Safety Data Sheet Issue Date: 8-Sep-22 Revision Date: New Version 1 _____________________________________________________________________________________________ Page 1 / 9 1. IDENTIFICATION Product identifier Product Name SPLASH -75?F RV and Marine Antifreeze Other means of identification SDS/Part # 619533-35 UN/ID No UN1170 Recommended use of the chemical and restrictions on use Recommended Use Anti-freeze. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Red liquid Physical state Liquid Odor Slight alcohol Classification Serious eye damage/eye irritation Category 2 Flammable liquids Category 3 Signal Word Warning Hazard statements Causes serious eye irritation Flammable liquid and vapor SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 9 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Use explosion-proof equipment Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Ethyl Alcohol 64-17-5 10-15 Glycerol 56-81-5 1-5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Inhalation Remove to fresh air. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms Causes serious eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 9 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use CO2, dry chemical, or foam for extinction. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Flammable liquid and vapor. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Use explosion proof equipment. Conditions for safe storage, including any incompatibilities Storage Conditions Store in a well-ventilated place. Keep cool. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 9 Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Glycerol 56-81-5 - TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Red liquid Odor Slight alcohol Color Red Odor Threshold Not determined Property Values Remarks ? Method pH Not determined Melting point / freezing point -9.67 ?C / 14.6 ?F Boiling point / boiling range Not determined Flash point 42.5 ?C / 108.5 ?F (based on components) Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits Not determined Lower flammability or explosive limits Not determined Vapor Pressure Not determined Vapor Density Not determined Relative Density 0.9904 Water Solubility Complete Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 9 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethyl Alcohol 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Glycerol 56-81-5 = 12600 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) > 2.75 mg/L ( Rat ) 4 h Propylene Glycol 57-55-6 = 20 g/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Serious eye damage/eye irritation Causes serious eye irritation. SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 9 Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage. Chemical name ACGIH IARC NTP OSHA Ethyl Alcohol 64-17-5 A3 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 43,531.2814 mg/kg ATEmix (inhalation-dust/mist) 64.30 mg/L 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical name Algae/aquatic plants Fish Crustacea Ethyl Alcohol 64-17-5 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static Glycerol 56-81-5 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static Propylene Glycol 57-55-6 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 Static Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient Ethyl Alcohol 64-17-5 -0.32 Glycerol 56-81-5 -1.76 Other Adverse Effects SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 9 Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical name California Hazardous Waste Status Ethyl Alcohol 64-17-5 Toxic Ignitable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated if shipped in NON BULK packaging (single containers less than 119 gal/ 882 lbs) by ground transport BULK Packaging (single containers larger than 119 gal/ 882 lbs): UN/ID No UN1170 Proper Shipping Name Ethanol solutions Hazard class 3 Packing Group III IATA Please refer to IATA DGR for limited quantity information. UN number UN1170 Proper Shipping Name Ethanol solutions Transport hazard class(es) 3 Packing Group III IMDG Packages with inner packagings not over 5 liters/5kg may be reclassified as a Limited Quantity UN number UN1170 Proper Shipping Name Ethanol solutions Transport hazard class(es) 3 Packing Group III 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS Ethyl Alcohol X ACTIVE X X X X X X X Glycerol X ACTIVE X X X X X X X Propylene Glycol X ACTIVE X X X X X X X SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 9 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical name California Proposition 65 Ethyl Alcohol - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Ethyl Alcohol 64-17-5 X X X Glycerol 56-81-5 X X X Propylene Glycol 57-55-6 X X SPLASH -75?F RV and Marine Antifreeze Revision Date: New _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 9 / 9 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 8-Sep-22 Revision Date: New Revision Note: New Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet