3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 1 of 16 Safety Data Sheet Copyright,2019,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 18-2193-3 Version Number: 8.04 Issue Date: 01/14/19 Supercedes Date: 05/31/18 SECTION 1: Identification 1.1. Product identifier 3M? Throttle Plate & Carb Cleaner, 08866 Product Identification Numbers ID Number UPC ID Number UPC LB-K100-0312-5 60-4550-3021-7 60-4550-3780-8 60-4550-4496-0 60-4550-6925-6 00051131088665 60-9800-4495-6 7000028270, 7100016679 1.2. Recommended use and restrictions on use Recommended use Automotive, Clean and lubricate throttle body assemblies. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Aspiration Hazard: Category 1. 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 2 of 16 Reproductive Toxicity: Category 2. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: cardiovascular system | sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | May cause damage to organs through prolonged or repeated exposure: sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 3 of 16 Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 17% of the mixture consists of ingredients of unknown acute oral toxicity. 17% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Acetone 67-64-1 15 - 40 Trade Secret * Hydrotreated Light Naphtha (Petroleum) 64742-49-0 10 - 30 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 10 - 30 Trade Secret * Petroleum Gases, Liquefied, Sweetened 68476-86-8 10 - 30 Trade Secret * Heptane 142-82-5 5 - 10 Trade Secret * Xylene 1330-20-7 5 - 10 Trade Secret * Methyl Acetate 79-20-9 3 - 7 Trade Secret * Ethylbenzene 100-41-4 1 - 5 Trade Secret * Polyether Amine Trade Secret* 1 - 5 Trade Secret * Methyl Alcohol 67-56-1 0 - 0.1225 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 4 of 16 Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. Non-combustible. Use a fire fighting agent suitable for surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters In case of fire: Stop leak if safe to do so. Fight fire with normal precautions from a reasonable distance. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Close cylinder. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 5 of 16 7.1. Precautions for safe handling Avoid eye contact. Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Protect from sunlight. Store in a well-ventilated place. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., SKIN Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm SKIN Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human carcin Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm) Methyl Acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl Acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 6 of 16 Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Gas Specific Physical Form: Aerosol Odor, Color, Grade: Amber Liquid dispensed as an aerosol, solvent odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point -150 ?F Evaporation rate No Data Available Flammability (solid, gas) Flammable Aerosol: Category 1. Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 35 psi Vapor Density >=1 [Ref Std:AIR=1] Density 0.88 g/ml Specific Gravity 0.88 [Ref Std:WATER=1] Solubility in Water Moderate Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature Not Applicable Viscosity No Data Available Hazardous Air Pollutants 10.03 % weight [Test Method:Calculated] Volatile Organic Compounds 44.5 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 524 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 98 % weight VOC Less H2O & Exempt Solvents 905 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 7 of 16 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Formaldehyde Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 8 of 16 Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation- Vapor (4 hours) Rat LC50 76 mg/l Acetone Ingestion Rat LD50 5,800 mg/kg Hydrotreated Light Naphtha (Petroleum) Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Naphtha (Petroleum) Inhalation- Vapor (4 hours) Rat LC50 > 14.7 mg/l Hydrotreated Light Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Petroleum Gases, Liquefied, Sweetened Inhalation- Gas (4 hours) Rat LC50 277,000 ppm Heptane Dermal Rabbit LD50 3,000 mg/kg 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 9 of 16 Heptane Inhalation- Vapor (4 hours) Rat LC50 103 mg/l Heptane Ingestion Rat LD50 > 15,000 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l Xylene Ingestion Rat LD50 3,523 mg/kg Methyl Acetate Dermal Rat LD50 > 2,000 mg/kg Methyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl Acetate Ingestion Rat LD50 > 5,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Acetone Mouse Minimal irritation Hydrotreated Light Naphtha (Petroleum) Rabbit Irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Petroleum Gases, Liquefied, Sweetened Professio nal judgeme nt No significant irritation Heptane Human Mild irritant Xylene Rabbit Mild irritant Methyl Acetate Rabbit No significant irritation Ethylbenzene Rabbit Mild irritant Methyl Alcohol Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Acetone Rabbit Severe irritant Hydrotreated Light Naphtha (Petroleum) Rabbit Mild irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Petroleum Gases, Liquefied, Sweetened Professio nal judgeme nt No significant irritation Heptane Professio nal judgeme nt Moderate irritant Xylene Rabbit Mild irritant Methyl Acetate Rabbit Moderate irritant Ethylbenzene Rabbit Moderate irritant Methyl Alcohol Rabbit Moderate irritant Skin Sensitization Name Species Value Hydrotreated Light Naphtha (Petroleum) Guinea Not classified 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 10 of 16 pig Hydrotreated Light Petroleum Distillates Guinea pig Not classified Methyl Acetate Human Not classified Ethylbenzene Human Not classified Methyl Alcohol Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Naphtha (Petroleum) In Vitro Not mutagenic Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Petroleum Gases, Liquefied, Sweetened In Vitro Not mutagenic Heptane In Vitro Not mutagenic Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Methyl Acetate In Vitro Not mutagenic Methyl Acetate In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Acetone Not Specified Multiple animal species Not carcinogenic Hydrotreated Light Naphtha (Petroleum) Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Ethylbenzene Inhalation Multiple animal species Carcinogenic Methyl Alcohol Inhalation Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700 mg/kg/day 13 weeks Acetone Inhalation Not classified for development Rat NOAEL 5.2 mg/l during organogenesi 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 11 of 16 s Xylene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Xylene Ingestion Not classified for development Mouse NOAEL Not available during organogenesi s Xylene Inhalation Not classified for development Multiple animal species NOAEL Not available during gestation Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3 mg/l premating & during gestation Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600 mg/kg/day 21 days Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 mg/kg/day during organogenesi s Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s Lactation Name Route Species Value Xylene Ingestion Mouse Not classified for effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Acetone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 hours Acetone Inhalation liver Not classified Guinea pig NOAEL Not available Acetone Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Hydrotreated Light Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Light Naphtha (Petroleum) Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Light Petroleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Notavailable Petroleum Gases, Liquefied, Sweetened Inhalation cardiac sensitization Causes damage to organs similar compoun ds NOAEL Not available 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 12 of 16 Petroleum Gases, Liquefied, Sweetened Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Petroleum Gases, Liquefied, Sweetened Inhalation respiratory irritation Not classified NOAEL Not available Heptane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Heptane Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Not classified Rat NOAEL 3.5 mg/l not available Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Not classified Rat NOAEL 250 mg/kg not applicable Methyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl Acetate Inhalation blindness Not classified NOAEL Not available Methyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 hours Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse Methyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Dermal eyes Not classified Guinea pig NOAEL Not available 3 weeks Acetone Inhalation hematopoietic system Not classified Human NOAEL 3 mg/l 6 weeks Acetone Inhalation immune system Not classified Human NOAEL 1.19 6 days 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 13 of 16 mg/l Acetone Inhalation kidney and/or bladder Not classified Guinea pig NOAEL 119 mg/l not available Acetone Inhalation heart | liver Not classified Rat NOAEL 45 mg/l 8 weeks Acetone Ingestion kidney and/or bladder Not classified Rat NOAEL 900 mg/kg/day 13 weeks Acetone Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion hematopoietic system Not classified Rat NOAEL 200 mg/kg/day 13 weeks Acetone Ingestion liver Not classified Mouse NOAEL 3,896 mg/kg/day 14 days Acetone Ingestion eyes Not classified Rat NOAEL 3,400 mg/kg/day 13 weeks Acetone Ingestion respiratory system Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion muscles Not classified Rat NOAEL 2,500 mg/kg 13 weeks Acetone Ingestion skin | bone, teeth, nails, and/or hair Not classified Mouse NOAEL 11,298 mg/kg/day 13 weeks Petroleum Gases, Liquefied, Sweetened Inhalation kidney and/or bladder Not classified Rat NOAEL Not available Heptane Inhalation liver | nervous system | kidney and/or bladder Not classified Rat NOAEL 12 mg/l 26 weeks Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | gastrointestinal tract | hematopoietic system | muscles | kidney and/or bladder | respiratory system Not classified Multiple animal species NOAEL 3.5 mg/l 13 weeks Xylene Ingestion auditory system Not classified Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Not classified Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Not classified Multiple animal species NOAEL Not available Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system Not classified Mouse NOAEL 1,000 mg/kg/day 103 weeks Methyl Acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl Acetate Inhalation endocrine system | Not classified Rat NOAEL 6.1 28 days 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 14 of 16 hematopoietic system | liver | immune system | kidney and/or bladder mg/l Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Not classified Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation gastrointestinal tract Not classified Rat NOAEL 3.3 mg/l 2 years Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles Not classified Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system Not classified Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Not classified Rat NOAEL 680 mg/kg/day 6 months Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55 mg/l 4 weeks Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1 mg/l 6 weeks Methyl Alcohol Ingestion liver | nervous system Not classified Rat NOAEL 2,500 mg/kg/day 90 days Aspiration Hazard Name Value Hydrotreated Light Naphtha (Petroleum) Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Heptane Aspiration hazard Xylene Aspiration hazard Ethylbenzene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 15 of 16 Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. The facility should be equipped to handle gaseous waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Aspiration Hazard Carcinogenicity Reproductive toxicity Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Xylene 1330-20-7 Trade Secret 5 - 10 Xylene (Benzene, dimethyl-) 1330-20-7 5 - 10 Ethylbenzene 100-41-4 Trade Secret 1 - 5 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing ETHYLBENZENE 100-41-4 Carcinogen METHANOL 67-56-1 Developmental Toxin 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 3M? Throttle Plate & Carb Cleaner, 08866 01/14/19 __________________________________________________________________________________________ Page 16 of 16 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 18-2193-3 Version Number: 8.04 Issue Date: 01/14/19 Supercedes Date: 05/31/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com