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18093G Gas Treatment
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SECTION 1: Identification 1.1 Product identifier Trade name STP Gas Treatment - bottle Alternative number(s) 067788183622, 071153785731, 071153192430, 067788171155, 071153785786, 071153786097, 071153785915 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses General use 1.3 Details of the supplier of the safety data sheet Energizer Manufacturing, Inc. 25225 Detroit Rd. Westlake OH 44145 United States ? Telephone: 800-383-7323; 314-985-2000 (USA / CANADA) Website: http://data.energizer.com Energizer Trading Ltd. Sword House, Totteridge Road, High Wycombe, HP13 6DG, UK Telephone: +44(0)8000353376 e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4 Emergency telephone number Emergency information service 1-314-985-1511 Int'l: 1-800-526-4727 This number is only available during the following office hours: Mon-Fri 09:00 AM - 05:00 PM SECTION 2: Hazard(s) identification 2.1 Classification of the substance or mixture Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) Section Hazard class Category Hazard class and category Hazard state- ment A.1I acute toxicity (inhal.) 3 Acute Tox. 3 H331 A.5 germ cell mutagenicity 1B Muta. 1B H340 A.6 carcinogenicity 1A Carc. 1A H350 A.7 reproductive toxicity 2 Repr. 2 H361d A.10 aspiration hazard 1 Asp. Tox. 1 H304 Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 1 / 37 Section Hazard class Category Hazard class and category Hazard state- ment B.6 flammable liquid 3 Flam. Liq. 3 H226 For full text of abbreviations: see SECTION 16. The most important adverse physicochemical, human health and environmental effects The product is combustible and can be ignited by potential ignition sources. 2.2 Label elements Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word danger - Pictograms GHS02, GHS06, GHS08 - Hazard statements H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H331 Toxic if inhaled. H340 May cause genetic defects. H350 May cause cancer. H361d Suspected of damaging the unborn child. - Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing mist/vapors. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/eye protection/face protection. P301+P310 If swallowed: Immediately call a poison center/doctor. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P311 Call a poison center/doctor. P321 Specific treatment (see on this label). P331 Do NOT induce vomiting. P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 2 / 37 - Precautionary statements P405 Store locked up. P501 Dispose of contents/container in accordance with national regulations. 2.2.1.7- Hazardous ingredients for labelling Distillates (petroleum), hydrodesulfurized middle, Kerosene, toluene, benzene 2.3 Other hazards Hazards not otherwise classified May be harmful in contact with skin (GHS category 5: acutely toxic - dermal). Toxic to aquatic life with long lasting effects (GHS category 2: aquatic toxicity - acute and/or chronic). SECTION 3: Composition/information on ingredients 3.1 Substances Not relevant (mixture) 3.2 Mixtures Description of the mixture Name of substance Identifier Wt% Classification acc. to GHS Pictograms Straight-run Kerosene CAS No 64741-44-2 10???100 mg/l fish 24 h Straight-run Kerosene 64741-44-2 EL50 >1,000 mg/l aquatic invertebrates 24 h Distillates (petroleum), hydrodesulfurized middle 64742-80-9 LL50 >100 mg/l fish 24 h Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 18 / 37 Aquatic toxicity (acute) of components of the mixture Name of substance CAS No Endpoint Value Species Exposure time Distillates (petroleum), hydrodesulfurized middle 64742-80-9 EL50 >1,000 mg/l aquatic invertebrates 24 h Kerosene 8008-20-6 LL50 5 mg/l fish 96 h Kerosene 8008-20-6 EL50 1.4 mg/l aquatic invertebrates 48 h Kerosene 8008-20-6 LOEL 1 mg/l algae 72 h Distillates (petroleum), hydrodesulfurized light catalytic cracked 68333-25-5 LL50 >0.3 mg/l fish 96 h Distillates (petroleum), hydrodesulfurized light catalytic cracked 68333-25-5 LC50 >0.21 mg/l fish 96 h Distillates (petroleum), hydrodesulfurized light catalytic cracked 68333-25-5 EL50 0.32 mg/l aquatic invertebrates 48 h Kerosine (petroleum), hydrodesulfurized 64742-81-0 LL50 5 mg/l fish 96 h Kerosine (petroleum), hydrodesulfurized 64742-81-0 EL50 1.4 mg/l aquatic invertebrates 48 h Kerosine (petroleum), hydrodesulfurized 64742-81-0 LOEL 1 mg/l algae 72 h Distillates (petroleum), light hydrocracked 64741-77-1 LL50 >100 mg/l fish 24 h Distillates (petroleum), light hydrocracked 64741-77-1 EL50 180 mg/l aquatic invertebrates 24 h Solvent naphtha (petro- leum), light arom. 64742-95-6 LL50 8.2 mg/l fish 96 h Solvent naphtha (petro- leum), light arom. 64742-95-6 EL50 4.5 mg/l aquatic invertebrates 48 h Solvent naphtha (petro- leum), medium aliph. 