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08883 Rubberized Undercoating, black
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3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2021, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-4303-7 Version Number: 5.04 Issue Date: 07/01/21 Supercedes Date: 12/10/19 SECTION 1: Identification 1.1. Product identifier 3M? Rubberized Undercoating Black, PN 08883 Product Identification Numbers ID Number UPC ID Number UPC 60-4550-5115-5 60-4551-0228-9 7000119862, 7100166585 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2B. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 2 of 15 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes eye irritation. Causes skin irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: cardiovascular system | Causes damage to organs through prolonged or repeated exposure: nervous system | respiratory system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 3 of 15 If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Talc 14807-96-6 10 - 30 Trade Secret * Toluene 108-88-3 10 - 30 Trade Secret * Methyl Acetate 79-20-9 < 20 Trade Secret * Asphalt 8052-42-4 < 13 Trade Secret * Oxidized Petroleum Asphalt 64742-93-4 < 13 Trade Secret * Propane 74-98-6 7 - 13 Trade Secret * Alpha-Methylstyrene-Isoamylene-Piperylene Polymer 62258-49-5 5 - 10 Trade Secret * Solvent Naphtha (Petroleum), Light Aliphatic 64742-89-8 5 - 10 Trade Secret * Butadiene-Styrene-Meta-Divinylbenzene Polymer 26471-45-4 3 - 7 Trade Secret * Dimethyl Ether 115-10-6 1 - 5 Trade Secret * Carbon Black 1333-86-4 0.5 - 1.5 Trade Secret * Styrene-Butadiene Polymer 9003-55-8 0.5 - 1.5 Trade Secret * Methyl Alcohol 67-56-1 < 0.5 Trade Secret * Benzene 71-43-2 < 0.02 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 4 of 15 4.2. Most important symptoms and effects, both acute and delayed No critical symptoms or effects. See Section 11.1, information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Sulfide During Combustion Oxides of Sulfur During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 5 of 15 precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin, Ototoxicant Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Dimethyl Ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 OSHA TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Naphtha 64742-89-8 OSHA TWA:400 mg/m3(100 ppm) Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm Danger of cutaneous absorption Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., SKIN Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 Propane 74-98-6 ACGIH Limit value not established: simple asphyxiant Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) Methyl Acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl Acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) Asphalt 8052-42-4 ACGIH TWA(as benzene solubles, inh fume):0.5 mg/m3 A4: Not class. as human carcin ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 6 of 15 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid In aerosol container Black Specific Physical Form: Aerosol Odor Solvent Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point 39.2 ?F [Test Method:Pensky-Martens Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 1.08 g/ml Specific Gravity 1.08 [Ref Std:WATER=1] Solubility In Water No Data Available 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 7 of 15 Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature >=263 ?C [Details:literature value] Decomposition temperature No Data Available Viscosity 7,500 centipoise Average particle size No Data Available Bulk density No Data Available Hazardous Air Pollutants 0.46 lb HAPS/lb solids [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds 39.4 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 426 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 48.4 % weight Softening point No Data Available VOC Less H2O & Exempt Solvents 529 g/l [Test Method:calculated SCAQMD rule 443.1] * The values noted with an asterisk (*) in the above table are representative values based on testing of raw materials and selected products. Additionally, a material's characteristics may change depending upon the process and conditions of use at a facility, including further changes in particle size, or mixture with other materials. In order to obtain specific data for the material, we recommend the user conduct characterization testing based on the use factors at the specific facility. SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Reducing agents Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 8 of 15 Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. May cause additional health effects (see below). Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation BITUMENTS, EXTRACT. 64742-93-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Asphalt 8052-42-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 9 of 15 Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Oxidized Petroleum Asphalt 64742-93-4 Grp. 2A: Probable human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg Talc Ingestion LD50 estimated to be > 5,000 mg/kg Methyl Acetate Dermal Rat LD50 > 2,000 mg/kg Methyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl Acetate Ingestion Rat LD50 > 5,000 mg/kg Asphalt Dermal Rabbit LD50 > 2,000 mg/kg Oxidized Petroleum Asphalt Dermal Rabbit LD50 > 2,000 mg/kg Asphalt Ingestion Rat LD50 > 5,000 mg/kg Oxidized Petroleum Asphalt Ingestion Rat LD50 > 5,000 mg/kg Alpha-Methylstyrene-Isoamylene-Piperylene Polymer Dermal LD50 estimated to be > 5,000 mg/kg Alpha-Methylstyrene-Isoamylene-Piperylene Polymer Ingestion Rat LD50 > 40,000 mg/kg Solvent Naphtha (Petroleum), Light Aliphatic Dermal Rabbit LD50 3,000 mg/kg Solvent Naphtha (Petroleum), Light Aliphatic Inhalation- Vapor (4 hours) Rat LC50 > 5.2 mg/l Solvent Naphtha (Petroleum), Light Aliphatic Ingestion Rat LD50 > 5,000 mg/kg Butadiene-Styrene-Meta-Divinylbenzene Polymer Dermal LD50 estimated to be > 5,000 mg/kg Butadiene-Styrene-Meta-Divinylbenzene Polymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Dimethyl Ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Styrene-Butadiene Polymer Dermal Rabbit LD50 > 2,000 mg/kg Styrene-Butadiene Polymer Ingestion Rat LD50 > 5,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Propane Rabbit Minimal irritation Toluene Rabbit Irritant Talc Rabbit No significant irritation Methyl Acetate Rabbit No significant irritation 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 10 of 15 Asphalt Human Minimal irritation Oxidized Petroleum Asphalt Human Minimal irritation Solvent Naphtha (Petroleum), Light Aliphatic Rabbit Irritant Butadiene-Styrene-Meta-Divinylbenzene Polymer Professio nal judgeme nt Minimal irritation Styrene-Butadiene Polymer Professio nal judgeme nt No significant irritation Carbon Black Rabbit No significant irritation Methyl Alcohol Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Propane Rabbit Mild irritant Toluene Rabbit Moderate irritant Talc Rabbit No significant irritation Methyl Acetate Rabbit Moderate irritant Asphalt Human Mild irritant Oxidized Petroleum Asphalt Human Mild irritant Solvent Naphtha (Petroleum), Light Aliphatic Rabbit No significant irritation Carbon Black Rabbit No significant irritation Methyl Alcohol Rabbit Moderate irritant Skin Sensitization Name Species Value Toluene Guinea pig Not classified Methyl Acetate Human Not classified Methyl Alcohol Guinea pig Not classified Photosensitization Name Species Value Asphalt Human Not sensitizing Oxidized Petroleum Asphalt Human Not sensitizing Respiratory Sensitization Name Species Value Talc Human Not classified Germ Cell Mutagenicity Name Route Value Propane In Vitro Not mutagenic Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Methyl Acetate In Vitro Not mutagenic Methyl Acetate In vivo Not mutagenic Asphalt In vivo Not mutagenic Asphalt In Vitro Some positive data exist, but the data are not sufficient for classification Oxidized Petroleum Asphalt In vivo Not mutagenic Oxidized Petroleum Asphalt In Vitro Some positive data exist, but the data are not sufficient for classification 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 11 of 15 Solvent Naphtha (Petroleum), Light Aliphatic In Vitro Not mutagenic Dimethyl Ether In Vitro Not mutagenic Dimethyl Ether In vivo Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Asphalt Not Specified Human and animal Some positive data exist, but the data are not sufficient for classification Oxidized Petroleum Asphalt Not Specified Human and animal Some positive data exist, but the data are not sufficient for classification Solvent Naphtha (Petroleum), Light Aliphatic Dermal Mouse Some positive data exist, but the data are not sufficient for classification Dimethyl Ether Inhalation Rat Not carcinogenic Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Methyl Alcohol Inhalation Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Talc Ingestion Not classified for development Rat NOAEL 1,600 mg/kg during organogenesi s Dimethyl Ether Inhalation Not classified for development Rat NOAEL 40,000 ppm during organogenesi s Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600 mg/kg/day 21 days Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 mg/kg/day during organogenesi s Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 12 of 15 Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation Not classified Human NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Methyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl Acetate Inhalation blindness Not classified NOAEL Not available Methyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Solvent Naphtha (Petroleum), Light Aliphatic Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Solvent Naphtha (Petroleum), Light Aliphatic Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Solvent Naphtha (Petroleum), Light Aliphatic Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Dimethyl Ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl Ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 hours Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse Methyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation auditory system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation nervous system May cause damage to organs though prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 13 of 15 Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Not classified Rat NOAEL 18 mg/m3 113 weeks Methyl Acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl Acetate Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL 6.1 mg/l 28 days Asphalt Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Oxidized Petroleum Asphalt Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Dimethyl Ether Inhalation hematopoietic system Not classified Rat NOAEL 25,000 ppm 2 years Dimethyl Ether Inhalation liver Not classified Rat NOAEL 20,000 ppm 30 weeks Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55 mg/l 4 weeks Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1 mg/l 6 weeks Methyl Alcohol Ingestion liver | nervous system Not classified Rat NOAEL 2,500 mg/kg/day 90 days Aspiration Hazard Name Value Toluene Aspiration hazard Solvent Naphtha (Petroleum), Light Aliphatic Aspiration hazard 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 14 of 15 Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Carcinogenicity Reproductive toxicity Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt 3M? Rubberized Undercoating Black, PN 08883 07/01/21 __________________________________________________________________________________________ Page 15 of 15 Toluene 108-88-3 Trade Secret 10 - 30 Benzene 71-43-2 Trade Secret < 0.02 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 27-4303-7 Version Number: 5.04 Issue Date: 07/01/21 Supercedes Date: 12/10/19 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com