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Seafoam
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BBG4 - Gal BUGS-B-GONE CONCENTRATE
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BBG4__BBG32-SDS-US-ENG-v20230504.pdf
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Applicable Law: USA Page 1 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 SECTION 1. IDENTIFICATION Product name : Bugs B Gone (Concentrate) Product code : BBG4, BBG32, BBG55 Product form : Mixture. Recommended use and restrictions : Multi-use cleaner, road bugs on all vehicle surfaces, organic material on carpet and vinyl upholstery, coolers, kitchen sinks, and other surfaces. Manufacturer : Sea Foam Sales Company 510 N. Chestnut Street Chaska, MN, USA 55347 T 952-938-4811 Emergency Telephone Number : INFOTRAC - (800) 535-5053 (Within Continental US) (8-4:30pm CST); +1 (352) 323-3500 (Outside US) NOTE: INFOTRAC emergency number is to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. SECTION 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Precautionary statements (GHS US) If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Wash hands, forearms and face thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If on skin: wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Other Hazards No additional information available. Unknown Acute Toxicity Not applicable. Classification (GHS) Skin Irrit. 2 Eye Irrit. 2A Causes skin irritation Causes serious eye irritation. GHS Label elements, including precautionary statements GHS-US labelling Hazard pictograms (GHS US) Signal Word (GHS US) Warning Hazard statements (GHS US) Causes skin irritation Causes serious eye irritation. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Name Chemical Name/Synonyms Product Identifier % wt Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)- .omega.-hydroxy-, branched 4-Nonylphenol, branched, ethoxylated / Polyethylene glycol, mono(p-nonylphenyl) ether, branched / .alpha.-(4-Nonylphenyl)-.omega.-hydroxy poly(oxy-1,2-ethanediyl), branched / .alpha.-(p-Nonylphenyl)-.omega.-hydroxypoly(oxyethylene) branched / 4- Nonylphenol, branched and linear, ethoxylated / .alpha.-(4-Nonylphenyl)-.omega.- hydroxypoly(oxy-1,2-ethanediyl) branched / Ethoxylated branched and linear 4- nonylphenol / Poly (oxy-1,2-ethanediyl), alpha-(4-nonylphenyl)-omega-hydroxy-, branched / 4-Nonylphenol, branched, ethoxylated, 1 - 2.5 moles ethoxylated * 1 ? 5* Glycine, N,N'-1,2- ethanediylbis[N- (carboxymethyl)-, tetrasodium salt Tetrasodium ethylenediaminetetraacetate / Ethylenediaminetetraacetic acid, tetrasodium salt / N,N'-1,2-Ethanediylbis(N-(carboxymethyl)glycine) tetrasodium salt / Tetrasodium ethylene diamine tetraacetate / edetate sodium / Edetate sodium / Tetrasodium edetate / EDTA, tetrasodium / Acetic acid, (ethylenedinitrilo)tetra-, tetrasodium salt / Tetrasodium salt of ethylenediaminetetraacetic acid / EDTA tetrasodium salt / TETRASODIUM EDTA / Glycine, N,N'-1,2-ethanediylbis[N- (carboxymethyl)-, tetrasodium salt / Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, sodium salt (1:4) / Tetrasodium 2,2',2'',2'''-(ethylenedinitrilo)tetraacetate * 0.1 ? 1* Applicable Law: USA Page 2 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 2-butoxyethanol 2-Butoxy-1-ethanol / Butoxyethanol / Ethanol, 2-butoxy- / Ethylene glycol monobutyl ether / Ethylene glycol n-butyl ether / Hydroxyethyl butyl ether / Ethylene glycol butyl ether / 2- Butoxyethan-1-ol / Ethylene glycol mono-n-butyl ether / 2-n-Butoxyethanol / Butyl glycol / BUTOXYETHANOL / EGBE / EGMBE / Butoxyethanol, 2- / Butyl Cellosolve / Monobutyl ether of ethyleneglycol * 0.1 ? 1* Potassium hydroxide Caustic potash / Potassium hydroxide (K(OH)) / POTASSIUM HYDROXIDE * 0.1 ? 1* *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret SECTION 4. FIRST-AID MEASURES Description of first aid measures First-aid measures after ingestion : Do NOT induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : If skin irritation occurs: Wash skin with plenty of water. Get medical advice/attention. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Most important symptoms and effects, both acute and delayed Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Symptoms/effects after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Immediate medical attention and special treatment, if necessary Other medical advice or treatment : Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray. Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Unsuitable extinguishing media : Do not use a solid water stream as it may scatter and spread fire. Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Protection during firefighting : Keep upwind of fire. Wear full firefighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental Precautions : Prevent entry to sewers and public waters. Methods and material for containment and cleaning up For containment : Absorb and/or contain spill with inert material (sand, vermiculite, or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment. Methods for cleaning up : Provide ventilation. Sweep or shovel spills into appropriate container for disposal. Reference to other sections : For further information refer to section 8: "Exposure controls/personal protection." Applicable Law: USA Page 3 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 SECTION 7. HANDLING AND STORAGE Precautions for safe handling :Read label before use. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow. Handle and open container with care. When using do not eat, drink, or smoke. Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Store tightly closed in a dry, cool and well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Bugs B Gone (Concentrate) No additional Information available Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt No additional information available 2-butoxyethanol USA - ACGIH - Occupational Exposure Limits Local name 2-Butoxyethanol (EGBE) ACGIH OEL TWA [ppm] 20 ppm Remark (ACGIH) TLV? Basis: Eye & URT irr. Notations: A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans); BEI ACGIH chemical category Confirmed Animal Carcinogen with Unknown Relevance to Humans Regulatory reference ACGIH 2020 USA - ACGIH - Biological Exposure Indices BEI 200 mg/g creatinine Parameter: Butoxyacetic acid with hydrolysis - Medium: urine - Sampling time: end of shift USA - OSHA - Occupational Exposure Limits Local name 2-Butoxyethanol OSHA PEL (TWA) [1] 240 mg/m? OSHA PEL (TWA) [2] 50 ppm Limit value category (OSHA) prevent or reduce skin absorption Regulatory reference (US-OSHA) OSHA Annotated Table Z-1 USA - IDLH - Occupational Exposure Limits IDLH [ppm] 700 ppm USA - NIOSH - Occupational Exposure Limits NIOSH REL (TWA) 24 mg/m? NIOSH REL TWA [ppm] 5 ppm US-NIOSH chemical category SK: SYS-DIR(IRR) Apr 2011 Potassium hydroxide USA - ACGIH - Occupational Exposure Limits ACGIH OEL C 2 mg/m? USA - NIOSH - Occupational Exposure Limits NIOSH REL (Ceiling) 2 mg/m? Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-, branched No additional information available Applicable Law: USA Page 4 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 Appropriate engineering controls : Ensure good ventilation of the workstation. Provide readily accessible eye wash stations and safety showers. Environmental exposure controls : Avoid release to the environment. Individual protection measures, such as personal protective equipment Eye protection : Wear eye/face protection. Skin and body protection : Wear suitable protective clothing. Hand protection : Wear suitable gloves resistant to chemical penetration. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Other information : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid. Flammability (solid, gas): Not flammable. Appearance: Clear liquid. Explosive properties/explosive limits: Not explosive/No data available. Colour: Colourless. Vapour pressure: No data available. Odour: Natural. Relative vapour density at 20 ?C: No data available. Odour threshold: No data available. Relative density: No data available. pH: 10.7 Solubility: Soluble in water. Melting/Freezing point: -2.22 ?C / 28 ?F Partition coefficient: n-octanol/water: No data available. Boiling point: 101.1 ?C / 214 ?F Auto-ignition temperature: No data available. Flash point: > 300 ?C / 572 ?F Decomposition temperature: No data available. Relative evaporation rate (butylacetate = 1): No data available. Viscosity, kinematic: No data available. Relative evaporation rate (ether=1): No data available. Other information: No additional information available. SECTION 10. STABILITY AND REACTIVITY Reactivity : No dangerous reactions known under normal conditions of use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reactions known under normal conditions of use. Conditions to avoid : Heat. Incompatible materials. Incompatible materials : Strong oxidizing agents. Applicable Law: USA Page 5 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 Hazardous decomposition products : May include and are not limited to: oxides of carbon. SECTION 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity (oral) : Not classified. Acute toxicity (dermal) : Not classified. Acute toxicity (inhalation) : Not classified. Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt LD50 oral rat 1658 mg/kg LD50 oral 1210 mg/kg ATE US (oral) 1210 mg/kg body weight 2-butoxyethanol LD50 oral rat 1746 mg/kg body weight Animal: rat, Animal sex: male, Guideline: OECD Guideline 401 (Acute Oral Toxicity), 95% CL: 1322 - 2301 LD50 oral 1414 mg/kg body weight Animal: guinea pig, Guideline: OECD Guideline 401 (Acute Oral Toxicity), 95% CL: 1020 - 1961 LD50 dermal rabbit 435 mg/kg LC50 inhalation rat 2.35 mg/l LC50 inhalation rat 486 ppm/4h ATE US (oral) 1414 mg/kg body weight ATE US (Dermal) 435 mg/kg body weight ATE US (Gases) 486 ppmv/4h ATE US (vapors) 2.35 mg/l/4h ATE US (dust, mist) 2.35 mg/l/4h Potassium hydroxide LD50 oral rat 284 mg/kg LD50 oral 284 mg/kg ATE US (oral) 284 mg/kg body weight Poly(oxy-1,2-ethanediyl), .alpha.-(nonylphenyl)-.omega.