64742-88-7 LL50 5 mg/l fish 96 h Solvent naphtha (petro- leum), medium aliph. 64742-88-7 EL50 1.4 mg/l aquatic invertebrates 48 h Solvent naphtha (petro- leum), medium aliph. 64742-88-7 LOEL 1 mg/l algae 72 h naphthalene 91-20-3 LC50 1.6 mg/l fish 96 h Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 19 / 37 Aquatic toxicity (acute) of components of the mixture Name of substance CAS No Endpoint Value Species Exposure time naphthalene 91-20-3 EC50 2.16 mg/l aquatic invertebrates 48 h toluene 108-88-3 LC50 5.5 mg/l fish 96 h toluene 108-88-3 EC50 84 mg/l microorganisms 24 h benzene 71-43-2 LC50 5.3 mg/l fish 96 h benzene 71-43-2 EC50 10 mg/l aquatic invertebrates 24 h benzene 71-43-2 ErC50 100 mg/l algae 72 h benzene 71-43-2 growth (EbCx) 10% 10 mg/l algae 72 h benzene 71-43-2 growth rate (ErCx) 10% 34 mg/l algae 72 h ethylbenzene 100-41-4 LC50 7 mg/l fish 24 h ethylbenzene 100-41-4 EC50 2.4 mg/l aquatic invertebrates 48 h ethylbenzene 100-41-4 NOEC 3.3 mg/l fish 96 h cumene 98-82-8 LC50 4.7 mg/l fish 96 h cumene 98-82-8 EC50 2.14 mg/l aquatic invertebrates 48 h cumene 98-82-8 ErC50 2.01 mg/l algae 72 h cumene 98-82-8 NOEC <2.9 mg/l fish 96 h cumene 98-82-8 growth (EbCx) 10% 1.3 mg/l aquatic invertebrates 48 h cumene 98-82-8 growth rate (ErCx) 10% 1.35 mg/l algae 72 h 2-ethylhexan-1-ol 104-76-7 LC50 17.1 mg/l fish 96 h 2-ethylhexan-1-ol 104-76-7 EC50 39 mg/l aquatic invertebrates 48 h 2-ethylhexan-1-ol 104-76-7 ErC50 16.6 mg/l algae 72 h 2-ethylhexan-1-ol 104-76-7 NOEC 14 mg/l fish 96 h 2-ethylhexan-1-ol 104-76-7 growth (EbCx) 10% 3.2 mg/l algae 72 h 2-ethylhexan-1-ol 104-76-7 growth rate (ErCx) 10% 5.3 mg/l algae 72 h Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 20 / 37 Aquatic toxicity (chronic) of components of the mixture Name of substance CAS No Endpoint Value Species Exposure time Straight-run Kerosene 64741-44-2 EL50 >1,000 mg/l microorganisms 40 h Distillates (petroleum), hydrodesulfurized middle 64742-80-9 EL50 >1,000 mg/l microorganisms 40 h Kerosene 8008-20-6 EL50 0.89 mg/l aquatic invertebrates 21 d Kerosene 8008-20-6 LOEL 1.2 mg/l aquatic invertebrates 21 d Distillates (petroleum), hydrodesulfurized light catalytic cracked 68333-25-5 EL50 0.22 mg/l aquatic invertebrates 21 d Distillates (petroleum), hydrodesulfurized light catalytic cracked 68333-25-5 EC50 0.17 mg/l aquatic invertebrates 21 d Distillates (petroleum), hydrodesulfurized light catalytic cracked 68333-25-5 NOEC 0.038 mg/l aquatic invertebrates 21 d Kerosine (petroleum), hydrodesulfurized 64742-81-0 EL50 0.89 mg/l aquatic invertebrates 21 d Kerosine (petroleum), hydrodesulfurized 64742-81-0 LOEL 1.2 mg/l aquatic invertebrates 21 d Distillates (petroleum), light hydrocracked 64741-77-1 EL50 >1,000 mg/l microorganisms 40 h Solvent naphtha (petro- leum), light arom. 64742-95-6 EL50 10 mg/l fish 21 d Solvent naphtha (petro- leum), light arom. 64742-95-6 EC50 15.41 mg/l microorganisms 40 h Solvent naphtha (petro- leum), medium aliph. 64742-88-7 EL50 0.89 mg/l aquatic invertebrates 21 d Solvent naphtha (petro- leum), medium aliph. 64742-88-7 LOEL 1.2 mg/l aquatic invertebrates 21 d naphthalene 91-20-3 EC50 2.96 mg/l algae 4 h naphthalene 91-20-3 NOEC 0.37 mg/l fish 40 d naphthalene 91-20-3 LOEC 0.38 mg/l fish 40 d toluene 108-88-3 LC50 3.78 mg/l aquatic invertebrates 2 d toluene 108-88-3 EC50 3.23 mg/l aquatic invertebrates 7 d Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 21 / 37 Aquatic toxicity (chronic) of components of the mixture Name of substance CAS No Endpoint Value Species Exposure time toluene 108-88-3 LOEC 2.77 mg/l fish 40 d toluene 108-88-3 NOEC 1.39 mg/l fish 40 d benzene 71-43-2 LOEC 1.6 mg/l fish 32 d ethylbenzene 100-41-4 LC50 3.6 mg/l aquatic invertebrates 7 d ethylbenzene 100-41-4 LOEL 1.7 mg/l aquatic invertebrates 7 d ethylbenzene 100-41-4 NOEC 0.96 mg/l aquatic invertebrates 7 d ethylbenzene 100-41-4 LOEC 1.7 mg/l aquatic invertebrates 7 d cumene 98-82-8 EC50 1.5 mg/l aquatic invertebrates 21 d cumene 98-82-8 LC50 >3 mg/l aquatic invertebrates 21 d cumene 98-82-8 NOEC 0.38 mg/l fish 28 d cumene 98-82-8 growth (EbCx) 10% 0.6 mg/l aquatic invertebrates 21 d 12.2 Persistence and degradability Data are not available. 12.3 Bioaccumulative potential Data are not available. 12.4 Mobility in soil Data are not available. 12.5 Results of PBT and vPvB assessment Data are not available. 12.6 Endocrine disrupting properties None of the ingredients are listed. 12.7 Other adverse effects Data are not available. Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 22 / 37 SECTION 13: Disposal considerations 13.1 Waste treatment methods Waste treatment-relevant information Solvent reclamation/regeneration. Sewage disposal-relevant information Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets. Waste treatment of containers/packages Only packagings which are approved (e.g. acc. to DOT) may be used. Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself. Remarks Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities. SECTION 14: Transport information 14.1 UN number DOT 1268 IMDG-Code 1268 ICAO-TI 1268 14.2 UN proper shipping name DOT Petroleum distillates, n.o.s. IMDG-Code PETROLEUM DISTILLATES, N.O.S. ICAO-TI Petroleum distillates, n.o.s. 14.3 Transport hazard class(es) DOT 3 IMDG-Code 3 ICAO-TI 3 14.4 Packing group DOT III IMDG-Code III ICAO-TI III 14.5 Environmental hazards hazardous to the aquatic environment 14.5.1 Additional information LTD QTY Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 23 / 37 Environmentally hazardous substance (aquatic environment) Kerosene 14.6 Special precautions for user There is no additional information. 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code The cargo is not intended to be carried in bulk. Information for each of the UN Model Regulations Transport of dangerous goods by road or rail (49 CFR US DOT) - Additional information Particulars in the shipper's declaration UN1268, Petroleum distillates, n.o.s., (contains: Straight-run Kerosene, Distillates (petroleum), hy- drodesulfurized middle), 3, III, environmentally hazardous Reportable quantity (RQ) 5,063 lbs (2,298 kg) (benzene) (naphthalene) Danger label(s) 3, fish and tree Environmental hazards yes (hazardous to the aquatic environment) Special provisions (SP) 144, B1, IB3, T4, TP1, TP29, LTD QTY ERG No 128 International Maritime Dangerous Goods Code (IMDG) - Additional information Particulars in the shipper's declaration UN1268, PETROLEUM DISTILLATES, N.O.S., (con- tains: Straight-run Kerosene, Distillates (petroleum), hydrodesulfurized middle), 3, III, 44?C c.c., MARINE POLLUTANT Marine pollutant yes (hazardous to the aquatic environment) (Kerosene) Danger label(s) 3, fish and tree Special provisions (SP) 223, 955 Excepted quantities (EQ) E1 Limited quantities (LQ) 5 L EmS F-E, S-E Stowage category A Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 24 / 37 International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information Particulars in the shipper's declaration UN1268, Petroleum distillates, n.o.s., (contains: Straight-run Kerosene, Distillates (petroleum), hy- drodesulfurized middle), 3, III Environmental hazards yes (hazardous to the aquatic environment) Danger label(s) 3 Special provisions (SP) A3 Excepted quantities (EQ) E1 Limited quantities (LQ) 10 L SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States) Toxic Substance Control Act (TSCA) all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III ) - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304) none of the ingredients are listed - Specific Toxic Chemical Listings (EPCRA Section 313) Toxics Release Inventory: Specific Toxic Chemical Listings Name of substance CAS No Remarks Effective date benzene 71-43-2 1987-01-01 ethylbenzene 100-41-4 1987-01-01 cumene 98-82-8 1987-01-01 naphthalene 91-20-3 1987-01-01 toluene 108-88-3 1987-01-01 Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 25 / 37 Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4) Name of substance CAS No Remarks Statutory code Final RQ pounds (Kg) benzene 71-43-2 a 1 2 3 4 10 (4,54) benzene ethylbenzene 100-41-4 1 2 3 1000 (454) cumene 98-82-8 3 4 5000 (2270) naphthalene 91-20-3 1 2 3 4 100 (45,4) toluene 108-88-3 1 2 3 4 1000 (454) Legend 1 "1" indicates that the statutory source is section 311(b)(2) of the Clean Water Act 2 "2" indicates that the source is section 307(a) of the Clean Water Act 3 "3" indicates that the source is section 112 of the Clean Air Act 4 "4" indicates that the source is section 3001 of the Resource Conservation and Recovery