SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 1 / 13 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? Durablend? SAE 10W-40 Motor Oil Product code : VV301 Relevant identified uses of the substance or mixture and uses advised against Recommended use : Motor Oil Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Defatter Hazardous components Chemical name CAS-No. Classification Concentration (%) DISTILLATES (PETROLEUM), 64742-54-7 Not a hazardous >=40.00 - < 50.00 SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 2 / 13 HYDROTREATED HEAVY PARAFFINIC substance or mixture. Distillates, petroleum, solvent- refined heavy paraffinic 64741-88-4 Not a hazardous substance or mixture. >=5.00 - < 10.00 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : No hazards which require special first aid measures. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. In case of eye contact : Remove contact lenses. Protect unharmed eye. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 3 / 13 Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Materials to avoid : No materials to be especially mentioned. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 ACGIH SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 4 / 13 Inhalable particulate matter TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL Distillates, petroleum, solvent- refined heavy paraffinic 64741-88-4 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 Inhalable particulate matter ACGIH TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL Engineering measures : General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: Safety shoes Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : General industrial hygiene practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 5 / 13 Appearance : liquid Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : 662 ?F / 350 ?C Calculated Phase Transition Liquid/Gas Flash point : > 394 ?F / > 201 ?C Method: Cleveland open cup Evaporation rate : No data available Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : No data available No data available Lower explosion limit / Lower flammability limit : No data available No data available Vapour pressure : 3 hPa (77 ?F / 25 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.868 g/cm3 Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 6 / 13 Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : > 21 mm2/s (104 ?F / 40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : None known. None known. Incompatible materials : Strong oxidizing agents Hazardous decomposition products No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg Distillates, petroleum, solvent-refined heavy paraffinic: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.58 mg/l Exposure time: 4 h SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 7 / 13 Test atmosphere: dust/mist Assessment: Not classified as acutely toxic by inhalation under GHS. Remarks: No mortality observed at this dose. Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Remarks: No mortality observed at this dose. Skin corrosion/irritation Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation Distillates, petroleum, solvent-refined heavy paraffinic: Species : Rabbit Result : No skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Remarks : Unlikely to cause eye irritation or injury. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result : No eye irritation Assessment : No eye irritation Distillates, petroleum, solvent-refined heavy paraffinic: Species : Rabbit Result : No eye irritation Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Distillates, petroleum, solvent-refined heavy paraffinic: Test Type : Buehler Test Species : Guinea pig Assessment : Does not cause skin sensitisation. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 8 / 13 Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: No aspiration toxicity classification Distillates, petroleum, solvent-refined heavy paraffinic: No aspiration toxicity classification Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 9 / 13 Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. Distillates, petroleum, solvent-refined heavy paraffinic: Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 203 Remarks: No toxicity at the limit of solubility Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 202 Toxicity to algae : NOEL (Pseudokirchneriella subcapitata (green algae)): >= 100 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : NOELR (Oncorhynchus mykiss (rainbow trout)): Calculated >= 1,000 mg/l Exposure time: 14 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEL (Daphnia (water flea)): 10 mg/l Exposure time: 21 d Test substance: WAF SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 10 / 13 Method: OECD Test Guideline 211 Persistence and degradability Components: Distillates, petroleum, solvent-refined heavy paraffinic: Biodegradability : Result: Not readily biodegradable. Biodegradation: 2 - 4 % Exposure time: 28 d Method: OECD Test Guideline 301B No data available Bioaccumulative potential Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Partition coefficient: n- octanol/water : log Pow: Expected > 7 No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : No data available Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 11 / 13 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : No SARA Hazards SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : Not in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory TSCA : On TSCA Inventory SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 12 / 13 TSCA list No substances are subject to TSCA 12(b) export notification requirements. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Internal information : R0289381 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). Flammability H e a lt h In s ta b ility 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH Special hazard 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET Valvoline? Durablend? SAE 10W-40 Motor Oil Version: 1.4 Revision Date: 02/28/2020 Print Date: 06/21/2023 13 / 13 List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System