AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/15/2015 : Version: 1.1 15/05/2015 EN (English US) 1/1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Product code : 701152 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Brake Parts Cleaner 1.3. Details of the supplier of the safety data sheet Warren Oil Company, Inc. 2340 Highway 301 North Dunn, NC 28334 T 910-892-6456 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Aerosol 2 H223 Compressed gas H280 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Repr. 2 H361 STOT SE 1 H370 STOT SE 3 H336 STOT RE 2 H373 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS04 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H223 - Flammable aerosol H280 - Contains gas under pressure; may explode if heated H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H370 - Causes damage to organs H373 - May cause damage to organs through prolonged or repeated exposure Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat,sparks,open flames,hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P260 - Do not breathe dust,fumes,gas,mist,vapor spray P261 - Avoid breathing dust,fume,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves,protective clothing,eye protection,face protection P302+P352 - If on skin: Wash with plenty of soap and water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P307+P311 - If exposed: Call a poison center/doctor P308+P313 - If exposed or concerned: Get medical advice/attention AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 2/1 P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment: See section 4.1 on SDS P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P410+P403 - Protect from sunlight. Store in a well-ventilated place P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may explode if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Acetone (CAS No) 67-64-1 70 - 85 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Carbon Dioxide, Liquefied, Under Pressure (CAS No) 124-38-9 10 - 30 Compressed gas, H280 Toluene (CAS No) 108-88-3 5 - 10 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 Methanol (CAS No) 67-56-1 1 - 5 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:dust,mist), H331 STOT SE 1, H370 The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician. First-aid measures after inhalation : Cough. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Direct contact with the eyes is likely to be irritating. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/injuries after inhalation : Coughing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Shortness of breath. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Itching. Red skin. Causes skin irritation. Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 3/1 5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable aerosol. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire reaches explosives. Evacuate area. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : Aerosol Level 2. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove ignition sources. Use special care to avoid static electric charges. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not spray on an open flame or other ignition source. Obtain special instructions . Do not handle until all safety precautions have been read and understood. Avoid breathing dust,fume,gas,mist,vapor spray. Use only outdoors or in a well-ventilated area. Do not breathe dust,fumes,gas,mist,vapor spray. Hygiene measures : Wash contaminated clothing before reuse. Wash affected areas thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 1 ppm AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 4/1 Benzene (71-43-2) USA ACGIH ACGIH STEL (ppm) 5 ppm USA ACGIH ACGIH Ceiling (ppm) 25 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 5 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (mg/m?) 75 mg/m? USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Carbon Dioxide, Liquefied, Under Pressure (124-38-9) USA ACGIH ACGIH TWA (mg/m?) 9000 mg/m? USA ACGIH ACGIH TWA (ppm) 5000 ppm USA ACGIH ACGIH STEL (mg/m?) 54000 USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm Methanol (67-56-1) USA ACGIH ACGIH TWA (mg/m?) 262 mg/m? USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (mg/m?) 328 mg/m? USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 260 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm Acetone (67-64-1) USA ACGIH ACGIH TWA (mg/m?) 1188 mg/m? USA ACGIH ACGIH TWA (ppm) 500 ppm USA ACGIH ACGIH STEL (mg/m?) 1782 mg/m? USA ACGIH ACGIH STEL (ppm) 750 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 2400 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid. Molecular mass : 58.08 g/mol Color : Colourless to light yellow. Odor : Acetone odour. Solvent-like odour. AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 5/1 Odor threshold : 306 - 653 ppm 737 - 1574 mg/m? pH : 7 Relative evaporation rate (butyl acetate=1) : 6 Relative evaporation rate (ether=1) : 2 Melting point : -95 ?C Freezing point : -78 ?C (Lowest Component-Acetone) Boiling point : 56 ?C (Lowest Component-Acetone) Flash point : -18 ?C (Lowest Component-Acetone) Auto-ignition temperature : 385 ?C (Lowest Component-Acetone) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 247 hPa Vapor pressure at 50 ?C : 828 hPa Critical pressure : 47010 hPa Relative vapor density at 20 ?C : 2.0 Relative density : 0.81 Relative density of saturated gas/air mixture : 1.2 Specific gravity / density : 809 kg/m? Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in dimethyl ether. Soluble in petroleum spirit. Soluble in chloroform. Soluble in dimethylformamide. Soluble in oils/fats. Water: Complete Ethanol: Complete Ether: Complete Log Pow : -0.24 (Test data) Log Kow : No data available Viscosity, kinematic : 0.417 mm?/s Viscosity, dynamic : 0.00033 Pa.s Explosive properties : No data available Oxidizing properties : No data available Explosion limits : 2 - 12.8 vol % 60 - 310 g/m? 9.2. Other information Minimum ignition energy : 1.15 mJ Specific conductivity : 500000 pS/m Saturation concentration : 589 g/m? VOC content : 9.6 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Flammable aerosol. Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 6/1 Benzene (71-43-2) LD50 oral rat > 930 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; > 2000 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 8240 mg/kg (Rabbit; Experimental value; 21 CFR 191.10; > 9.4; Rabbit) LC50 inhalation rat (mg/l) 43.767 mg/l/4h (Rat; Experimental value) LC50 inhalation rat (ppm) 13700 ppm/4h (Rat; Experimental value) Toluene (108-88-3) LD50 oral rat 5580 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Literature study; 5580 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 5000 mg/kg body weight LD50 quoted as 14.1 mL/kg (12267 mg/kg using density of 0.87) LC50 inhalation rat (mg/l) > 28.1 mg/l/4h (Rat; Air, Literature study) Methanol (67-56-1) LD50 oral rat >= 2528 mg/kg body weight application as 50% aqueous solution LD50 dermal rabbit 17100 mg/kg corresponding to 20 ml/kg bw according to the authors LC50 inhalation rat (mg/l) 128.2 mg/l/4h Air Acetone (67-64-1) LD50 oral rat 5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rabbit 20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402) LC50 inhalation rat (mg/l) 71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value) LC50 inhalation rat (ppm) 30000 ppm/4h (Rat; Experimental value) Skin corrosion/irritation : Causes skin irritation. pH: 7 Serious eye damage/irritation : Causes serious eye irritation. pH: 7 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Benzene (71-43-2) IARC group 1 Toluene (108-88-3) IARC group 3 Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Causes damage to organs. May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Coughing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Shortness of breath. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Itching. Red skin. Causes skin irritation. Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Causes serious eye irritation. SECTION 12: Ecological information 12.1. Toxicity Benzene (71-43-2) LC50 fish 1 5.3 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 18 mg/l (24 h; Daphnia magna) LC50 fish 2 15.1 mg/l (96 h; Pimephales promelas) EC50 Daphnia 2 10 mg/l (48 h; Daphnia magna) TLM fish 1 22.5 mg/l (96 h; Lepomis macrochirus; Soft water) TLM fish 2 32 mg/l (96 h; Pimephales promelas; Hard water) Threshold limit algae 1 100 mg/l (72 h; Pseudokirchneriella subcapitata; GLP) Threshold limit algae 2 50 mg/l (24 h; Phaeodactylum; Photosynthesis) Toluene (108-88-3) LC50 fish 1 24 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 84 mg/l (24 h; Daphnia magna; Locomotor effect) AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 7/1 Toluene (108-88-3) LC50 fish 2 13 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 2 11.5 - 19.6 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 400 mg/l (168 h; Scenedesmus quadricauda; Toxicity test) Threshold limit algae 2 105 mg/l (192 h; Microcystis aeruginosa) Acetone (67-64-1) TLM fish 1 13000 ppm (96 h; Gambusia affinis; Turbulent water) TLM fish 2 > 1000 ppm (96 h; Pisces) Threshold limit other aquatic organisms 1 3000 mg/l (Plankton) Threshold limit other aquatic organisms 2 28 mg/l (Protozoa) Threshold limit algae 1 7500 mg/l (Scenedesmus quadricauda; pH = 7) Threshold limit algae 2 3400 mg/l (48 h; Chlorella sp.) Carbon Dioxide, Liquefied, Under Pressure (124-38-9) LC50 fish 1 35 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Lethal) LC50 fish 2 60 - 240 mg/l (12 h; Salmo gairdneri (Oncorhynchus mykiss); Lethal) Methanol (67-56-1) LC50 fish 1 15400 mg/l (96 h; Lepomis macrochirus; Lethal) EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna; Lethal) LC50 fish 2 10800 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 2 24500 mg/l (48 h; Daphnia magna; Locomotor effect) Threshold limit other aquatic organisms 1 6600 mg/l (16 h; Pseudomonas putida) Threshold limit algae 1 530 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 8000 mg/l (168 h; Scenedesmus quadricauda) Acetone (67-64-1) LC50 fish 1 6210 mg/l (96 h; Pimephales promelas; Nominal concentration) EC50 Daphnia 1 8800 mg/l (48 h; Daphnia pulex) LC50 fish 2 5540 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) TLM fish 1 13000 ppm (96 h; Gambusia affinis; Turbulent water) TLM fish 2 > 1000 ppm (96 h; Pisces) Threshold limit other aquatic organisms 1 3000 mg/l (Plankton) Threshold limit other aquatic organisms 2 28 mg/l (Protozoa) Threshold limit algae 1 7500 mg/l (Scenedesmus quadricauda; pH = 7) Threshold limit algae 2 3400 mg/l (48 h; Chlorella sp.) 12.2. Persistence and degradability AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Persistence and degradability Not established. Benzene (71-43-2) Persistence and degradability Readily biodegradable in water. Ozonation in water. Forming sediments in water. Biodegradable in the soil. Low potential for adsorption in soil. Photolysis in the air. Biochemical oxygen demand (BOD) 2.18 g O? /g substance Chemical oxygen demand (COD) 2.15 g O? /g substance ThOD 3.10 g O? /g substance BOD (% of ThOD) 0.70 % ThOD Toluene (108-88-3) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Low potential for adsorption in soil. Biochemical oxygen demand (BOD) 2.15 g O? /g substance Chemical oxygen demand (COD) 2.52 g O? /g substance ThOD 3.13 g O? /g substance BOD (% of ThOD) 0.69 % ThOD Acetone (67-64-1) Persistence and degradability Not established. Carbon Dioxide, Liquefied, Under Pressure (124-38-9) Persistence and degradability Biodegradability: not applicable. Not applicable (gas). Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 8/1 Methanol (67-56-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil. Biochemical oxygen demand (BOD) 0.6 - 1.12 g O? /g substance Chemical oxygen demand (COD) 1.42 g O? /g substance ThOD 1.5 g O? /g substance BOD (% of ThOD) 0.8 % ThOD Acetone (67-64-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No (test)data on mobility of the substance available. Not established. Biochemical oxygen demand (BOD) 1.43 g O? /g substance Chemical oxygen demand (COD) 1.92 g O? /g substance ThOD 2.20 g O? /g substance BOD (% of ThOD) (20 day(s)) 0.872 12.3. Bioaccumulative potential AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Log Pow -0.24 (Test data) Bioaccumulative potential Not established. Benzene (71-43-2) BCF fish 1 19 Salmo gairdneri (Oncorhynchus mykiss) BCF fish 2 < 10 (3 days; Leuciscus idus) BCF other aquatic organisms 1 30 (24 h; Chlorella sp.; Fresh weight) Log Pow 2.13 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Toluene (108-88-3) BCF fish 1 13.2 (Anguilla japonica) BCF fish 2 90 (72 h; Leuciscus idus) BCF other aquatic organisms 1 380 (24 h; Chlorella sp.; Fresh weight) BCF other aquatic organisms 2 4.2 (Mytilus edulis; Fresh weight) Log Pow 2.73 (Experimental value; Other; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Acetone (67-64-1) Bioaccumulative potential Not established. Carbon Dioxide, Liquefied, Under Pressure (124-38-9) Log Pow 0.83 (Experimental value) Bioaccumulative potential Bioaccumulation: not applicable. Methanol (67-56-1) BCF fish 1 < 10 (72 h; Leuciscus idus) BCF fish 2 1 (72 h; Cyprinus carpio; Blood) Log Pow -0.77 (Experimental value; Other) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Acetone (67-64-1) BCF fish 1 0.69 (Pisces) BCF other aquatic organisms 1 3 Log Pow -0.24 (Test data) Bioaccumulative potential Not bioaccumulative. Not established. 12.4. Mobility in soil Benzene (71-43-2) Surface tension 0.029 N/m (20 ?C) Toluene (108-88-3) Surface tension 0.03 N/m (20 ?C) Methanol (67-56-1) Surface tension 0.023 N/m (20 ?C) Acetone (67-64-1) Surface tension 0.0237 N/m (20 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 9/1 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information : Flammable vapors may accumulate in the container. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1950, Aerosols, 2.1, Limited Quantity ICAO/IATA (air): UN1950, Aerosols, 2.1 , Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.1 , Limited Quantity Special Provisions: N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols. Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Aerosols flammable, (each not exceeding 1 L capacity) Transport hazard class(es) (DOT) : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 Hazard labels (DOT) : 2.1 - Flammable gas DOT Special Provisions (49 CFR 172.102) : N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : None DOT Packaging Bulk (49 CFR 173.xxx) : None 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 48 - Stow ??away from?? sources of heat,87 - Stow ??separated from?? Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 75 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Sudden release of pressure hazard Benzene (71-43-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 Toluene (108-88-3) Listed on United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 10/1 Toluene (108-88-3) SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Methanol (67-56-1) Listed on United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 Listed on the United States SARA Section 355 SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard Delayed (chronic) health hazard 15.2. International regulations CANADA AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. WHMIS Classification Class B Division 5 - Flammable Aerosol Benzene (71-43-2) Listed on the Canadian DSL (Domestic Sustances List) Toluene (108-88-3) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Methanol (67-56-1) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Acetone (67-64-1) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations Toluene (108-88-3) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Methanol (67-56-1) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Acetone (67-64-1) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)- Directive 79/831/EEC, sixth Amendment of Directive 67/548/EEC (dangerous substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Repr.Cat.3; R63 F; R11 Xn; R20/21/22 Xn; R68/20/21/22 Xn; R48/20 Xi; R36/38 Full text of R-phrases: see section 16 15.2.2. National regulations AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 11/1 Benzene (71-43-2) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on KECI (Korean Existing Chemicals Inventory) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Toluene (108-88-3) Methanol (67-56-1) Listed on the Canadian IDL (Ingredient Disclosure List) Acetone (67-64-1) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on KECI (Korean Existing Chemicals Inventory) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) 15.3. US State regulations AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Benzene (71-43-2) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes Yes No Yes Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No Yes Yes No Acetone (67-64-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No Carbon Dioxide, Liquefied, Under Pressure (124-38-9) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No Methanol (67-56-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No Yes No No Acetone (67-64-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - U.S. - California - Proposition 65 - Reproductive Toxicity - No significance risk level (NSRL) AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 12/1 Acetone (67-64-1) Female Male Yes No No No Benzene (71-43-2) State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) U.S. - Pennsylvania - RTK (Right to Know) List New Jersey Right-to-Know Toluene (108-88-3) State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) U.S. - New Jersey - Special Health Hazards Substances List New Jersey Right-to-Know U.S. - Massachusetts - Right To Know List Rhode Island Right to Know U.S. - Michigan - Critical Materials List U.S. - New Jersey - Environmental Hazardous Substances List U.S. - Illinois - Toxic Air Contaminants U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List Methanol (67-56-1) State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) New Jersey Right-to-Know Florida Right to Know U.S. - Massachusetts - Right To Know List U.S. - Pennsylvania - RTK (Right to Know) List Acetone (67-64-1) State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Benzene 71-43-2 U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Other information : None. Full text of H-phrases: ------ Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 ------ Acute Tox. 3 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 3 ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Asp. Tox. 1 Aspiration hazard Category 1 ------ Compressed gas Gases under pressure Compressed gas ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Aerosol 2 Flammable aerosol Category 2 ------ Flam. Liq. 2 Flammable liquids Category 2 ------ Repr. 2 Reproductive toxicity Category 2 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 ------ STOT SE 1 Specific target organ toxicity (single exposure) Category 1 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H223 Flammable aerosol ------ H225 Highly flammable liquid and vapor ------ H280 Contains gas under pressure; may explode if heated ------ H301 Toxic if swallowed ------ H304 May be fatal if swallowed and enters airways ------ H311 Toxic in contact with skin ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H331 Toxic if inhaled ------ H336 May cause drowsiness or dizziness ------ H361 Suspected of damaging fertility or the unborn child AUTOGUARD NON-CHLORINATED BRAKE CLEANER 13 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15/05/2015 EN (English US) 13/1 ------ H370 Causes damage to organs ------ H373 May cause damage to organs through prolonged or repeated exposure NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 1 Slight Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.