Act (RCRA) a Benzene was already a CERCLA hazardous substance prior to the CAA Amendments of 1990 and received an adjusted 10-pound RQ based on potential carcinogenicity in an August 14, 1989, final rule (54 FR 33418). The CAA Amendments specify that ?benzene (including benzene from gasoline)? is a hazardous air pollutant and, thus, a CERCLA hazardous substance. Clean Air Act none of the ingredients are listed Right to Know Hazardous Substance List - Toxic or Hazardous Substance List (MA-TURA) Name of substance Name acc. to inventory CAS No DEP CODE PBT / HHS / LHS PBT / HHS Thres hold De Minimis Concentra- tion Threshold Propylbenzene Cumene 98-82-8 0.1 % benzene Benzene 71-43-2 1.0 % ethylbenzene Ethylbenzene 100-41-4 0.1 % Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 26 / 37 Name of substance Name acc. to inventory CAS No DEP CODE PBT / HHS / LHS PBT / HHS Thres hold De Minimis Concentra- tion Threshold cumene Cumene 98-82-8 0.1 % 1,2,4 trimethlybenzene 1,2,4-Trimethylbenzene 95-63-6 1.0 % xylene Xylene (mixed isomers) 1330-20-7 1.0 % naphthalene Naphthalene 91-20-3 0.1 % toluene Toluene 108-88-3 1.0 % - Hazardous Substances List (MN-ERTK) Name of substance Name acc. to inventory CAS No References Remarks benzene Benzene 71-43-2 A, N, O, R, T, * Legend * Substances which are regulated by OSHA as carcinogens; have been categorized by the ACGIH as either "human carcinogens" or "suspect of carcinogenic potential for man"; have been evaluated by the International Agency for Research on Cancer (IARC) and found to be carcinogens or potential carcinogens; or have been listed as a carcinogen or potential carcinogen in the Annual Re- port on Carcinogens published by the National Toxicology Program (NTP). A American Conference of Governmental Industrial Hygienists (ACGIH), "Threshold Limit Values for Chemical Substances and Physic- al Agents and Biological Exposure Indices for 1992-93", available from ACGIH N National Institute for Occupational Safety and Health (NIOSH), "Recommendations for Occupational Safety and Health Standards," August 1988, available from NIOSH, Publications Dissemination Office, Division of Standards Development and Technology Trans- fer O Occupational Safety and Health Administration (OSHA), Safety and Health Standards, Code of Federal Regulations, title 29, part 1910, subpart Z, "Toxic and Hazardous Substances, 1990." General information: Minnesota Department of Labor and Industry, Oc- cupational Safety and Health Division R International Agency for Research on Cancer (IARC) Monographs on the Evaluation of the Carcinogenic Risks to Humans; Overall Evaluations of Carcinogenicity: An Updating of IARC Monographs Volumes 1 to 42, Supplement 7 (1987). Available from: WHO Publications Centre USA T National Toxicology Program (NTP) "Fifth Annual Report on Carcinogens," 1989 (NTP 89-239). Order information: (919) 541-3992 - Hazardous Substance List (NJ-RTK) Name of substance Name acc. to inventory CAS No Remarks Classifications Propylbenzene propylbenzene (benzene, pro- pyl-) 103-65-1 F3 1,2,3-Trimethylbenzene TRIMETHYL BENZENE (mixed isomers) (BENZENE, TRIMETHYL- ) 25551-13-7 F2 benzene benzene 71-43-2 CA MU F3 ethylbenzene ethylbenzene (benzene, ethyl-) 100-41-4 CA F3 Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 27 / 37 Name of substance Name acc. to inventory CAS No Remarks Classifications cumene cumene 98-82-8 F3 R1 Kerosene Kerosine (petroleum) 8008-20-6 F2 1,2,4 trimethlybenzene pseudocumene 95-63-6 F2 xylene xylene, mixture of isomers (ben- zene, dimethyl-) 1330-20-7 F3 naphthalene naphthalene 91-20-3 CA F2 1,3,5-trimethylbenzene TRIMETHYL BENZENE (mixed isomers) (BENZENE, TRIMETHYL- ) 25551-13-7 F2 toluene toluene (benzene, methyl-) (tolu- ol) 108-88-3 TE F3 Legend CA Carcinogenic F2 Flammable - Second Degree F3 Flammable - Third Degree MU Mutagenic R1 Reactive - First Degree TE Teratogenic - Hazardous Substance List (Chapter 323) (PA-RTK) Name of substance Name acc. to inventory CAS No Classification benzene BENZENE 71-43-2 E, S ethylbenzene BENZENE, ETHYL- 100-41-4 E cumene BENZENE, (1-METHYLETHYL)- 98-82-8 E Kerosene KEROSINE (PETROLEUM) 8008-20-6 1,2,4 trimethlybenzene PSEUDOCUMENE 95-63-6 E xylene BENZENE, DIMETHYL- 1330-20-7 E naphthalene NAPHTHALENE 91-20-3 E toluene BENZENE, METHYL- 108-88-3 E Legend E Environmental hazard S Special hazardous substance Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 28 / 37 - Hazardous Substance List (RI-RTK) Name of substance Name acc. to inventory CAS No References Propylbenzene cumene 98-82-8 T, F 1,2,3-Trimethylbenzene Trimethyl benzene 25551-13-7 T benzene benzene 71-43-2 T, F, C ethylbenzene Ethyl benzene 100-41-4 T, F cumene cumene 98-82-8 T, F Kerosene Kerosene 8008-20-6 F 1,2,4 trimethlybenzene Trimethyl benzene 25551-13-7 T xylene Dimethylbenzene 1330-20-7 T, F naphthalene naphthalene 91-20-3 T, F 1,3,5-trimethylbenzene Trimethyl benzene 25551-13-7 T toluene Methylbenzene 108-88-3 T, F Legend C Carcinogenicity (IARC) F Flammability (NFPA?) T Toxicity (ACGIH?) California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987 Proposition 65 List of chemicals Name acc. to inventory CAS No Remarks Type of the toxicity benzene 71-43-2 cancer benzene 71-43-2 developmental, male ethylbenzene 100-41-4 cancer cumene 98-82-8 cancer naphthalene 91-20-3 cancer toluene 108-88-3 developmental Industry or sector specific available guidance(s) NPCA-HMIS? III Hazardous Materials Identification System. American Coatings Association. Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 29 / 37 Category Rating Description Chronic * chronic (long-term) health effects may result from repeated overexposure Health 1 irritation or minor reversible injury possible Flammability 2 material that must be moderately heated or exposed to relatively high ambient tem- peratures before ignition can occur Physical hazard 0 material that is normally stable, even under fire conditions, and will not react with wa- ter, polymerize, decompose, condense, or self-react. Non-explosive Personal protection - NFPA? 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Re- sponse (United States). Category Degree of hazard Description Flammability 2 material that must be moderately heated or exposed to relatively high ambient tem- peratures before ignition can occur Health 2 material that, under emergency conditions, can cause temporary incapacitation or re- sidual injury Instability 0 material that is normally stable, even under fire conditions Special hazard National inventories Country Inventory Status AU AICS all ingredients are listed CA DSL all ingredients are listed CA NDSL not all ingredients are listed CN IECSC all ingredients are listed EU ECSI all ingredients are listed EU REACH Reg. not all ingredients are listed JP CSCL-ENCS not all ingredients are listed JP ISHA-ENCS not all ingredients are listed KR KECI all ingredients are listed MX INSQ not all ingredients are listed NZ NZIoC not all ingredients are listed Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 30 / 37 Country Inventory Status PH PICCS all ingredients are listed TR CICR not all ingredients are listed TW TCSI not all ingredients are listed US TSCA all ingredients are listed Legend AICS Australian Inventory of Chemical Substances CICR Chemical Inventory and Control Regulation CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS) DSL Domestic Substances List (DSL) ECSI EC Substance Inventory (EINECS, ELINCS, NLP) IECSC Inventory of Existing Chemical Substances Produced or Imported in China INSQ National Inventory of Chemical Substances ISHA-ENCS Inventory of Existing and New Chemical Substances (ISHA-ENCS) KECI Korea Existing Chemicals Inventory NDSL Non-domestic Substances List (NDSL) NZIoC New Zealand Inventory of Chemicals PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS) REACH Reg. REACH registered substances TCSI Taiwan Chemical Substance Inventory TSCA Toxic Substance Control Act 15.2 Chemical Safety Assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information, including date of preparation or last revision Indication of changes (revised safety data sheet) Section Former entry (text/value) Actual entry (text/value) Safety- relev- ant 2.2 - Precautionary statements: change in the listing (table) yes 2.3 Results of PBT and vPvB assessment: This mixture does not contain any substances that are assessed to be a PBT or a vPvB. yes 3.2 Description of the mixture: change in the listing (table) yes 7.2 - Packaging compatibilities: Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used. yes 12.1 Aquatic toxicity (acute) of components of the mix- ture: change in the listing (table) yes Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 31 / 37 Section Former entry (text/value) Actual entry (text/value) Safety- relev- ant 12.1 Aquatic toxicity (chronic) of components of the mixture: change in the listing (table) yes 12.7 Other adverse