-hydroxy-, branched LD50 oral rat 1310 mg/kg LD50 oral 657.2 mg/kg body weight Animal: rabbit, Animal sex: male, Guideline: other:, Remarks on results: other:, 95% CL: 265 - 1664,2 LD50 dermal rabbit ? ATE US (oral) 657.2 mg/kg body weight Skin corrosion/irritation : Causes skin irritation. pH: 10.7 Potassium hydroxide pH 13 (conc: 1 % (solution) Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-, branched pH 5.95 Temp.: 26 ?C Concentration: 1 other: Serious eye damage/irritation : Causes serious eye irritation. pH: 10.7 Potassium hydroxide pH 13 (conc: 1 % (solution) Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-, branched pH 5.95 Temp.: 26 ?C Concentration: 1 other: Applicable Law: USA Page 6 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 Respiratory or skin sensitization : Not classified. Germ cell mutagenicity : Not classified. Carcinogenicity : Not classified. 2-butoxyethanol IARC group 3 - Not classifiable Reproductive toxicity : Not classified. STOT-single exposure : Not classified. 2-butoxyethanol STOT-single exposure May cause respiratory irritation. STOT-repeated exposure : Not classified. Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt LOAEC (inhalation, rat, dust/mist/fume, 90 days) 0.015 mg/l air Animal: rat, Animal sex: female, Guideline: OECD Guideline 413 (Subchronic Inhalation Toxicity: 90-Day Study) NOAEL (oral, rat, 90 days) ? 500 mg/kg body weight Animal: rat 2-butoxyethanol NOAEL (dermal, rat/rabbit, 90 days) > 150 mg/kg body weight Animal: rabbit, Guideline: OECD Guideline 411 (Subchronic Dermal Toxicity: 90-Day Study), Remarks on results: other: STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified. Viscosity, kinematic : No data available. Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Symptoms/effects after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting, and cracking of the skin. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Other information : Likely routes of exposure: ingestion, inhalation, skin, and eye. SECTION 12. ECOLOGICAL INFORMATION Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt LC50 - Fish [1] 41 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) LC50 - Fish [2] 59.8 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 - Crustacea [1] 140 mg/l Test organisms (species): Daphnia magna ErC50 algae 1.01 mg/l EC50 72h - Algae [1] 1.01 mg/l (Species: Desmodesmus subspicatus) NOEC chronic fish ? 25.7 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio) Duration: '35 d' NOEC (chronic) 25 mg/l Test organisms (species): Daphnia magna Duration: '21 d' LOEC (chronic) 50 mg/l Test organisms (species): Daphnia magna Duration: '21 d' 2-butoxyethanol LC50 - Fish [1] 1474 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo gairdneri) LC50 - Fish [2] 2950 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) EC50 - Crustacea [1] ? 1800 mg/l Test organisms (species): Daphnia magna EC50 72h - Algae [1] 911 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) Applicable Law: USA Page 7 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 EC50 72h - Algae [2] 1840 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) NOEC chronic fish > 100 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio) Duration: '21 d' NOEC (chronic) 100 mg/l Test organisms (species): Daphnia magna Duration: '21 d' Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-, branched LC50 - Fish [1] 84.7 mg/l Test organisms (species): Lepomis macrochirus EC50 - Crustacea [1] 14 mg/l Test organisms (species): Daphnia magna EC50 72h - Algae [1] 1948545 mg/l Test organisms (species): Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) EC50 96h - Algae [1] 12 mg/l Test organisms (species): other: Persistence and degradability Bugs B Gone (concentrate) Persistence and degradability : Not established. Bioaccumulative potential Bugs B Gone (concentrate) Bioaccumulative potential : Not established. 2-butoxyethanol Partition coefficient n-octanol/water 0.81 (at 25 ?C) Potassium hydroxide Partition coefficient n-octanol/water 0.65 Other information : No other effects known. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Product/packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. The generation of waste should be avoided or minimized wherever possible. Additional Information : Recycle empty containers where allowed. SECTION 14. TRANSPORTATION INFORMATION In accordance with DOT. UN number : Not regulated for transport. UN proper shipping name Proper shipping name (DOT) : Not applicable. Transport hazard class(es) (DOT) : Not applicable. Packing group (DOT) : Not applicable. Environmental hazards Other information : No additional information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not applicable. Applicable Law: USA Page 8 of 8 EN (English) Version: 2305 SDS Revision Date: 05/03/2023 BUGS B GONE SAFETY DATA SHEET according to the Hazard Communication Standard (CFR 291910.1200) HazCom 2012 SECTION 15. REGULATORY INFORMATION Federal regulations : All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. International regulations : No additional information available. US State Regulations WARNING: This product can expose you to Ethylene oxide, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. SECTION 16. OTHER INFORMATION Full text of H-phrases Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Ittit. 2 Skin corrosion/irritation Category 2 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.