SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 1 / 14 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? CRIMSON #2 GREASE Product code : VV70124 Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin sensitization : Category 1 GHS label elements Hazard pictograms : Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Precautionary Statements : Prevention: Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Response: Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/ attention. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 2 / 14 IF ON SKIN: Wash with plenty of soap and water. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) Pentene, 2,4,4-trimethyl-, sulfurized 68515-88-8 Skin Irrit. 2; H315 Skin Sens. 1A; H317 >=0.10 - < 0.50 2,5-BIS(OCTYLDITHIO)-1,3,4- THIADIAZOLE 13539-13-4 Acute Tox. 4; H332 Skin Irrit. 2; H315 Eye Irrit. 2A; H319 Skin Sens. 1; H317 >=0.10 - < 0.50 5,5'-dithiodi-1,3,4-thiadiazole- 2(3H)-thione 72676-55-2 Skin Sens. 1; H317 >=0.10 - < 0.50 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 3 / 14 If on skin, rinse well with water. First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. Wash contaminated clothing before re-use. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. May cause an allergic skin reaction. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : No hazardous combustion products are known Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 4 / 14 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Container hazardous when empty. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 5 / 14 Personal protective equipment Respiratory protection : Respiratory protection is not required under normal conditions of use. No personal respiratory protective equipment normally required. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: Impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of wear. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : paste Colour : red Odour : hydrocarbon-like Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : > 700 ?F / > 371 ?C Flash point : > 399 ?F / > 204 ?C SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 6 / 14 Evaporation rate : < 0.01 Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : No data available Lower explosion limit / Lower flammability limit : No data available Vapour pressure : < 0.1 mmHg (68 ?F / 20 ?C) Relative density : 0.9 (60.1 ?F / 15.6 ?C) Density : 0.9 g/cm3 (68 ?F / 20 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : > 1000 mm2/s (104 ?F / 40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : None known. Incompatible materials : None known. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 7 / 14 Hazardous decomposition products No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: 2,5-BIS(OCTYLDITHIO)-1,3,4-THIADIAZOLE: Acute inhalation toxicity : Assessment: The component/mixture is classified as acute inhalation toxicity, category 4. 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: Not classified as acutely toxic by ingestion under GHS. Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. Skin corrosion/irritation Not classified based on available information. Product: Remarks : May cause skin irritation in susceptible persons. Components: Pentene, 2,4,4-trimethyl-, sulfurized: Result : Severe skin irritation 2,5-BIS(OCTYLDITHIO)-1,3,4-THIADIAZOLE: Result : Irritating to skin. 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Species : Rabbit Result : No skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Remarks : Unlikely to cause eye irritation or injury. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 8 / 14 Components: 2,5-BIS(OCTYLDITHIO)-1,3,4-THIADIAZOLE: Result : Irritating to eyes. 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Species : Rabbit Result : Slight, transient irritation Respiratory or skin sensitisation Skin sensitisation May cause an allergic skin reaction. Respiratory sensitisation Not classified based on available information. Product: Remarks : May cause allergic skin reaction. Components: Pentene, 2,4,4-trimethyl-, sulfurized: Test Type : Open epicutaneous test Species : Guinea pig Assessment : The product is a skin sensitiser, sub-category 1A. Method : OECD Test Guideline 406 2,5-BIS(OCTYLDITHIO)-1,3,4-THIADIAZOLE: Assessment : May cause sensitisation by skin contact. 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Test Type : Local lymph node assay Assessment : May cause sensitisation by skin contact. Method : OECD Test Guideline 429 Germ cell mutagenicity Not classified based on available information. Components: 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Result: negative Carcinogenicity Not classified based on available information. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 9 / 14 Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Short-term (acute) aquatic hazard : Acute aquatic toxicity Category 3; Harmful to aquatic life. Long-term (chronic) aquatic hazard : Chronic aquatic toxicity Category 3; Harmful to aquatic life with long lasting effects. Components: Pentene, 2,4,4-trimethyl-, sulfurized: Toxicity to fish : LC50 (Fish): 0.494 mg/l Exposure time: 96 h Test Type: static test Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : EC50 (Aquatic invertebrates): 0.004 mg/l Exposure time: 96 h Test Type: static test Ecotoxicology Assessment Short-term (acute) aquatic hazard : Acute aquatic toxicity Category 1; Very toxic to aquatic life. Long-term (chronic) aquatic hazard : Chronic aquatic toxicity Category 1; Very toxic to aquatic life with long lasting effects. 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Toxicity to fish : EC50 (Pimephales promelas (fathead minnow)): > 454 mg/l Exposure time: 96 h Test Type: semi-static test SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 10 / 14 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 3 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 20 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Persistence and degradability Components: 5,5'-dithiodi-1,3,4-thiadiazole-2(3H)-thione: Biodegradability : Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301B No data available Bioaccumulative potential Components: No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : No data available Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 11 / 14 SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations CFR_ROAD Not regulated as a dangerous good Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Respiratory or skin sensitisation SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 12 / 14 AICS : On the inventory, or in compliance with the inventory ENCS : Not in compliance with the inventory KECI : Not in compliance with the inventory PICCS : Not in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory TSCA : On the inventory, or in compliance with the inventory TSCA list No substances are subject to TSCA 12(b) export notification requirements. Inventories AICS (Australia), AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Internal information : R0290463 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H315 Causes skin irritation. Flammability H e a lt h In s ta b ility 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 13 / 14 H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value SAFETY DATA SHEET Valvoline? CRIMSON #2 GREASE Version: 1.4 Revision Date: 03/04/2021 Print Date: 06/21/2023 14 / 14 TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System