SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 1 / 23 SECTION 1. IDENTIFICATION Product name : Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Product code : 774038 Manufacturer or supplier's details Company name of supplier : Valvoline Global Operations Address : 100 Valvoline Way Lexington, KY 40509 United States of America (USA) Telephone : 1-800-TEAMVAL (1-800-832-6825) E-mail address : This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number : +1-800-VALVOLINE (+1-800-825-8654) Recommended use of the chemical and restrictions on use Recommended use : Lubricant SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 2 / 23 Components Chemical name CAS-No. Concentration (% w/w) Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 >= 40 - < 50 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 >= 10 - < 15 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 >= 5 - < 10 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 >= 1.5 - < 5 Distillates (petroleum), solvent- dewaxed light paraffinic 64742-56-9 >= 1.5 - < 5 ZINC BIS[O-(6- METHYLHELPTYL)]BIS[O-SEC- BUTYL)]BIS(DITHIOPHOSPATE) 93819-94-4 >= 1 - < 1.5 DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 >= 1 - < 1.5 CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM) 64742-70-7 >= 1 - < 1.5 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 3 / 23 Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. Notes to physician : Treat symptomatically. No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Unsuitable extinguishing media : High volume water jet Hazardous combustion products : carbon dioxide and carbon monoxide Nitrogen oxides (NOx) Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Environmental precautions : Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against : Normal measures for preventive fire protection. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 4 / 23 fire and explosion Advice on safe handling : Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Further information on storage stability : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 5 / 23 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH Distillates (petroleum), solvent- dewaxed light paraffinic 64742-56-9 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable particulate matter) 5 mg/m3 ACGIH TWA (Mist) 5 mg/m3 OSHA P0 TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM) 64742-70-7 TWA (Mist) 5 mg/m3 OSHA Z-1 Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 6 / 23 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : 392 ?F / 200 ?C Calculated Phase Transition Liquid/Gas Flash point : > 390 ?F / > 199 ?C Evaporation rate : No data available Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : 6 %(V) GLP: Calculated Explosive Limit Lower explosion limit / Lower flammability limit : 1 %(V) GLP: Calculated Explosive Limit Vapour pressure : 1.3333333 hPa (68 ?F / 20 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : 0.8556 (68 ?F / 20 ?C) Density : No data available Solubility(ies) Water solubility : insoluble Solubility in other solvents : No data available Partition coefficient: n- : No data available SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 7 / 23 octanol/water Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : 100 mm2/s (104 ?F / 40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reactions : No decomposition if stored and applied as directed. Conditions to avoid : excessive heat Incompatible materials : Acids Strong oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 15 g/kg SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 8 / 23 Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT): Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Distillates (petroleum), solvent-dewaxed light paraffinic: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.53 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Acute oral toxicity : LD50 (Rat): 2,600 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM): Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Remarks: The toxicological data has been taken from products of similar composition. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 9 / 23 Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: The toxicological data has been taken from products of similar composition. Skin corrosion/irritation Not classified based on available information. Product: Remarks : May cause skin irritation and/or dermatitis. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Assessment : Slight, transient irritation Result : Slight, transient irritation DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT): Result : Slight, transient irritation DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation Distillates (petroleum), solvent-dewaxed light paraffinic: Species : Rabbit Result : Slight, transient irritation ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Species : Guinea pig Method : OECD Test Guideline 404 Result : Irritating to skin. Remarks : The toxicological data has been taken from products of similar composition. DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA: SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 10 / 23 Assessment : Slight, transient irritation Result : Slight, transient irritation CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM): Assessment : Slight, transient irritation Result : Slight, transient irritation Serious eye damage/eye irritation Not classified based on available information. Product: Remarks : May cause irreversible eye damage. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Result : No eye irritation Assessment : No eye irritation DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result : No eye irritation Assessment : No eye irritation DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT): Result : Slight, transient irritation DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Result : Slight, transient irritation Assessment : Slight, transient irritation Distillates (petroleum), solvent-dewaxed light paraffinic: Species : Rabbit Result : Slight, transient irritation ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Species : Rabbit Result : Corrosive Remarks : The toxicological data has been taken from products of similar composition. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 11 / 23 DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA: Result : Slight, transient irritation Assessment : Slight, transient irritation CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM): Result : Slight, transient irritation Assessment : Slight, transient irritation Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Distillates (petroleum), solvent-dewaxed light paraffinic: Test Type : Buehler Test Species : Guinea pig Assessment : Does not cause skin sensitisation. Method : OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT): Genotoxicity in vitro : Test Type: Ames test Result: negative ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Remarks: The toxicological data has been taken from products of similar composition. Genotoxicity in vivo : Test Type: Micronucleus test Species: Mouse Method: OECD Test Guideline 474 Result: negative SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 12 / 23 Remarks: The toxicological data has been taken from products of similar composition. Carcinogenicity Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT): Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) Distillates (petroleum), solvent-dewaxed light paraffinic: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM): Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) IARC Group 1: Carcinogenic to humans DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 (Mineral oils, untreated or mildly treated) Group 1: Carcinogenic to humans DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 13 / 23 (Mineral oils, untreated or mildly treated) Group 1: Carcinogenic to humans DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 (Mineral oils, untreated or mildly treated) OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP Known to be human carcinogen DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 (Mineral Oils: Untreated and Mildly Treated) Known to be human carcinogen DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 (Mineral Oils: Untreated and Mildly Treated) Known to be human carcinogen DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 (Mineral Oils: Untreated and Mildly Treated) Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: May be fatal if swallowed and enters airways. DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: May be fatal if swallowed and enters airways. Distillates (petroleum), solvent-dewaxed light paraffinic: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 14 / 23 Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 15 / 23 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT): Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Distillates (petroleum), solvent-dewaxed light paraffinic: Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : NOEL (Pseudokirchneriella subcapitata (green algae)): >= 100 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEL (Daphnia magna (Water flea)): 10 mg/l Exposure time: 21 d Test Type: semi-static test Test substance: WAF Method: OECD Test Guideline 211 Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 16 / 23 Chronic aquatic toxicity : Not classified based on available information. ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4.5 mg/l Exposure time: 96 h Test Type: semi-static test Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 5.4 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae/aquatic plants : EC50 (Selenastrum capricornutum (green algae)): 2.1 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Ecotoxicology Assessment Acute aquatic toxicity : Acute aquatic toxicity Category 2; Toxic to aquatic life. Chronic aquatic toxicity : Chronic aquatic toxicity Category 2; Toxic to aquatic life with long lasting effects. DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM): Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Persistence and degradability Components: Distillates (petroleum), solvent-dewaxed light paraffinic: Biodegradability : Result: Inherently biodegradable. Biodegradation: 31 % Exposure time: 28 d Method: OECD Test Guideline 301B SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 17 / 23 ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Biodegradability : Result: Not readily biodegradable. Biodegradation: 1.5 % Exposure time: 28 d Method: OECD Test Guideline 301B Bioaccumulative potential Components: ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Partition coefficient: n- octanol/water : log Pow: 0.59 - 1.2 (73 ?F / 23 ?C) CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM): Partition coefficient: n- octanol/water : log Pow: > 3.5 Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 18 / 23 SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good Special precautions for user Not applicable Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity Listed substances in the product are at low enough levels to not be expected to exceed the RQ SARA 304 Extremely Hazardous Substances Reportable Quantity Listed substances in the product are at low enough levels to not be expected to exceed the RQ SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : No SARA Hazards SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 19 / 23 ZINC BIS[O-(6- METHYLHELPT YL)]BIS[O-SEC- BUTYL)]BIS(DIT HIOPHOSPATE) 93819-94-4 >= 1 - < 5 % Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: ETHYLENEDIAMINE 107-15-3 >= 0 - < 0.1 % VINYL ACETATE MONOMER 108-05-4 >= 0 - < 0.1 % The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: ETHYLENEDIAMINE 107-15-3 >= 0 - < 0.1 % VINYL ACETATE MONOMER 108-05-4 >= 0 - < 0.1 % This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 ZINC BIS[O-(6- METHYLHELPTYL)]BIS[ O-SEC- BUTYL)]BIS(DITHIOPHO SPATE) 93819-94-4 >= 1 - < 5 % This product does not contain any priority pollutants related to the U.S. Clean Water Act US State Regulations Massachusetts Right To Know Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Distillates (petroleum), solvent-dewaxed light paraffinic 64742-56-9 Reaction products of Benzeneamine, N-phenyl- with nonene (branched) 36878-20-3 DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 CATALYTIC DE WAXED HEAVY PARAFFINIC OIL (PETROLEUM) 64742-70-7 ETHYLENEDIAMINE 107-15-3 VINYL ACETATE MONOMER 108-05-4 SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 20 / 23 Pennsylvania Right To Know Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 PROPRIETARY OF INFINEUM D3510L - 0-271834 Not Assigned DECENE-1 HOMOPOLYMER HYDROGENATED 68037-01-4 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 Distillates (petroleum), solvent-dewaxed light paraffinic 64742-56-9 ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC- BUTYL)]BIS(DITHIOPHOSPATE) 93819-94-4 DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 Maine Chemicals of High Concern Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Reaction products of Benzeneamine, N-phenyl- with nonene (branched) 36878-20-3 Dodecylphenol, mixed isomers (branched) 74499-35-7 TOLUENE 108-88-3 BENZENE 71-43-2 Vermont Chemicals of High Concern Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Reaction products of Benzeneamine, N-phenyl- with nonene (branched) 36878-20-3 Dodecylphenol, mixed isomers (branched) 74499-35-7 ETHYLENE GLYCOL 107-21-1 TOLUENE 108-88-3 BENZENE 71-43-2 Washington Chemicals of High Concern Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Reaction products of Benzeneamine, N-phenyl- with nonene (branched) 36878-20-3 Dodecylphenol, mixed isomers (branched) 74499-35-7 ETHYLENE GLYCOL 107-21-1 TOLUENE 108-88-3 BENZENE 71-43-2 California List of Hazardous Substances DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC (<3 % DMSO EXTRACT) 64742-65-0 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC- 93819-94-4 SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 21 / 23 BUTYL)]BIS(DITHIOPHOSPATE) DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 California Permissible Exposure Limits for Chemical Contaminants Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PA 64741-89-5 The components of this product are reported in the following inventories: TCSI : Not in compliance with the inventory TSCA : All substances listed as active on the TSCA inventory AIIC : Not in compliance with the inventory DSL : All components of this product are on the Canadian DSL ENCS : Not in compliance with the inventory ISHL : Not in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory TECI : Not in compliance with the inventory TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. Inventories AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TECI (Thailand), TSCA (USA) SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 22 / 23 SECTION 16. OTHER INFORMATION Further information NFPA 704: HMIS? IV: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard. Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA P0 / TWA : 8-hour time weighted average OSHA Z-1 / TWA : 8-hour time weighted average AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; HEALTH 1 1 0 Flammability Instability Special hazard FLAMMABILITY PHYSICAL HAZARD / 1 1 0 Health SAFETY DATA SHEET Premium Blue? Heavy Duty SAE 5W-40 Engine Oil Version: 2.0 Revision Date: 06/06/2023 Print Date: 06/21/2023 23 / 23 GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self- Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative Revision Date : 06/06/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN Internal information : 000000091604