Safety Data Sheet Issue Date: 18-Dec-2018 Revision Date: 01-May-2020 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product identifier Product Name Splash 6% bleach Other means of identification SDS#/Part# 269300-28 UN/ID No UN1791 Recommended use of the chemical and restrictions on use Recommended Use Deodorizer, laundry bleach, hard surface cleaner, stain remover. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear yellow liquid Physical state Liquid Odor Slight chlorine Classification Skin corrosion/irritation Category 1 Sub-category C Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other hazards Very toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Sodium hypochlorite 7681-52-9 5-10 Sodium hydroxide 1310-73-2 0.1-1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures General Advice Immediately call a poison center or doctor/physician. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Inhalation Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center or doctor/physician. Ingestion Rinse mouth. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Symptoms Causes severe skin burns and eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Do not breathe dusts or mists. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Incompatible Materials Strong oxidizing agents. Strong bases. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 TWA: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 IDLH: 10 mg/m3 Ceiling: 2 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/Face Protection Tight sealing safety goggles. Face protection shield. Skin and Body Protection Gloves made of plastic, suitable protective clothing, rubber boots, apron, lab coat or coveralls, as appropriate, to prevent skin contact. SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear yellow liquid Odor Slight chlorine Color Yellow Odor Threshold Not determined Property Values Remarks ? Method pH 13 Melting point / freezing point -18 ?C / -1 ?F Boiling point / boiling range 100 ?C / 212 ?F Flash point Not determined Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits Not determined Lower flammability or explosive limits Not determined Vapor Pressure 65.8 @ 55?C (131?F) Vapor Density Not determined Relative Density 1.17 Water Solubility 100% Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials Strong oxidizing agents. Strong bases. Strong acids. Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapors. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Sodium Chloride 7647-14-5 = 3 g/kg ( Rat ) > 10 g/kg ( Rabbit ) > 42 g/m3 ( Rat ) 1 h Sodium hypochlorite 7681-52-9 = 8.91 g/kg ( Rat ) > 10000 mg/kg ( Rabbit ) - Sodium hydroxide 1310-73-2 = 325 mg/kg ( Rat ) = 1350 mg/kg ( Rabbit ) - Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Causes severe skin burns. Serious eye damage/eye irritation Causes serious eye damage. Carcinogenicity Group 3 IARC components are "not classifiable as human carcinogens". Chemical name ACGIH IARC NTP OSHA Sodium hypochlorite 7681-52-9 Group 3 Legend IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document . Oral LD50 16,900.48 mg/kg Dermal LD50 50,264.10 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 Component Information Chemical name Algae/aquatic plants Fish Crustacea Sodium hypochlorite 7681-52-9 0.095: 24 h Skeletonema costatum mg/L EC50 4.5 - 7.6: 96 h Pimephales promelas mg/L LC50 static 0.05 - 0.771: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 0.18 - 0.22: 96 h Oncorhynchus mykiss mg/L LC50 static 0.4 - 0.8: 96 h Lepomis macrochirus mg/L LC50 static 0.28 - 1: 96 h Lepomis macrochirus mg/L LC50 flow-through 0.03 - 0.19: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 0.06 - 0.11: 96 h Pimephales promelas mg/L LC50 flow-through 2.1: 96 h Daphnia magna mg/L EC50 0.033 - 0.044: 48 h Daphnia magna mg/L EC50 Static Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical name California Hazardous Waste Status Sodium hydroxide 1310-73-2 Toxic Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT This product is packaged in 1 gallon bottles and 55 gallon drums. By ground transportation, the limited quantity exception may be used for the 1 gallon bottles. UN/ID No UN1791 Proper Shipping Name Hypochlorite solutions Hazard class 8 Packing Group III SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 IATA UN number UN1791 Proper Shipping Name Hypochlorite solutions Transport hazard class(es) 8 Packing Group III IMDG This product is packaged in 1 gallon bottles and 55 gallon drums. By vessel transportation, the limited quantity exception may be used for the 1 gallon bottles. UN number UN1791 Proper Shipping Name Hypochlorite solutions Transport hazard class(es) 8 Packing Group III 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS Sodium Chloride X ACTIVE X X X X X X X Sodium hypochlorite X ACTIVE X X X X X X X Sodium hydroxide X ACTIVE X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Sodium hypochlorite 7681-52-9 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ Sodium hydroxide 1310-73-2 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) Chemical name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hypochlorite 100 lb X Sodium hydroxide 1000 lb X US State Regulations California Proposition 65 SPLASH 6% bleach Revision Date: 01-May-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Sodium hypochlorite 7681-52-9 X X X Sodium hydroxide 1310-73-2 X X X 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 18-Dec-2018 Revision Date: 01-May-2020 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet