SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 1 / 12 SECTION 1. IDENTIFICATION Product name : GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone : 1 (330) 255-6000 Emergency telephone number : CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2A GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : H319 Causes serious eye irritation. Precautionary statements : Prevention: P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 2 / 12 attention. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (%) Laureth-7 9002-92-0 >= 1 - < 5 Glycerin 56-81-5 >= 1 - < 5 Limonene 5989-27-5 >= 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact : Get medical attention if irritation develops and persists. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media : None known. Hazardous combustion products : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 3 / 12 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use. Conditions for safe storage : Keep in properly labelled containers. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Glycerin 56-81-5 TWA (mist, respirable fraction) 5 mg/m3 OSHA Z-1 TWA (mist, total dust) 15 mg/m3 OSHA Z-1 Limonene 5989-27-5 TWA 20 ppm ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : No special protective equipment required. Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : No special protective equipment required. Protective measures : Choose body protection in relation to its type, to the SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 4 / 12 concentration and amount of dangerous substances, and to the specific work-place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : grey, opaque Odour : citrus Odour Threshold : No data available pH : 4.0 - 6.0, (20 ?C) Melting point/freezing point : No data available Initial boiling point and boiling range : > 90 ?C Flash point : > 100 ?C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : Not applicable Density : 1.03 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : No data available Thermal decomposition : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 10000 - 45000 mm2/s (20 ?C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 5 / 12 Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: Laureth-7: Acute oral toxicity : LD50 (Rat): > 500 - 2,000 mg/kg Remarks: Based on data from similar materials Acute inhalation toxicity : LC50 (Rat): > 1.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Remarks: Based on data from similar materials Glycerin: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Limonene: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Remarks: Based on data from similar materials Skin corrosion/irritation Not classified based on available information. Components: Laureth-7: Species: Rabbit Result: No skin irritation Remarks: Based on data from similar materials Glycerin: SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 6 / 12 Result: No skin irritation Limonene: Species: Rabbit Result: Skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Components: Laureth-7: Species: Rabbit Result: Irreversible effects on the eye Remarks: Based on data from similar materials Glycerin: Result: No eye irritation Limonene: Species: Rabbit Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Product: Result: Does not cause skin sensitisation. Components: Laureth-7: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Remarks: Based on data from similar materials Limonene: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: positive Assessment: Probability or evidence of skin sensitisation in humans Germ cell mutagenicity Not classified based on available information. Components: Laureth-7: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 7 / 12 Remarks: Based on data from similar materials Glycerin: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Limonene: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Transgenic rodent somatic cell gene mutation assay Test species: Rat Application Route: Ingestion Result: negative Carcinogenicity Not classified based on available information. Components: Glycerin: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative Limonene: Species: Mouse Application Route: Ingestion Exposure time: 103 weeks Result: negative IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: Glycerin: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 8 / 12 Effects on foetal development : Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Result: negative STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: Glycerin: Species: Rat NOAEL: 167 mg/m3 LOAEL: 660 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 13 w Symptoms: Local irritation Limonene: Species: Rat NOAEL: 600 mg/kg Application Route: Ingestion Exposure time: 13 w Aspiration toxicity Not classified based on available information. Components: Limonene: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: Laureth-7: Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): > 0.1 - 1 mg/l Exposure time: 21 d Remarks: Based on data from similar materials SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 9 / 12 Glycerin: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 1,955 mg/l Exposure time: 48 h Toxicity to bacteria : NOEC (Pseudomonas putida): > 10,000 mg/l Exposure time: 16 h Limonene: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.36 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials M-Factor (Acute aquatic toxicity) : 1 Persistence and degradability Components: Laureth-7: Biodegradability : Result: rapidly degradable Remarks: Based on data from similar materials Glycerin: Biodegradability : Result: Readily biodegradable. Biodegradation: 94 % Exposure time: 1 d Limonene: Biodegradability : Result: Readily biodegradable. Biodegradation: 80 % Exposure time: 28 d Remarks: Based on data from similar materials Bioaccumulative potential Components: Laureth-7: Bioaccumulation : Species: Fish Bioconcentration factor (BCF): < 500 Remarks: Based on data from similar materials Glycerin: Partition coefficient: n- octanol/water : log Pow: -1.76 Limonene: Partition coefficient: n- : log Pow: 4.38 SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 10 / 12 octanol/water Mobility in soil No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 11 / 12 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): Glycerin 56-81-5 1 % This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. California Prop 65 This product does not require a warning label under California Proposition 65. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory AICS : On the inventory, or in compliance with the inventory DSL : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory ISHL : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005951 Revision Date: 04/27/2021 12 / 12 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Revision Date : 04/27/2021 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability H ea lth Instability 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic