SAFETY DATA SHEET 10-4058, 12378514 - ACDelco VERSATRAK? Fluid 75W-85 GL-5 Product name SDS # GM VERSATRAK Fluid #12378514 467853 Code 467853-US89 Relevant identified uses of the substance or mixture and uses advised against Product use Gear lubricant For specific application advice see appropriate Technical Data Sheet or consult our company representative. Manufacturer BP Lubricants USA Inc. 1500 Valley Road Wayne, NJ 07470 Telephone: (973) 633-2200 Telecopier: (973) 633-7475 EMERGENCY HEALTH INFORMATION: 1 (800) 447-8735 Outside the US: +1 703-527-3887 (CHEMTREC) EMERGENCY SPILL INFORMATION: 1 (800) 424-9300 CHEMTREC (USA) OTHER PRODUCT INFORMATION 1 (866) 4 BP - MSDS (866-427-6737 Toll Free - North America) email: This email address is being protected from spambots. You need JavaScript enabled to view it. OSHA/HCS status This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Not classified. GHS label elements Signal word No signal word. Hazard statements No known significant effects or critical hazards. Precautionary statements General Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention Not applicable. Response Not applicable. Storage Not applicable. Disposal Not applicable. Hazards not otherwise classified Defatting to the skin. Section 2. Hazards identification Section 1. Identification Product name Version 1 Product code Format US (US) 467853-US89 Page: 1/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Synthetic base stock. Proprietary performance additives. Substance/mixture Mixture Ingredient name CAS number % Polysulfides, di-tert-Bu 68937-96-2 1-5 amines, C12-14-alkyl, reaction products with hexanol, phosphorus oxide 91745-46-9 1-5 (P2O5), phosphorus sulfide (P2S5) and propylene oxide Base oil - highly refined Varies 1-5 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Description of necessary first aid measures Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention. Skin contact Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if symptoms occur. Inhalation Ingestion If inhaled, remove to fresh air. Get medical attention if symptoms occur. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. Most important symptoms/effects, acute and delayed See Section 11 for more detailed information on health effects and symptoms. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treatment should in general be symptomatic and directed to relieving any effects. Specific treatments No specific treatment. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray. Do not use water jet. Specific hazards arising from the chemical Hazardous combustion products Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst. Combustion products may include the following: carbon dioxide carbon monoxide phosphorus oxides Special protective actions for fire-fighters Special protective equipment for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. Section 5. Fire-fighting measures Section 4. First aid measures Section 3. Composition/information on ingredients Product name Version 1 Product code Format US (US) 467853-US89 Page: 2/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Personal precautions, protective equipment and emergency procedures For non-emergency personnel No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up Small spill Large spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid contact of spilled material and runoff with soil and surface waterways. Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Not suitable Prolonged exposure to elevated temperature. Control parameters Occupational exposure limits Ingredient name Exposure limits Base oil - highly refined ACGIH TLV (United States). TWA: 5 mg/m3 8 hours. Issued/Revised: 11/2009 Form: Inhalable fraction NIOSH REL (United States). TWA: 5 mg/m3 10 hours. Issued/Revised: 6/1994 Form: Mist STEL: 10 mg/m3 15 minutes. Issued/Revised: 6/1994 Form: Mist OSHA PEL (United States). TWA: 5 mg/m3 8 hours. Issued/Revised: 6/1993 Section 8. Exposure controls/personal protection Section 7. Handling and storage Section 6. Accidental release measures Product name Version 1 Product code Format US (US) 467853-US89 Page: 3/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) While specific OELs for certain components may be shown in this section, other components may be present in any mist, vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only. Appropriate engineering controls Environmental exposure controls All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures Eye/face protection Skin protection Hand protection Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses with side shields. Wear protective gloves if prolonged or repeated contact is likely. Wear chemical resistant gloves. Recommended: Nitrile gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/ manufacturer and with a full assessment of the working conditions. Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions. Body protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Section 8. Exposure controls/personal protection Product name Version 1 Product code Format US (US) 467853-US89 Page: 4/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Appearance Physical state Color Odor Odor threshold pH Melting point Liquid. Yellow. Oily Not available. Not available. Not available. Boiling point Not available. Flash point Open cup: 204?C (399.2?F) [Cleveland.] Evaporation rate Not available. Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Density Solubility Partition coefficient: n- octanol/water Auto-ignition temperature Not applicable. Based on - Physical state Not available. Not available. Not available. 880.4 kg/m3 (0.88 g/cm3) at 15?C insoluble in water. >3 Not available. Decomposition temperature Not available. Viscosity Kinematic: 58.6 mm2/s (58.6 cSt) at 40?C Kinematic: 11.5 mm2/s (11.5 cSt) at 100?C Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information. Chemical stability The product is stable. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions to avoid Incompatible materials Avoid all possible sources of ignition (spark or flame). Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Information on toxicological effects Aspiration hazard Information on the likely routes of exposure Potential acute health effects Eye contact Routes of entry anticipated: Dermal, Inhalation. No known significant effects or critical hazards. Name Base oil - highly refined Result ASPIRATION HAZARD - Category 1 Section 11. Toxicological information Section 10. Stability and reactivity Section 9. Physical and chemical properties Product name Version 1 Product code Format US (US) 467853-US89 Page: 5/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Skin contact No known significant effects or critical hazards. Inhalation Vapor inhalation under ambient conditions is not normally a problem due to low vapor pressure. Ingestion No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Skin contact Adverse symptoms may include the following: irritation dryness cracking Inhalation May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal decomposition products occurs. Ingestion No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Not available. Potential delayed effects Not available. Long term exposure Potential immediate effects Not available. Potential delayed effects Not available. Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Toxicity No testing has been performed by the manufacturer. Persistence and degradability Not expected to be rapidly degradable. Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment. Mobility in soil Section 12. Ecological information Route Oral ATE value 38270.2 mg/kg Section 11. Toxicological information Product name Version 1 Product code Format US (US) 467853-US89 Page: 6/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Soil/water partition coefficient (KOC) Not available. Mobility Spillages may penetrate the soil causing ground water contamination. Other adverse effects No known significant effects or critical hazards. Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired. Disposal methods The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information DOT Classification TDG Classification IMDG IATA UN number Not regulated. Not regulated. UN3082 UN3082 UN proper shipping name - - Environmentally hazardous substance, liquid, n.o.s. ( (Z)-octadec- 9-enylamine) Environmentally hazardous substance, liquid, n.o.s. ( (Z)-octadec- 9-enylamine) Transport hazard class(es) - - 9 9 Packing group - - III III Environmental hazards No. No. Yes. Yes. Additional information - - The marine pollutant mark is not required when transported in sizes of ::5 L or ::5 kg. Emergency schedules (EmS) F-A, S-F The environmentally hazardous substance mark is not required when transported in sizes of ::5 L or ::5 kg. Section 13. Disposal considerations Section 12. Ecological information Product name Version 1 Product code Format US (US) 467853-US89 Page: 7/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not available. Not available. U.S. Federal regulations United States inventory (TSCA 8b) SARA 302/304 All components are listed or exempted. Composition/information on ingredients No products were found. SARA 311/312 Classification Immediate (acute) health hazard Delayed (chronic) health hazard SARA 313 Form R - Reporting requirements Supplier notification State regulations Massachusetts This product does not contain any hazardous ingredients at or above regulated thresholds. This product does not contain any hazardous ingredients at or above regulated thresholds. None of the components are listed. New Jersey None of the components are listed. Pennsylvania None of the components are listed. California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer. cumene; 4-methylpentan-2-one; Ethyl acrylate; Arsenic; Ethylbenzene WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Toluene Other regulations Australia inventory (AICS) WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Benzene; lead; Cadmium (Non-pyrophoric) All components are listed or exempted. Canada inventory All components are listed or exempted. China inventory (IECSC) Japan inventory (ENCS) Korea inventory (KECI) Philippines inventory (PICCS) Not determined. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. REACH Status The company, as identified in Section 1, sells this product in the EU in compliance with the current requirements of REACH. Section 15. Regulatory information Section 14. Transport information Product name Version 1 Product code Format US (US) 467853-US89 Page: 8/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Hazardous Material Information System (U.S.A.) Health * 2 Flammability 1 Physical hazards 0 Personal protection x Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. National Fire Protection Association (U.S.A.) Health 1 Flammability 2 0 Instability/Reactivity Special History Date of issue/Date of revision Date of previous issue 04/18/2014. No previous validation. Key to abbreviations ACGIH = American Conference of Industrial Hygienists ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor CAS Number = Chemical Abstracts Service Registry Number GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OEL = Occupational Exposure Limit SDS = Safety Data Sheet STEL = Short term exposure limit TWA = Time weighted average UN = United Nations UN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods. Indicates information that has changed from previously issued version. Notice to reader All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet. The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited. Section 16. Other information Product name Version 1 Product code Format US (US) 467853-US89 Page: 9/9 GM VERSATRAK Fluid #12378514 Date of issue 04/18/2014. Language ENGLISH (ENGLISH) Product name SDS # Relevant identified uses of the substance or mixture and uses advised against Product use Gear lubricant EMERGENCY HEALTH INFORMATION: EMERGENCY SPILL INFORMATION: OTHER PRODUCT INFORMATION Classification of the substance or mixture GHS label elements Precautionary statements Hazards not otherwise classified Substance/mixture There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Inhalation Ingestion Most important symptoms/effects, acute and delayed Extinguishing media Specific hazards arising from the chemical Special protective actions for fire-fighters Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Precautions for safe handling Advice on general occupational hygiene Control parameters Occupational exposure limits Appropriate engineering controls Individual protection measures Hygiene measures Respiratory protection Appearance Physical state Color Flash point Flammability (solid, gas) Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition Information on toxicological effects Aspiration hazard Ingestion Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Long term exposure Potential chronic health effects Numerical measures of toxicity Acute toxicity estimates Persistence and degradability Bioaccumulative potential Mobility in soil Disposal methods Special precautions for user U.S. Federal regulations SARA 302/304 Composition/information on ingredients SARA 311/312 SARA 313 Other regulations Hazardous Material Information System (U.S.A.) Indicates information that has changed from previously issued version.