effects Other adverse effects: Data are not available. yes 13.1 Waste treatment of containers/packages: Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself. Waste treatment of containers/packages: Only packagings which are approved (e.g. acc. to DOT) may be used. Completely emptied pack- ages can be recycled. Handle contaminated pack- ages in the same way as the substance itself. yes 14.1 UN number: 1268 UN number yes 14.1 DOT: 1268 yes 14.1 IMDG-Code: 1268 yes 14.1 ICAO-TI: 1268 yes 14.2 UN proper shipping name: Petroleum distillates, n.o.s. UN proper shipping name yes 14.2 DOT: Petroleum distillates, n.o.s. yes 14.2 IMDG-Code: PETROLEUM DISTILLATES, N.O.S. yes 14.2 ICAO-TI: Petroleum distillates, n.o.s. yes 14.3 Class: 3 (flammable liquids) yes 14.3 DOT: 3 yes 14.3 IMDG-Code: 3 yes 14.3 ICAO-TI: 3 yes 14.4 Packing group: III (substance presenting low danger) Packing group yes 14.4 DOT: III yes Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 32 / 37 Section Former entry (text/value) Actual entry (text/value) Safety- relev- ant 14.4 IMDG-Code: III yes 14.4 ICAO-TI: III yes 14.7 Transport of dangerous goods by road or rail (49 CFR US DOT): Not subject to transport regulations. Transport of dangerous goods by road or rail (49 CFR US DOT) - Additional information yes 14.7 Particulars in the shipper's declaration: UN1268, Petroleum distillates, n.o.s., (contains: Straight-run Kerosene, Distillates (petroleum), hy- drodesulfurized middle), 3, III, environmentally hazardous yes 14.7 Reportable quantity (RQ): 5,063 lbs (2,298 kg) (benzene) (naphthalene) yes 14.7 Danger label(s): 3, fish and tree yes 14.7 Danger label(s): change in the listing (table) yes 14.7 Environmental hazards: yes (hazardous to the aquatic environment) yes 14.7 Special provisions (SP): 144, B1, IB3, T4, TP1, TP29, LTD QTY yes 14.7 ERG No: 128 yes 14.7 UN number: 1268 yes 14.7 Proper shipping name: PETROLEUM DISTILLATES, N.O.S. yes 14.7 Class: 3 yes 14.7 Packing group: III yes 14.7 Particulars in the shipper's declaration: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, 44?C c.c., MARINE POLLUTANT Particulars in the shipper's declaration: UN1268, PETROLEUM DISTILLATES, N.O.S., (con- tains: Straight-run Kerosene, Distillates (petro- leum), hydrodesulfurized middle), 3, III, 44?C c.c., MARINE POLLUTANT yes 14.7 Marine pollutant: yes (hazardous to the aquatic environment) Marine pollutant: yes (hazardous to the aquatic environment) (Ker- osene) yes Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 33 / 37 Section Former entry (text/value) Actual entry (text/value) Safety- relev- ant 14.7 UN number: 1268 yes 14.7 Proper shipping name: Petroleum distillates, n.o.s. yes 14.7 Class: 3 yes 14.7 Packing group: III yes 14.7 Particulars in the shipper's declaration: UN1268, Petroleum distillates, n.o.s., 3, III Particulars in the shipper's declaration: UN1268, Petroleum distillates, n.o.s., (contains: Straight-run Kerosene, Distillates (petroleum), hy- drodesulfurized middle), 3, III yes Abbreviations and acronyms Abbr. Descriptions of used abbreviations 29 CFR 1910.1000 29 CFR 1910.1000, Tables Z-1, Z-2, Z-3 - Occupational Safety and Health Standards: Toxic and Hazardous Sub- stances (permissible exposure limits) 49 CFR US DOT 49 CFR U.S. Department of Transportation ACGIH? American Conference of Governmental Industrial Hygienists ACGIH? 2019 From ACGIH?, 2019 TLVs? and BEIs? Book. Copyright 2019. Reprinted with permission. Information on the proper use of the TLVs? and BEIs?: http://www.acgih.org/tlv-bei-guidelines/policies-procedures-presenta- tions/tlv-bei-position-statement Acute Tox. Acute toxicity Asp. Tox. Aspiration hazard ATE Acute Toxicity Estimate Cal/OSHA PEL California Division of Occupational Safety and Health (Cal/OSHA): Permissible Exposure Limits (PELs) Carc. Carcinogenicity CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances) Ceiling-C Ceiling value DEP CODE Department of Environmental Protection Code DGR Dangerous Goods Regulations (see IATA/DGR) DNEL Derived No-Effect Level DOT Department of Transportation (USA) Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 34 / 37 Abbr. Descriptions of used abbreviations EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval EINECS European Inventory of Existing Commercial Chemical Substances EL50 Effective Loading 50 %: the EL50 corresponds to the loading rate required to produce a response in 50% of the test organisms ELINCS European List of Notified Chemical Substances EmS Emergency Schedule ErC50 ? EC50: in this method, that concentration of test substance which results in a 50 % reduction in either growth (EbC50) or growth rate (ErC50) relative to the control ERG No Emergency Response Guidebook - Number Eye Dam. Seriously damaging to the eye Eye Irrit. Irritant to the eye Flam. Liq. Flammable liquid GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations HHS Higher hazard substance IARC International Agency for Research on Cancer IATA International Air Transport Association IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA) ICAO International Civil Aviation Organization ICAO-TI Technical instructions for the safe transport of dangerous goods by air IMDG International Maritime Dangerous Goods Code IMDG-Code International Maritime Dangerous Goods Code LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 % lethality during a specified time interval LHS Lower hazard substance LL50 Lethal Loading 50 %: the LL50 corresponds to the loading rate causing 50 % lethality LOEC Lowest Observed Effect Concentration LOEL Lowest Observed Effect Level MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant") Muta. Germ cell mutagenicity NFPA? National Fire Protection Association (United States) Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 35 / 37 Abbr. Descriptions of used abbreviations NIOSH REL National Institute for Occupational Safety and Health (NIOSH): Recommended Exposure Limits (RELs) NLP No-Longer Polymer NOEC No Observed Effect Concentration NPCA-HMIS? III National Paint and Coatings Association: Hazardous Materials Identification System - HMIS? III, Third Edition OSHA Occupational Safety and Health Administration (United States) PBT Persistent, Bioaccumulative and Toxic PEL Permissible exposure limit PNEC Predicted No-Effect Concentration ppm Parts per million RCP Reciprocal calculation procedure Repr. Reproductive toxicity RTECS Registry of Toxic Effects of Chemical Substances (database of NIOSH with toxicological information) Skin Corr. Corrosive to skin Skin Irrit. Irritant to skin STEL Short-term exposure limit STOT RE Specific target organ toxicity - repeated exposure STOT SE Specific target organ toxicity - single exposure TLV? Threshold Limit Values TWA Time-weighted average vPvB Very Persistent and very Bioaccumulative Key literature references and sources for data OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200. Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA). Classification procedure Physical and chemical properties: The classification is based on tested mixture. Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mix- ture (additivity formula). Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 36 / 37 List of relevant phrases (code and full text as stated in chapter 2 and 3) Code Text H224 Extremely flammable liquid and vapor. H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H227 Combustible liquid. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H330 Fatal if inhaled. H331 Toxic if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H371 May cause damage to organs. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. Disclaimer This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product. Safety Data Sheet acc. to 29 CFR 1910.1200 App D STP Gas Treatment - bottle Version number: 9.0 Replaces version of: 2020-10-22 (8) Revision: 2021-01-05 United States: en Page: 37 / 37 - SECTION 1: Identification 1.1 Product identifier Trade name Alternative number(s) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses 1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number Emergency information service - SECTION 2: Hazard(s) identification 2.1 Classification of the substance or mixture Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) The most important adverse physicochemical, human health and environmental effects 2.2 Label elements Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word - Pictograms 2.2.1.7 - Hazardous ingredients for labelling 2.3 Other hazards Hazards not otherwise classified - SECTION 3: Composition/information on ingredients 3.1 Substances 3.2 Mixtures Description of the mixture - SECTION 4: First-aid measures 4.1 Description of first-aid measures General notes Following inhalation Following skin contact Following eye contact Following ingestion 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed - SECTION 5: Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2 