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Valvoline
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VV349 - 5GAL VALV DEX/MERC AUTOMATIC TRANS FLUID - Version 2
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VV349__VAL_ATF_DEX_MERC_PL_5_GA_VV349_United_States_-_English.pdf
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SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 1 / 15 SECTION 1. IDENTIFICATION Product name : Valvoline? DEX/MERC Automatic Transmission Fluid Product code : VV349 Manufacturer or supplier's details Company name of supplier : Valvoline Global Operations Address : 100 Valvoline Way Lexington, KY 40509 United States of America (USA) Telephone : 1-800-TEAMVAL (1-800-832-6825) E-mail address : This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number : +1-800-VALVOLINE (+1-800-825-8654) SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Not a hazardous substance or mixture. GHS label elements No hazard pictogram, no signal word, no hazard statement(s), no precautionary statement(s) required Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 2 / 15 Components Chemical name CAS-No. Concentration (% w/w) DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 >= 80 - < 90 HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 >= 5 - < 10 PETROLEUM DISTILLATES 64742-55-8 >= 1.5 - < 5 Short-, medium- and long-chain alkyl methacrylates and short-chain alkyl methacrylamide copolymer Not Assigned >= 1 - < 1.5 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. Notes to physician : No hazards which require special first aid measures. Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media : High volume water jet SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 3 / 15 Hazardous combustion products : carbon dioxide and carbon monoxide Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Conditions for safe storage : Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : No materials to be especially mentioned. Further information on storage stability : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 4 / 15 Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH PETROLEUM DISTILLATES 64742-55-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : Safety glasses Skin and body protection : Protective suit Hygiene measures : General industrial hygiene practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : red Odour : hydrocarbon-like Odour Threshold : No data available pH : No data available SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 5 / 15 Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : 394 - 480 ?F / 201 - 249 ?C Method: Cleveland open cup Evaporation rate : > 1 Ethyl Ether Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : 6 %(V) GLP: Calculated Explosive Limit Lower explosion limit / Lower flammability limit : 1 %(V) GLP: Calculated Explosive Limit Vapour pressure : 0.0133333 hPa (70.00 ?F / 21.11 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.862 g/cm3 (60.01 ?F / 15.56 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : ca. 43 mm2/s (104 ?F / 40 ?C) Oxidizing properties : No data available SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 6 / 15 SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reactions : Stable under recommended storage conditions. No hazards to be specially mentioned. Conditions to avoid : excessive heat Incompatible materials : Strong oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg Skin corrosion/irritation Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Assessment : Slight, transient irritation Result : Slight, transient irritation Serious eye damage/eye irritation Not classified based on available information. SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 7 / 15 Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result : No eye irritation Assessment : No eye irritation HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result : Slight, transient irritation Assessment : Slight, transient irritation Short-, medium- and long-chain alkyl methacrylates and short-chain alkyl methacrylamide copolymer: Result : Eye irritation Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Product: Assessment : Does not cause skin sensitisation. Remarks : Expected based on components. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) PETROLEUM DISTILLATES: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 8 / 15 IARC Group 1: Carcinogenic to humans DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 (Mineral oils, untreated or mildly treated) OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP Known to be human carcinogen DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 (Mineral Oils: Untreated and Mildly Treated) Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: No aspiration toxicity classification HYDROTREATED LIGHT PARAFFINIC DISTILLATE: May be fatal if swallowed and enters airways. Further information Product: Remarks : No data available SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 9 / 15 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. PETROLEUM DISTILLATES: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 10 / 15 Chronic aquatic toxicity : Not classified based on available information. Short-, medium- and long-chain alkyl methacrylates and short-chain alkyl methacrylamide copolymer: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Persistence and degradability No data available Bioaccumulative potential Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Partition coefficient: n- octanol/water : log Pow: Expected > 7 Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 11 / 15 SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good Special precautions for user Not applicable Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : No SARA Hazards SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 12 / 15 This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 This product does not contain any priority pollutants related to the U.S. Clean Water Act US State Regulations Massachusetts Right To Know HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 PETROLEUM DISTILLATES 64742-55-8 distillates (petroleum), hydrotreated light paraffinic 64742-55-8 Pennsylvania Right To Know DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 PROPRIETARY OF HITEC 3421 - 000000147781 Not Assigned PETROLEUM DISTILLATES 64742-55-8 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 Maine Chemicals of High Concern Lubricating oils (petroleum), C15-30, hydrotreated neutral oil- based 72623-86-0 Vermont Chemicals of High Concern Lubricating oils (petroleum), C15-30, hydrotreated neutral oil- based 72623-86-0 Washington Chemicals of High Concern Lubricating oils (petroleum), C15-30, hydrotreated neutral oil- based 72623-86-0 California Permissible Exposure Limits for Chemical Contaminants DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 The components of this product are reported in the following inventories: TCSI : On the inventory, or in compliance with the inventory SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 13 / 15 TSCA : All substances listed as active on the TSCA inventory AIIC : Not in compliance with the inventory DSL : All components of this product are on the Canadian DSL ENCS : Not in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. Inventories AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TECI (Thailand), TSCA (USA) SECTION 16. OTHER INFORMATION Further information SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 14 / 15 NFPA 704: HMIS? IV: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard. Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average OSHA Z-1 / TWA : 8-hour time weighted average AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; HEALTH 1 1 0 Flammability Instability Special hazard FLAMMABILITY PHYSICAL HAZARD / 0 1 0 Health SAFETY DATA SHEET Valvoline? DEX/MERC Automatic Transmission Fluid Version: 2.0 Revision Date: 06/13/2023 Print Date: 06/21/2023 15 / 15 NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self- Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative Revision Date : 06/13/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN Internal information : R0200299