Issue Date: 05-Jul-2018 SAFETY DATA SHEET Version 3 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name SPLASH RV & Marine Antifreeze -50?F Other means of identification Part # 619527 (1 gallon), 619525 (2.5 gallon), 900956 (55 gallon drum), 483951 (250 gallon tote) UN/ID No UN1993 Recommended use of the chemical and restrictions on use Recommended Use Antifreeze. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency Telephone Number Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Pink liquid Physical state Liquid Odor Slight alcohol Classification Serious eye damage/eye irritation Category 2 Flammable Liquids Category 3 Signal Word Warning Hazard statements Causes serious eye irritation Flammable liquid and vapor Precautionary Statements - Prevention Wear protective gloves/protective clothing/eye protection/face protection Wash face, hands and any exposed skin thoroughly after handling Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower IN CASE OF FIRE: Use CO2, dry chemical, or foam to extinguish Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Ethyl Alcohol 64-17-5 10-15 Glycerol 56-81-5 1-5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES First Aid Measures General Advice Provide this SDS to medical personnel for treatment. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If irritation occurs, get medical attention. Inhalation Remove to fresh air. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects Symptoms Causes serious eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Flammable liquid and vapor. Hazardous Combustion Products Smoke, fumes or vapors, and oxides of carbon. SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Explosion Data Sensitivity to Static Discharge Take precautionary measures against static discharge. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wear protective gloves/protective clothing and eye/face protection. Wash face, hands and any exposed skin thoroughly after handling. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Showers. Eyewash stations. Ventilation systems. SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Individual protection measures, such as personal protective equipment Eye/Face Protection Wear eye/face protection. Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Wear protective gloves and protective clothing. Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Pink liquid Odor Slight alcohol Color Pink Odor Threshold Not determined Property Values Remarks ? Method pH 8.2 Melting point / freezing point 82.2 ?C / 180 ?F Boiling Point / Boiling Range Not determined Flash Point 40 ?C / 104 ?F Evaporation Rate Not determined Flammability (Solid, Gas) Not determined Flammability Limit in Air Upper Flammability Limit Not determined Lower Flammability Limit Not determined Vapor Pressure Not determined Vapor Density Not determined Relative Density Not determined Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Eye Contact Causes serious eye irritation. Skin Contact Avoid contact with skin. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethyl Alcohol 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Glycerol 56-81-5 = 12600 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) > 570 mg/m3 ( Rat ) 1 h 1,2 Propanediol 57-55-6 = 20 g/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage. Chemical Name ACGIH IARC NTP OSHA Ethyl Alcohol 64-17-5 A3 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 50,071.54 mg/kg ATEmix (inhalation-dust/mist) 5.79 mg/L 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical Name Algae/aquatic plants Fish Crustacea Ethyl Alcohol 64-17-5 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 Glycerol 56-81-5 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static 500: 24 h Daphnia magna mg/L EC50 1,2 Propanediol 57-55-6 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 710: 96 h Pimephales promelas mg/L LC50 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static 1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Ethyl Alcohol 64-17-5 -0.32 Glycerol 56-81-5 -1.76 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Ethyl Alcohol 64-17-5 Toxic Ignitable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT FOR PART #619527 (1 gallon), 619525 (2.5 gallon), 900956 (55 gallon drum) NOT REGULATED PER 49 CFR 173.150(f)(2) ?Combustible liquids in non-bulk packages? FOR PART #483951 (250 gallon tote) UN/ID No UN1993 Proper Shipping Name Flammable liquid, n.o.s. (Ethyl alcohol) Hazard Class 3 Packing Group III IATA FOR ALL PART NUMBERS/ PACKAGE SIZES UN/ID No UN1993 Proper Shipping Name Flammable liquid, n.o.s. (Ethyl alcohol) Hazard Class 3 Packing Group III SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 IMDG FOR ALL PART NUMBERS/ PACAKGE SIZES UN/ID No UN1993 Proper Shipping Name Flammable liquid, n.o.s. (Ethyl alcohol) Hazard Class 3 Packing Group III 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/E LINCS ENCS IECSC KECL PICCS AICS Ethyl Alcohol X X X X X X X X Glycerol X X X X X X X X 1,2 Propanediol X X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 Ethyl Alcohol - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Ethyl Alcohol 64-17-5 X X X Glycerol 56-81-5 X X X 1,2 Propanediol 57-55-6 X X SPLASH RV & Marine Antifreeze -50?F Revision Date: 21-Apr-2021 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 05-Jul-2018 Revision Date: 21-April-2021 Revision Note: Regulatory update Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet