Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.1200), Health Canada HPR (SOR/2015-17), and Mexico NOM-018-STPS-2015 SECTION 1: Identification Product Identifier: atp? AT-200 Cooler Flush Code: 830381 Issue date: 19-Aug-2021 Relevant identified uses: Transmission System Flush Uses advised against: All others 24 Hour Emergency Phone Number: CHEMTREC Global +1 703 527 3887 CHEMTREC United States 1-800-424-9300 CHEMTREC Mexico 01-800-681-9531 Manufacturer/Supplier: Phillips 66 Spectrum Corporation 500 Industrial Park Drive Selmer, TN 38375-3276 United States of America SDS Information: URL: www.phillips66.com/SDS Phone: 800-762-0942 Email: This email address is being protected from spambots. You need JavaScript enabled to view it. Technical Information: 1-800-264-6457 or +1-731-645-4972 SECTION 2: Hazard identification Classified Hazards Hazards Not Otherwise Classified (HNOC) H222 - Extremely flammable aerosol -- Category 1 H229 - Pressurized container: May burst if heated H304 -- Aspiration Hazard -- Category 1 H315 -- Skin corrosion/irritation -- Category 2 H319 -- Eye damage/irritation -- Category 2A H336 -- Specific target organ toxicity (single exposure) -- Category 3 (Central Nervous System (CNS)) H411 -- Hazardous to the aquatic environment, chronic toxicity -- Category 2 PHNOC: None known HHNOC: None known Label elements DANGER H222 - Extremely flammable aerosol H229 - Pressurized container: May burst if heated H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H411 - Toxic to aquatic life with long lasting effects P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking; P211 - Do not spray on an open flame or other ignition source; P251 - Pressurized container: Do not pierce or burn, even after use; P261 - Avoid breathing dust/fume/gas/mist/vapors/spray; P264 - Wash skin thoroughly after handling; P271 - Use only outdoors or in a well-ventilated area; P273 - Avoid release to the environment; P280 - Wear protective gloves/protective clothing and eye/face protection; P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician; P331 - Do NOT induce vomiting; P302 + P352 - IF ON SKIN: Wash with plenty of soap and water; P332 + P313 - If skin irritation occurs: Get medical advice/attention; P362 - Take off contaminated clothing and wash before reuse; P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing; P312 - Call a POISON CENTER or doctor/physician if you feel unwell; P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing; P337 + P313 - If eye irritation persists: Get medical advice/attention; P391 - Collect spillage; P403 + P233 - Store in a well-ventilated place. Keep container tightly closed; P405 - Store locked up; P410 - Protect from sunlight; P412 - Do not expose to temperatures exceeding 50 ?C/122 ?F; P501 - Dispose of contents/ container to an approved waste disposal plant _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 1/9 Issue date: 19-Aug-2021 Status: FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 2/9 Issue date: 19-Aug-2021 Status: FINAL SECTION 4: First aid measures Eye Contact: For direct contact, remove contact lenses if present and easy to do. Immediately hold eyelids apart and flush the affected eye(s) with clean water for at least 20 minutes. Seek immediate medical attention. Skin Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse. Inhalation: If respiratory symptoms develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. If breathing is difficult, oxygen or artificial respiration should be administered by qualified personnel. If symptoms persist, seek medical attention. Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek medical attention. Most important symptoms and effects, both acute and delayed: While significant vapor concentrations are not likely, high concentrations can cause minor respiratory irritation, headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Ingestion can cause irritation of the digestive tract, nausea, diarrhea, and vomiting. Light hydrocarbon gases are simple asphyxiants and can cause anesthetic effects at high concentrations. Symptoms of overexposure, which are reversible if exposure is stopped, can include shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting. Continued exposure can lead to hypoxia (inadequate oxygen), rapid breathing, cyanosis (bluish discoloration of the skin), numbness of the extremities, unconsciousness and death. Prolonged or repeated contact may dry skin and cause irritation. Notes to Physician: Treat according to symptoms. SECTION 5: Firefighting measures NFPA 704: National Fire Protection Association Extinguishing Media: Dry chemical, carbon dioxide, or foam is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Water may be ineffective for extinguishment, unless used under favorable conditions by experienced fire fighters. Specific hazards arising from the chemical SECTION 3: Composition/information on ingredients Substance CASRN Concentration? Petroleum distillates, hydrotreated light 64742-47-8 20-40 Solvent naphtha, petroleum, heavy aliphatic 64742-96-7 20-40 Isopropyl alcohol 67-63-0 1-20 Petroleum gases, liquefied, sweetened 68476-86-8 1-20 Solvent naphtha, petroleum, light aliphatic 64742-89-8 1-20 Naphtha, petroleum, heavy alkylate 64741-65-7 1-20 ? All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Health: 2 Flammability: 4 Instability: 0 0 = minimal hazard 1 = slight hazard 2 = moderate hazard 3 = severe hazard 4 = extreme hazard _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 2/9 Issue date: 19-Aug-2021 Status: FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 3/9 Issue date: 19-Aug-2021 Status: FINAL Unusual Fire & Explosion Hazards: Contents under pressure. Extremely flammable. This material can be ignited by heat, sparks, flames, or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, and electronic devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically safe) Vapors may travel considerable distances to a source of ignition where they can ignite, flash back, or explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. This product will float and can be reignited on surface water. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire. Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of nitrogen and sulfur may also be formed. Special protective actions for fire-fighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Avoid spreading burning liquid with water used for cooling purposes. Cool equipment exposed to fire with water, if it can be done safely. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Extremely flammable. Spillages of liquid product will create a fire hazard and may form an explosive atmosphere. Keep all sources of ignition and hot metal surfaces away from spill/release if safe to do so. The use of explosion-proof electrical equipment is recommended. Stay upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). See Sections 2 and 7 for additional information on hazards and precautionary measures. Environmental Precautions: Stop and contain spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use foam on spills to minimize vapors Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicable regulations. Recommended measures are based on the most likely spillage scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. SECTION 7: Handling and storage Precautions for safe handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Use non-sparking tools. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Avoid contact with eyes. Avoid contact with skin. Do not breathe vapor or mist. Use only with adequate ventilation. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use good personal hygiene practices and wear appropriate personal protective equipment (see section 8). Extremely Flammable. Contents under pressure. Open container slowly to relieve any pressure. May vaporize easily at ambient temperatures. The vapor is heavier than air and may create an explosive mixture of vapor and air. Beware of accumulation in confined spaces and low lying areas. Electrostatic charge may accumulate and create a hazardous condition when handling or processing this material. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. The use of explosion-proof electrical equipment is recommended and may be required (see appropriate fire codes). Refer to NFPA-70 and/or API RP 2003 for specific bonding/grounding requirements. Do not wear contaminated clothing or shoes. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Keep contaminated clothing away from sources of ignition such as sparks or open flames. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 3/9 Issue date: 19-Aug-2021 Status: FINAL Conditions for safe storage: Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved containers. Post area "No Smoking or Open Flame." Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Outdoor or detached storage is preferred. Indoor storage should meet Country or Committee _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 4/9 Issue date: 19-Aug-2021 Status: FINAL standards and appropriate fire codes. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Keep container tightly closed in a dry and well-ventilated place P102 - Keep out of reach of children Store locked up SECTION 8: Exposure controls/personal protection Substance ACGIH OSHA Mexico Phillips 66 Petroleum distillates, hydrotreated light --- --- --- TWA-8hr: 200 mg/m3 Skin Solvent naphtha, petroleum, heavy aliphatic --- --- --- TWA-8hr: 200 mg/m3 Skin Isopropyl alcohol TWA-8hr: 200 ppm STEL: 400 ppm TWA-8hr: 400 ppm TWA-8hr: 980 mg/m3 TWA-8hr: 200 ppm (VLE-PPT) STEL: 400 ppm (PPT-CT) --- Petroleum gases, liquefied, sweetened STEL: 1000 ppm Butane, isomers --- --- --- Naphtha, petroleum, heavy alkylate --- --- --- TWA-8hr: 450 mg/m3 STEL: 1100 mg/m3 Skin State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Substance ACGIH Mexican NOM-047-SSA1-2011 Isopropyl alcohol Acetone in urine: 40 mg/L (end of shift at end of workweek) Acetone in urine: 40 mg/L (end of shift at end of work week) State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. Eye/Face Protection: The use of eye protection (such as splash goggles) that meets or exceeds ANSI Z.87.1 is recommended when there is potential liquid contact to the eye. Depending on conditions of use, a face shield may be necessary. Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits. Suggested protective materials: Butyl rubber Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with organic vapor cartridges/canisters with R or P95 filters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. A NIOSH approved, self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode should be used in situations of oxygen deficiency (oxygen content less than 19.5 percent), unknown exposure concentrations, or situations that are immediately dangerous to life or health (IDLH). Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. Biological occupational exposure limits _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 4/9 Issue date: 19-Aug-2021 Status: FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 5/9 Issue date: 19-Aug-2021 Status: FINAL equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. SECTION 9: Physical and chemical properties Note: Unless otherwise stated, values are determined at 20?C (68?F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. Appearance: clear, Colorless Physical form of product: Aerosol Odor: Petroleum Solvent Odor threshold: No data pH: Not applicable Melting / freezing point: No data Initial boiling point and boiling range: No data Flash point: No data Method: Not applicable Evaporation Rate (nBuAc=1): No data Flammability (solid, gas): Not applicable Upper Explosive Limits (vol % in air): No data Lower Explosive Limits (vol % in air): No data Vapor pressure: No data Vapor density: >1 (air = 1) Relative density: 0.87 (water = 1) Solubility(ies): Negligible Partition coefficient n-octanol /water (log KOW): No data Autoignition temperature: 449 ?F / 232 ?C Decomposition temperature: No data Viscosity: No data Molecular weight: No data Other information Particle Size: No data Pour point: No data Bulk density No data VOC content (%): 20-30 SECTION 10: Stability and reactivity Reactivity: Not chemically reactive. Chemical stability: Stable under normal ambient and anticipated conditions of use. Possibility of Hazardous Reactions: Hazardous reactions not anticipated. Conditions to Avoid: Avoid all possible sources of ignition. Extremes of temperature and direct sunlight Prevent vapor accumulation. Incompatible Materials: Avoid contact with strong oxidizing agents and strong reducing agents. strong acids, strong bases. Hazardous Decomposition Products: Not anticipated under normal conditions of use. SECTION 11: Toxicological information Information on Toxicological Effects Substance / Mixture Acute Toxicity Hazard Additional Information LC50/LD50 Data Inhalation Unlikely to be harmful Simple Asphyxiant. May >5 mg/L (mist, estimated) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 5/9 Issue date: 19-Aug-2021 Status: FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 6/9 Issue date: 19-Aug-2021 Status: FINAL Likely Routes of Exposure: Inhalation, eye contact, skin contact Aspiration Hazard: May be fatal if swallowed and enters airways Skin Corrosion/Irritation: Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Causes serious eye irritation. Skin Sensitization: Not expected to be a skin sensitizer. Respiratory Sensitization: No information available on the mixture, however none of the components have been classified for respiratory sensitization (or are below the concentration threshold for classification). Specific target organ toxicity - Single exposure: May cause drowsiness and dizziness. Specific target organ toxicity - Repeated exposure: No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification). Carcinogenicity: No information available on the mixture, however none of the components have been classified for carcinogenicity (or are below the concentration threshold for classification). Germ Cell Mutagenicity: No information available on the mixture, however none of the components have been classified for germ cell mutagenicity (or are below the concentration threshold for classification). Reproductive Toxicity: No information available on the mixture, however none of the components have been classified for reproductive toxicity (or are below the concentration threshold for classification). Other Comments: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage (sometimes referred to as Solvent or Painters' Syndrome). Intentional misuse by deliberately concentrating and inhaling this material may be harmful or fatal. High concentrations may reduce the amount of oxygen available