?circuits.?Place?cardboard?between?layers?of?stacked?automotive?batteries?to?avoid?damage? and?short?circuits.?Keep?away?from?combustible?materials,?organic?chemicals,?reducing?substances,? metals,?strong?oxidizers?and?water.?Use?banding?or?stretch?wrap?to?secure?items?for?shipping.? Storage? Store?batteries?under?roof?in?cool,?dry,?well?ventilated?areas?separated?from?incompatible?materials?and? from?activities?that?may?create?flames,?spark,?or?heat.?Store?on?smooth,?impervious?surfaces?provided?with? measures?for?liquid?containment?in?the?event?of?electrolyte?spills.?Keep?away?from?metallic?objects?that? could?bridge?the?terminals?on?a?battery?and?create?a?dangerous?short?circuit.?Room?ventilation?is?required? for?batteries?utilized?for?standby?power?generation.?Never?recharge?batteries?in?an?unventilated,?enclosed? space.? Charging:? There?is?a?possible?risk?of?electric?shock?from?charging?equipment?and?from?strings?of?series?connected? batteries,?whether?or?not?being?charged.?Shut?off?power?to?chargers?whenever?not?in?use?and?before? detachment?of?any?circuit?connections.?Batteries?being?charged?will?generate?and?release?flammable? hydrogen?gas.?Charging?space?should?be?ventilated.?Keep?battery?vent?caps?in?position.?Prohibit?smoking? and?avoid?creation?of?flames?and?sparks?nearby.?Wear?face?and?eye?protection?when?near?batteries?being? charged.? Other? Follow?Manufacturers?Recommendations?regarding?maximum?recommended?currents?and?operating? temperature?range.?Do?not?overcharge?beyond?the?recommended?upper?charging?voltage?limit.?Applying? pressure?or?deforming?the?battery?may?lead?to?disassembly?followed?by?eye,?skin?and?throat?irritation.? ? ?8.?EXPOSURE?CONTROLS?/?PERSONAL?PROTECTION? ? ? Occupational?exposure?limits? US?OSHA?Specifically?Regulated?Substances?(29?CFR?1910.1001???1050)? Ingredient? CAS?Number? Type? Value? Lead? 7439?92?1? TWA? 0.05?mg/m?? Lead?Oxide? 1309?60?0? TWA? 0.05?mg/m?? Lead?Sulfate? 7446?14?2? TWA? 0.05?mg/m?? ? US?OSHA?Table?Z?1?Limits?for?Air?Contaminants?(?29CFR?1910.1000)? Ingredient? CAS?Number? Type? Value? Sulfuric?Acid? 7664?93?9? PEL? 1?mg/m?? ? US?ACGIH?Threshold?Limit?Values? Ingredient? CAS?Number? Type? Value? Form? Lead? 7439?92?1? TWA? 0.05?mg/m?? Lead?Oxide? 1309?60?0? TWA? 0.05?mg/m?? Lead?Sulfate? 7446?14?2? TWA? 0.05?mg/m?? Sulfuric?Acid? 7664?93?9? TWA? 0.2?mg/m?? Thoracic?Fractions? PS?HTR?ST?43?E_Lead?Acid?Battery? SDS?US? 4?of?11?Version?#:?05? Issue?Date:?04/01/2015? Revision?Date:?03/16/2017?? US?NIOSH:?Pocket?Guide?to?Chemical?Hazards? Ingredient? CAS?Number? Type? Value? Lead? 7439?92?1? TWA? 0.05?mg/m?? Lead?Oxide? 1309?60?0? TWA? 0.05?mg/m?? Sulfuric?Acid? 7664?93?9? TWA? 1?mg/m?? ? International?Exposure?Limits?(mg/m3)? *Chemical?&?Common?Name? Quebec?PEV? Ontario?OEL? EU?OEL? Lead?and?Lead?Compounds?(inorganic)? 0.05? 0.05? 0.15?(a)? Electrolyte?(H2SO4/H2O)? 1? 0.2? 0.05?(b)? (a)?As?inhalable?aerosol?(b)?Thoracic?fraction? ? Biological?limit?values? ACGIH?Biological?Exposure?Indices? Ingredient? Value? Determinant? Specimen? Sampling?Time? Lead? 300??g/l? Lead? Blood? *? Lead?Oxide? 300??g/l? Lead? Blood? *? Lead?Sulfate? 300??g/l? Lead? Blood? *? *???For?Sampling?details?please?see?the?source?document.? ? Engineering?Controls?(Ventilation):? Store?and?handle?in?well?ventilated?area.?If?mechanical?ventilation?is?used,?components?must?be?acid?resistant.?Handle?batteries? cautiously,?do?not?tip?to?avoid?spills.?Make?certain?vent?caps?are?on?securely.?If?battery?case?is?damaged,?avoid?bodily?contact?with? internal?components.?Wear?protective?clothing,?eye?and?face?protection,?when?filling,?charging,?or?handling?batteries.?Do?not?allow? metallic?materials?to?simultaneously?contact?both?the?positive?and?negative?terminals?of?the?batteries.?Charge?batteries?in?areas?with? adequate?ventilation.?General?dilution?ventilation?is?acceptable.? ? Respiratory?Protection?(NIOSH/MSHA?approved):? NONE?REQUIRED?FOR?NORMAL?HANDLING?OF?THE?FINISHED?PRODUCT.? When?concentrations?of?sulfuric?acid?mist?are?known?to?exceed?PEL,?use?NIOSH?or?MSHA?approved?respiratory?protection.? ? Skin?Protection:? NONE?REQUIRED?FOR?NORMAL?HANDLING?OF?THE?FINISHED?PRODUCT.? If?battery?case?is?damaged,?use?rubber?or?plastic?acid?resistant?gloves?with?elbow?length?gauntlet,?acid?resistant?apron,?clothing?and? boots.? ? Eye?Protection:? NONE?REQUIRED?FOR?NORMAL?HANDLING?OF?THE?FINISHED?PRODUCT.? If?necessary?to?handle?damage?product?where?exposure?to?the?organic?electrolyte?is?a?possibility,?chemical?splash?goggles?and?a?face? shield?are?recommended.? ? Other?Protection:? In?areas?where?water?and?sulfuric?acid?solutions?are?handled?in?concentrations?greater?than?1%,?emergency?eyewash?stations?and? showers?should?be?provided,?with?unlimited?water?supply.?Chemically?impervious?apron?and?face?shield?recommended?when?adding? water?or?electrolyte?to?batteries.?Wash?Hands?after?handling.? ? ?9.?PHYSICAL?AND?CHEMICAL?PROPERTIES? ? ? Appearance?and?Odor? Manufactured?article;?no?apparent?odor.?Electrolyte?is?a?clear?liquid?with?a?sharp,?penetrating,? pungent?odor.? Odor?Threshold? Not?applicable.? pH? Not?applicable? Boiling?Point? Not?applicable?unless?individual?components?exposed.? PS?HTR?ST?43?E_Lead?Acid?Battery? SDS?US? 5?of?11?Version?#:?05? Issue?Date:?04/01/2015? Revision?Date:?03/16/2017?? Battery?Electrolyte?(Acid)???230???233.6??F?(110???112??C)? Lead???3191??F?(1755??C)? Melting?Point? Lead???621.32??F?(327.4??C)? Specific?Gravity? (H2O?=?1)? 1.215?to?1.350? Flash?Point? 498.2??F?(259.0??C)?Hydrogen? Evaporation?Rate? (Butyl?Acetate?=?1)?