Safety Data Sheet Issue Date: 15-Aug-2018 Revision Date: 6-Jan-20 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product identifier Product Name SPLASH Concentrate 55 Gallon Drum Other means of identification SDS/PART # 234755 UN/ID No UN1230 Recommended use of the chemical and restrictions on use Recommended Use Windshield washer fluid Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear colorless Physical state Liquid Odor Very, slight alcohol smell Classification Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Vapors) Category 3 Acute toxicity - Inhalation (Dusts/Mists) Category 3 Specific target organ toxicity (single exposure) Category 1 Flammable Liquids Category 2 Signal Word Danger Hazard statements Toxic if swallowed Toxic in contact with skin Toxic if inhaled Causes damage to organs Highly flammable liquid and vapor SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF exposed: Call a POISON CENTER or doctor IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower Wash contaminated clothing before reuse Call a POISON CENTER or doctor if you feel unwell IF INHALED: Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER or doctor IF SWALLOWED: Immediately call a POISON CENTER or doctor Rinse mouth IN CASE OF FIRE: Use CO2, dry chemical, or foam to extinguish Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No. Weight-% Methanol 67-56-1 90-100 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret. ** 4. FIRST AID MEASURES Description of first aid measures General Advice IF exposed: Call a POISON CENTER or doctor/physician. Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Call a poison center or doctor/physician if you feel unwell. SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Inhalation Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician. Ingestion Immediately call a poison center or doctor/physician. Rinse mouth. Most important symptoms and effects, both acute and delayed Symptoms Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to organs. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Highly flammable liquid and vapor. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Keep cool. Wear protective gloves/protective clothing and eye/face protection. Conditions for safe storage, including any incompatibilities SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Storage Conditions Store locked up. Store in a well-ventilated place. Keep cool. Keep container tightly closed. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Methanol 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Appropriate engineering controls Engineering Controls Showers. Eyewash stations. Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear colorless Odor Very, slight alcohol smell Color Not determined Odor Threshold Not determined Property Values Remarks ? Method pH Not determined Melting point / freezing point -97.8 ?C / -144 ?F Boiling point / boiling range 64.4 ?C / 148 ?F Flash point 12.2 ?C / 54 ?F Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits Not determined Lower flammability or explosive limits Not determined Vapor Pressure Not determined Vapor Density Not determined Relative Density 0.7925 Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 Autoignition temperature Not determined Decomposition temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Toxic in contact with skin. Inhalation Toxic if inhaled. Ingestion Toxic if swallowed. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Methanol 67-56-1 = 6200 mg/kg (Rat) = 15800 mg/kg (Rabbit) = 15840 mg/kg (Rabbit) = 22500 ppm (Rat) 8 h = 64000 ppm (Rat) 4 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. STOT - single exposure Causes damage to organs. Numerical measures of toxicity SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 100.00 mg/kg ATEmix (dermal) 300.00 mg/kg ATEmix (inhalation-dust/mist) 0.50 mg/L ATEmix (inhalation-vapor) 3.00 mg/L 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical name Algae/aquatic plants Fish Crustacea Methanol 67-56-1 18 - 20: 96 h Oncorhynchus mykiss mL/L LC50 static 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient Methanol 67-56-1 -0.77 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Methanol 67-56-1 Included in waste stream: F039 U154 California Hazardous Waste Status Chemical name California Hazardous Waste Status Methanol Toxic SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 67-56-1 Ignitable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1230 Proper Shipping Name Methanol Hazard class 3 Packing Group II IATA UN number UN1230 Proper Shipping Name Methanol Transport hazard class(es) 3 Subsidiary hazard class 6.1 Packing Group II IMDG UN number UN1230 Proper Shipping Name Methanol Transport hazard class(es) 3 Subsidiary Hazard Class 6.1 Packing Group II 15. REGULATORY INFORMATION International Inventories Chemical name TSCA DSL/NDSL EINECS/E LINCS ENCS IECSC KECL PICCS AICS Methanol X X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Methanol 67-56-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA 313 Chemical name CAS No. Weight-% SARA 313 - Threshold Values % Methanol - 67-56-1 67-56-1 90-100 1.0 CWA (Clean Water Act) SPLASH Concentrate 55 Gallon Drum Revision Date: 6-Jan-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical name California Proposition 65 Methanol - 67-56-1 Developmental U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Methanol 67-56-1 X X X 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 15-Aug-2018 Revision Date: 6-Jan-20 Revision Note: Corrected recommended use name Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet