SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 1 / 16 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : ZEREX? ORIGINAL Antifreeze Coolant Product code : ZX001 Relevant identified uses of the substance or mixture and uses advised against Recommended use : Coolant and antifreeze. Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number +1-800-VALVOLINE (+1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Acute toxicity (Oral) : Category 4 Reproductive toxicity : Category 1B Specific target organ toxicity - repeated exposure (Oral) : Category 2 (Kidney, Liver) GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H302 Harmful if swallowed. H360 May damage fertility or the unborn child. H373 May cause damage to organs (Kidney, Liver) through prolonged or repeated exposure if swallowed. SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 2 / 16 Precautionary statements : Prevention: P203 Obtain, read and follow all safety instructions before use. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. Response: P301 + P317 + P330 IF SWALLOWED: Get medical help. Rinse mouth. P318 IF exposed or concerned, get medical advice. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification No information available. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) ETHYLENE GLYCOL 107-21-1 Acute Tox. 4; H302 Acute Tox. 4; H302 Acute Tox. 4; H302 Acute Tox. 4; H302 STOT RE 2; H373 >= 90.00 - <= 100.00 2,2'-oxybis-Ethanol 111-46-6 Acute Tox. 4; H302 STOT RE 2; H373 >= 1.00 - < 5.00 DISODIUM TETRABORATE 1330-43-4 Repr. 1B; H360 Aquatic Acute 3; H402 >= 0.10 - < 1.00 SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 3 / 16 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Induce vomiting immediately and call a physician. Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. Most important symptoms and effects, both acute and delayed : Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachypnia, tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post- exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Harmful if swallowed. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure if swallowed. SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 4 / 16 No symptoms known or expected. Notes to physician : This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86- proof or higher whiskey before or during transport to the hospital. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. No hazards which require special first aid measures. Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : No hazardous combustion products are known Specific extinguishing methods : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 5 / 16 respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ETHYLENE GLYCOL 107-21-1 CMP-C (aerosol) 100 mg/m3 aerosol AR OEL TWA 25 ppm Vapour ACGIH STEL 50 ppm Vapour ACGIH STEL 10 mg/m3 Inhalable fraction, Aerosol only ACGIH SODIUM BORATE 1303-96-4 CMP 5 mg/m3 AR OEL SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 6 / 16 DECAHYDRATE TWA 2 mg/m3 Inhalable particulate matter (Borate) ACGIH STEL 6 mg/m3 Inhalable particulate matter (Borate) ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : green Odour : No data available Odour Threshold : No data available pH : 9 - < 11 Melting point/freezing point : No data available Boiling point/boiling range : 197.6 ?C (1,013.232 hPa) Calculated Phase Transition Liquid/Gas Flash point : > 111 ?C Evaporation rate : No data available SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 7 / 16 Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : 15.3 %(V) GLP: Calculated Explosive Limit Lower explosion limit / Lower flammability limit : 3.2 %(V) GLP: Calculated Explosive Limit Vapour pressure : 0.12265 hPa (25 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 1.1205 g/cm3 (15.6 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reactions : No decomposition if stored and applied as directed. Conditions to avoid : No data available Incompatible materials : Aldehydes SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 8 / 16 Alkali metals Alkaline earth metals Strong acids strong alkalis Strong oxidizing agents Sulphur compounds Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Harmful if swallowed. Product: Acute oral toxicity : Acute toxicity estimate : 522.35 mg/kg Method: Calculation method Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: ETHYLENE GLYCOL: Acute oral toxicity : LD0 (Human): estimated 1.56 g/kg Assessment: The component/mixture is moderately toxic after single ingestion. Acute inhalation toxicity : LC50 (Rat): 10.9 mg/l Exposure time: 1 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): 9,530 mg/kg Acute toxicity (other routes of administration) : LD50 (Rat): 5,010 mg/kg Application Route: Intraperitoneal LD50 (Rat): 3,260 mg/kg Application Route: Intravenous 2,2'-oxybis-Ethanol: Acute oral toxicity : LD50 (Human): Expected 1,120 mg/kg Target Organs: Kidney Acute inhalation toxicity : LC50 (Rat): > 4.6 mg/l Exposure time: 4 h SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 9 / 16 Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): 13,300 mg/kg DISODIUM TETRABORATE: Acute inhalation toxicity : LC50 (Rat): > 2.03 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Skin corrosion/irritation Not classified based on available information. Components: ETHYLENE GLYCOL: Species: Rabbit Result: No skin irritation 2,2'-oxybis-Ethanol: Species: Human Result: Slight, transient irritation DISODIUM TETRABORATE: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. Components: ETHYLENE GLYCOL: Result: Slight, transient irritation 2,2'-oxybis-Ethanol: Species: Rabbit Result: Slight, transient irritation DISODIUM TETRABORATE: Result: Slight, transient irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 10 / 16 Components: ETHYLENE GLYCOL: Test Type: Maximisation Test Species: Guinea pig Assessment: Does not cause skin sensitisation. 2,2'-oxybis-Ethanol: Test Type: Maximisation Test Species: Guinea pig Method: Directive 67/548/EEC, Annex V, B.6. Result: Did not cause sensitisation on laboratory animals. DISODIUM TETRABORATE: Test Type: Buehler Test Species: Guinea pig Assessment: Does not cause skin sensitisation. Method: OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Components: ETHYLENE GLYCOL: Genotoxicity in vitro : Test Type: Ames test Test species: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative 2,2'-oxybis-Ethanol: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative GLP: yes : Test species: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: negative GLP: yes Genotoxicity in vivo : Test Type: In vivo micronucleus test Test species: Mouse Method: OECD Test Guideline 474 Result: negative GLP: yes Carcinogenicity Not classified based on available information. SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 11 / 16 Reproductive toxicity May damage fertility or the unborn child. Components: DISODIUM TETRABORATE: Reproductive toxicity - Assessment : Clear evidence of adverse effects on sexual function and fertility, and/or on development, based on animal experiments STOT - single exposure Not classified based on available information. STOT - repeated exposure May cause damage to organs (Kidney, Liver) through prolonged or repeated exposure if swallowed. Components: ETHYLENE GLYCOL: Exposure routes: Ingestion Target Organs: Kidney, Liver Assessment: May cause damage to organs through prolonged or repeated exposure. 2,2'-oxybis-Ethanol: Exposure routes: Ingestion Target Organs: Kidney Assessment: May cause damage to organs through prolonged or repeated exposure. Aspiration toxicity Not classified based on available information. Experience with human exposure Components: 2,2'-oxybis-Ethanol: Liver Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. Components: ETHYLENE GLYCOL: Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 27,540 mg/l Exposure time: 96 h Test Type: static test SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 12 / 16 LC50 (Pimephales promelas (fathead minnow)): 8,050 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 6,500 - 13,000 mg/l End point: Growth inhibition Exposure time: 7 Days Toxicity to fish (Chronic toxicity) : NOEC (Pimephales promelas (fathead minnow)): 32,000 mg/l Exposure time: 7 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 24,000 mg/l Exposure time: 7 d Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. 2,2'-oxybis-Ethanol: Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h Test Type: static test Method: DIN 38412 DISODIUM TETRABORATE: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 79.7 mg/l Exposure time: 96 h Remarks: Information refers to the main component. Toxicity to algae : NOEC (Pseudokirchneriella subcapitata (green algae)): 17.5 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 Remarks: Information refers to the main component. Toxicity to fish (Chronic toxicity) : NOEC (Danio rerio (zebra fish)): 5.6 mg/l Exposure time: 34 d Test Type: semi-static test Method: OECD Test Guideline 210 SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 13 / 16 Remarks: Information refers to the main component. Persistence and degradability Components: ETHYLENE GLYCOL: Biodegradability : Result: Readily biodegradable. Biodegradation: 90 - 100 % Exposure time: 10 d Method: OECD Test Guideline 301 2,2'-oxybis-Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 70 - 80 % Exposure time: 28 d Method: OECD Test Guideline 301B No data available Bioaccumulative potential Components: ETHYLENE GLYCOL: Bioaccumulation : Species: Crayfish (Procambarus) Bioconcentration factor (BCF): 0.27 Exposure time: 61 d Concentration: 1000 mg/l Method: Flow through Partition coefficient: n- octanol/water : log Pow: -1.36 2,2'-oxybis-Ethanol: Bioaccumulation : Species: Leuciscus idus (Golden orfe) Bioconcentration factor (BCF): 100 Partition coefficient: n- octanol/water : log Pow: -1.47 No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : No data available Components: SECTION 13. DISPOSAL CONSIDERATIONS SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 14 / 16 Disposal methods General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Control of precursors and essential chemicals for the preparation of drugs. : Contact your sales representative for additional information. The components of this product are reported in the following inventories: TCSI : Not in compliance with the inventory TSCA : All substances listed as active on the TSCA inventory AIIC : Not in compliance with the inventory DSL : All components of this product are on the Canadian DSL ENCS : Not in compliance with the inventory SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 15 / 16 ISHL : Not in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : Not in compliance with the inventory TECI : Not in compliance with the inventory Inventories AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TECI (Thailand), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Internal information : 000000139197 Full text of H-Statements H302 Harmful if swallowed. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure if swallowed. H402 Harmful to aquatic life. Other information : The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1- 800-VALVOLINE). Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. SAFETY DATA SHEET ZEREX? ORIGINAL Antifreeze Coolant Version: 1.1 Revision Date: 2021/11/04 Print Date: 06/21/2023 16 / 16 List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level