Special hazards arising from the substance or mixture Hazardous combustion products 5.3 Advice for firefighters - SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2 Environmental precautions 6.3 Methods and material for containment and cleaning up Advice on how to contain a spill Advice on how to clean up a spill Appropriate containment techniques Other information relating to spills and releases 6.4 Reference to other sections - SECTION 7: Handling and storage 7.1 Precautions for safe handling Recommendations - Measures to prevent fire as well as aerosol and dust generation - Specific notes/details Advice on general occupational hygiene 7.2 Conditions for safe storage, including any incompatibilities Managing of associated risks - Explosive atmospheres - Flammability hazards - Ventilation requirements - Packaging compatibilities 7.3 Specific end use(s) - SECTION 8: Exposure controls/personal protection 8.1 Control parameters 8.2 Exposure controls Appropriate engineering controls Individual protection measures (personal protective equipment) Eye/face protection Skin protection - Hand protection - Other protection measures Respiratory protection Environmental exposure controls - SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state Odor Other safety parameters pH (value) Explosive limits - Lower explosion limit (LEL) Vapor pressure Partition coefficient - n-octanol/water (log KOW) Auto-ignition temperature 9.2 Other information Temperature class (USA, acc. to NEC 500) - SECTION 10: Stability and reactivity 10.1 Reactivity If heated: 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid Hints to prevent fire or explosion 10.5 Incompatible materials 10.6 Hazardous decomposition products - SECTION 11: Toxicological information 11.1 Information on toxicological effects Classification procedure Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard - SECTION 12: Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment 12.6 Endocrine disrupting properties 12.7 Other adverse effects - SECTION 13: Disposal considerations 13.1 Waste treatment methods Waste treatment-relevant information Sewage disposal-relevant information Waste treatment of containers/packages Remarks - SECTION 14: Transport information 14.1 UN number DOT IMDG-Code ICAO-TI 14.2 UN proper shipping name DOT IMDG-Code ICAO-TI 14.3 Transport hazard class(es) DOT IMDG-Code ICAO-TI 14.4 Packing group DOT IMDG-Code ICAO-TI 14.5 Environmental hazards 14.5.1 Additional information Environmentally hazardous substance (aquatic environment) 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code Information for each of the UN Model Regulations Transport of dangerous goods by road or rail (49 CFR US DOT) - Additional information Particulars in the shipper's declaration Reportable quantity (RQ) Danger label(s) Environmental hazards Special provisions (SP) ERG No International Maritime Dangerous Goods Code (IMDG) - Additional information Particulars in the shipper's declaration Marine pollutant Danger label(s) Special provisions (SP) Excepted quantities (EQ) Limited quantities (LQ) EmS Stowage category International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information Particulars in the shipper's declaration Environmental hazards Danger label(s) Special provisions (SP) Excepted quantities (EQ) Limited quantities (LQ) - SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States) Toxic Substance Control Act (TSCA) Superfund Amendment and Reauthorization Act (SARA TITLE III ) - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304) - Specific Toxic Chemical Listings (EPCRA Section 313) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4) Clean Air Act Right to Know Hazardous Substance List - Toxic or Hazardous Substance List (MA-TURA) - Hazardous Substances List (MN-ERTK) - Hazardous Substance List (NJ-RTK) - Hazardous Substance List (Chapter 323) (PA-RTK) - Hazardous Substance List (RI-RTK) California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987 Industry or sector specific available guidance(s) NPCA-HMIS? III NFPA? 704 National inventories 15.2 Chemical Safety Assessment - SECTION 16: Other information, including date of preparation or last revision Indication of changes (revised safety data sheet) Abbreviations and acronyms Key literature references and sources for data Classification procedure List of relevant phrases (code and full text as stated in chapter 2 and 3) Disclaimer