3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 08-7522-9 Version Number: 12.04 Issue Date: 08/23/18 Supercedes Date: 08/22/18 SECTION 1: Identification 1.1. Product identifier 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 Product Identification Numbers ID Number UPC ID Number UPC 60-9800-3228-2 00-51135-08690-2 60-9800-3558-2 00051135086896 60-9800-3918-8 00-51135-08566-0 7000144585, 7000148240, 7010364098, 7000120469, 7000144586 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive/Sealant for Windshields 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Carcinogenicity: Category 2. 2.2. Label elements 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 2 of 11 Signal word Danger Symbols Health Hazard | Pictograms Hazard Statements Causes eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 39% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Polyether (NJTS: 04499600-7082) Trade Secret* 30 - 60 Trade Secret * Carbon Black 1333-86-4 10 - 30 Trade Secret * Phenol Alkyl Sulfonate (NJTS: 04499600-7083) Trade Secret* 10 - 30 Trade Secret * 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 3 of 11 Kaolin, Calcined 92704-41-1 7 - 13 Trade Secret * Hydrotreated Light Petoleum Distillates 64742-47-8 1 - 5 Trade Secret * P,P'-Methylenebis(phenyl isocyanate) 101-68-8 0.1 - 0.5 Trade Secret * Dibutyltin Dichloride 683-18-1 < 0.08 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media DO NOT USE WATER 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 4 of 11 Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up residue. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments P,P'-Methylenebis(phenyl isocyanate) 101-68-8 ACGIH TWA:0.005 ppm P,P'-Methylenebis(phenyl isocyanate) 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 JET FUELS (NON-AEROSOL), AS TOTAL HYDROCARBON VAPOR 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., SKIN Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., SKIN TIN, ORGANIC COMPOUNDS 683-18-1 ACGIH TWA(as Sn):0.1 mg/m3;STEL(as Sn):0.2 mg/m3 SKIN, A4: Not class. as human carcin TIN, ORGANIC COMPOUNDS 683-18-1 OSHA TWA(as Sn):0.1 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 5 of 11 STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Respiratory protection In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Slight odor Black paste Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 192 - 200 ?C Flash Point No flash point Evaporation rate No Data Available Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure No Data Available Vapor Density No Data Available Density 1.215 g/ml Specific Gravity 1.20 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 6 of 11 Autoignition temperature > 200 ?C Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.0033 lb HAPS/lb solids [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds 37 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 3.1 % weight [Test Method:calculated per CARB title 2] Percent volatile 1.70 % weight [Details:Excluding exempt compounds] VOC Less H2O & Exempt Solvents 37 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization may occur. Reacts with water. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Amines Alcohols Water 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 7 of 11 Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Phenol Alkyl Sulfonate (NJTS: 04499600-7083) Dermal Rat LD50 > 1,000 mg/kg Phenol Alkyl Sulfonate (NJTS: 04499600-7083) Ingestion Rat LD50 > 5,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Kaolin, Calcined Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Kaolin, Calcined Ingestion Rat LD50 > 2,000 mg/kg Hydrotreated Light Petoleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petoleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l Hydrotreated Light Petoleum Distillates Ingestion Rat LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Dermal Rabbit LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l P,P'-Methylenebis(phenyl isocyanate) Ingestion Rat LD50 31,600 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Carbon Black Rabbit No significant irritation Hydrotreated Light Petoleum Distillates Rabbit Mild irritant 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 8 of 11 P,P'-Methylenebis(phenyl isocyanate) official classifica tion Irritant Serious Eye Damage/Irritation Name Species Value Carbon Black Rabbit No significant irritation Hydrotreated Light Petoleum Distillates Rabbit Mild irritant P,P'-Methylenebis(phenyl isocyanate) official classifica tion Severe irritant Skin Sensitization Name Species Value Hydrotreated Light Petoleum Distillates Guinea pig Not classified P,P'-Methylenebis(phenyl isocyanate) official classifica tion Sensitizing Respiratory Sensitization Name Species Value P,P'-Methylenebis(phenyl isocyanate) Human Sensitizing Germ Cell Mutagenicity Name Route Value Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petoleum Distillates In Vitro Not mutagenic P,P'-Methylenebis(phenyl isocyanate) In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Hydrotreated Light Petoleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification P,P'-Methylenebis(phenyl isocyanate) Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration P,P'-Methylenebis(phenyl isocyanate) Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hydrotreated Light Inhalation central nervous May cause drowsiness or Human NOAEL Not 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 9 of 11 Petoleum Distillates system depression dizziness and animal available Hydrotreated Light Petoleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Light Petoleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Notavailable P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not available occupational exposure P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Aspiration Hazard Name Value Hydrotreated Light Petoleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 10 of 11 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Carcinogenicity Serious eye damage or eye irritation 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing Carbon Black 1333-86-4 Carcinogen 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. One or more chemical components of this material have been commercialized under the TSCA polymer exemption at 40CFR723.250. Polymers subject to this exemption are not listed on the TSCA Inventory, but are in compliance with TSCA requirements. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 08-7522-9 Version Number: 12.04 Issue Date: 08/23/18 Supercedes Date: 08/22/18 Reason for Reissue Conversion to GHS format SDS. DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for 3M? Fast Cure Auto Glass Urethane, PN 08566, 08689, 08690 08/23/18 __________________________________________________________________________________________ Page 11 of 11 user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com