for breathing, especially in confined spaces. Hypoxia (inadequate oxygen) during pregnancy may have adverse effects on the developing fetus. Information on Toxicological Effects of Components Petroleum distillates, hydrotreated light Reproductive Toxicity: Hydrodesulfurized kerosene applied to the skin of female rats at 494, 330, or 165 mg/kg daily for 7 consecutive weeks (premating, mating, and gestation), or for 8 consecutive weeks in males did not result in systemic, reproductive, or developmental toxicity. Petroleum gases, liquefied, sweetened Reproductive Toxicity: No adverse developmental effects were observed in rats exposed to concentrations of isobutane as high as 9000 ppm. Fertility and mating indices may have been affected at 9000 ppm but no effects were observed at 3000 ppm (NOAEL). Target Organ(s): No systemic or neurotoxic effects were noted in rats exposed to concentrations of isobutane as high as 9,000 ppm for 28 days. Solvent naphtha, petroleum, light aliphatic Carcinogenicity Information : Two year inhalation studies of vaporized unleaded gasoline produced an increased incidence of kidney tumors in male rats and liver tumors in female mice. Repeated skin application of various petroleum naphthas in mice for two years resulted in an increased incidence of skin tumors but only in the presence of severe skin irritation. Follow-up mechanistic studies suggest that the occurrence of these tumors may be the consequence of promotional processes and not relevant to human risk assessment. Epidemiology data collected from a study of more than 18,000 petroleum marketing and distribution workers showed no increased risk of leukemia, multiple myeloma, or kidney cancer from gasoline exposure. Unleaded gasoline has been identified as a possible carcinogen by the International Agency for Research on Cancer. Reproductive Toxicity: No evidence of developmental toxicity was found in pregnant laboratory animals (rats and mice) exposed to high vapor concentrations of unleaded gasoline and petroleum naphthas via inhalation. A two-generation displace oxygen and cause rapid suffocation. See section 4 for more information. Dermal Unlikely to be harmful > 2 g/kg (estimated) Oral Unlikely to be harmful > 5 g/kg (estimated) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 6/9 Issue date: 19-Aug-2021 Status: FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 7/9 Issue date: 19-Aug-2021 Status: FINAL reproductive toxicity study of vapor recovery gasoline did not adversely affect reproductive function or offspring survival and development. Target Organ(s): Two year inhalation studies of wholly vaporized unleaded gasoline, and 90 days studies of various petroleum naphthas, did not produce significant target organ toxicity in laboratory animals. Nephropathy in male rats, characterized by the accumulation of alpha-2-u- globulin in epithelial cells of the proximal tubules was observed, however follow-up studies suggest that these changes are unique to the male rat. Naphtha, petroleum, heavy alkylate Carcinogenicity Information : Two year inhalation studies of vaporized unleaded gasoline produced an increased incidence of kidney tumors in male rats and liver tumors in female mice. Repeated skin application of various petroleum naphthas in mice for two years resulted in an increased incidence of skin tumors but only in the presence of severe skin irritation. Follow-up mechanistic studies suggest that the occurrence of these tumors may be the consequence of promotional processes and not relevant to human risk assessment. Epidemiology data collected from a study of more than 18,000 petroleum marketing and distribution workers showed no increased risk of leukemia, multiple myeloma, or kidney cancer from gasoline exposure. Unleaded gasoline has been identified as a possible carcinogen by the International Agency for Research on Cancer. Reproductive Toxicity: No evidence of developmental toxicity was found in pregnant laboratory animals (rats and mice) exposed to high vapor concentrations of unleaded gasoline and petroleum naphthas via inhalation. A two-generation reproductive toxicity study of vapor recovery gasoline did not adversely affect reproductive function or offspring survival and development. Target Organ(s): Two year inhalation studies of wholly vaporized unleaded gasoline, and 90 days studies of various petroleum naphthas, did not produce significant target organ toxicity in laboratory animals. Nephropathy in male rats, characterized by the accumulation of alpha-2-u- globulin in epithelial cells of the proximal tubules was observed, however follow-up studies suggest that these changes are unique to the male rat. SECTION 12: Ecological information Toxicity: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable but are regarded as inherently biodegradable since their hydrocarbon components can be degraded by microorganisms. Bioaccumulative Potential: Hydrocarbon constituents of kerosine show measured or predicted Log Kow values ranging from 3 to 6 and above and therefore would be regarded as having the potential to bioaccumulate. In practice, metabolic processes may reduce bioconcentration. Mobility in Soil: On release to water, hydrocarbons will float on the surface and since they are sparingly soluble, the only significant loss is volatilization to air. It is possible that some of the higher molecular weight hydrocarbons will be adsorbed on sediment. Biodegradation in water is a minor loss process. In air, these hydrocarbons are photodegraded by reaction with hydroxyl radicals with half lives varying from 0.1 to 0.7 days. Other adverse effects: None anticipated. SECTION 13: Disposal considerations The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would be a federally regulated RCRA "listed" hazardous waste, and identified as the EPA hazardous waste number shown below. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the SDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste.Container contents should be completely used and containers should be emptied prior to discard. Container residues and rinseates could be considered to be hazardous wastes. EPA Waste Number(s) ? D001 - Ignitability characteristic _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 7/9 Issue date: 19-Aug-2021 Status: FINAL GHS Classification: H411 -- Hazardous to the aquatic environment, chronic toxicity -- Category 2 Toxic to aquatic life with long lasting effects. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 8/9 Issue date: 19-Aug-2021 Status: FINAL SECTION 14: Transport information UN Number: UN1950 UN proper shipping name: Aerosols, flammable, LTD. QTY Transport hazard class(es): 2.1 Packing Group: None Environmental Hazard(s): Marine pollutant - Environmentally Hazardous Special precautions for user: Container(s) greater than 5 liters (liquids) or 5 kilograms (solids), shipped by water mode and ALL bulk shipments may require the shipping description to contain the "Marine Pollutant" notation [49 CFR 172.203(l)] and the container(s) to display the [Marine Pollutant Mark] [49 CFR 172.322]. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable SECTION 15: Regulatory information CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds) This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/312 (Title III Hazard Categories) Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications. CERCLA/SARA - Section 313 and 40 CFR 372 This material contains the following chemicals subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR 372: Substance Concentration? de minimis Isopropyl alcohol 1-20 1.0% ? All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. EPA (CERCLA) Reportable Quantity (in pounds) This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65 This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm at concentrations that trigger the warning requirements of California Proposition 65. SECTION 16: Other information Mexican NOM-018-STPS-2015: The information within is considered correct but is not exhaustive and will be used for guidance only, which is based on the current knowledge of the substance or mixture and is applicable to the appropriate safety precautions for the product. Precautionary Statements P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash skin thoroughly after handling Revised Sections or Basis for Revision: Identified Hazards (Section 2); Precautionary Statement(s) (Section 2); Composition (Section 3); First Aid (Section 4); NFPA ratings (Sections 5); Exposure limits (Section 8); Physical Properties (Section 9); Toxicological (Section 11); Environmental hazards (Section 12); Shipping information (Section 14); Regulatory information (Section 15) Issue date Previous Issue Date: SDS Number Status: 19-Aug-2021 05-Mar-2019 830381 FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 8/9 Issue date: 19-Aug-2021 Status: FINAL _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 9/9 Issue date: 19-Aug-2021 Status: FINAL P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing and eye/face protection P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P331 - Do NOT induce vomiting P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention P391 - Collect spillage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P410 - Protect from sunlight P412 - Do not expose to temperatures exceeding 50 ?C/122 ?F P501 - Dispose of contents/ container to an approved waste disposal plant Guide to Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; GHS = Globally Harmonized System; HPR = Hazardous Products Regulations; IARC = International Agency for Research on Cancer; INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Disclaimer of Expressed and implied Warranties: The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 830381 - atp? AT-200 Cooler Flush Page 9/9 Issue date: 19-Aug-2021 Status: FINAL