SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 1 / 15 SECTION 1. IDENTIFICATION Product name : MM SUPER RADTR FLUSH 12/22 OZ Product code : C2124 Manufacturer or supplier's details Company name of supplier : Niteo Products, LLC Address : Dallas TX 75225 Email Address : This email address is being protected from spambots. You need JavaScript enabled to view it. Telephone : 1-844-696-4836 Emergency telephone num- ber : 1-800-424-9300 / 1-703-741-5970 Recommended use of the chemical and restrictions on use Recommended use : RADIATOR FLUSH Restrictions on use : Use only outdoors or in a well-ventilated area. SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin irritation : Category 2 Eye irritation : Category 2A Carcinogenicity : Category 2 Reproductive toxicity : Category 1B Specific target organ toxicity - repeated exposure (Inhala- tion) : Category 2 (Respiratory Tract) GHS label elements Hazard pictograms : Signal word : Danger SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 2 / 15 Hazard statements : Causes skin irritation. Causes serious eye irritation. Suspected of causing cancer. May damage fertility or the unborn child. May cause damage to organs (Respiratory Tract) through pro- longed or repeated exposure if inhaled. Precautionary statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (% w/w) Citric acid 77-92-9 >= 5 - < 10 Tetrasodium EDTA 64-02-8 >= 1 - < 5 Potassium dodecylbenzene sulfonate 27177-77-1 >= 1 - < 5 2-Butoxyethanol 111-76-2 >= 1 - < 5 N-Methylpyrrolidone 872-50-4 >= 1 - < 5 Trisodium nitrilotriacetate 5064-31-3 >= 0.1 - < 1 Any concentration shown as a range is to protect confidentiality or is due to batch variation. SECTION 4. FIRST AID MEASURES SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 3 / 15 General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Clean mouth with water and drink afterwards plenty of water. Induce vomiting immediately and call a physician. Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. Most important symptoms and effects, both acute and delayed : Causes skin irritation. Causes serious eye irritation. Suspected of causing cancer. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure if inhaled. Notes to physician : Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Unsuitable extinguishing media : High volume water jet Specific hazards during fire- fighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion prod- ucts : Nitrogen oxides (NOx) Carbon oxides Sulphur oxides Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if nec- essary. SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 4 / 15 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : Do not store near acids. Further information on stor- age stability : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis 2-Butoxyethanol 111-76-2 TWA 20 ppm ACGIH TWA 5 ppm 24 mg/m3 NIOSH REL TWA 50 ppm OSHA Z-1 SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 5 / 15 240 mg/m3 TWA 25 ppm 120 mg/m3 OSHA P0 N-Methylpyrrolidone 872-50-4 TWA 10 ppm US WEEL Biological occupational exposure limits Components CAS-No. Control parameters Biological specimen Sam- pling time Permissible concentra- tion Basis 2-Butoxyethanol 111-76-2 Butoxyace- tic acid (BAA) Urine End of shift (As soon as possible after exposure ceases) 200 mg/g Creatinine ACGIH BEI N-Methylpyrrolidone 872-50-4 5-Hydroxy- N-methyl-2- pyrrolidone Urine End of shift (As soon as possible after exposure ceases) 100 mg/l ACGIH BEI Personal protective equipment Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and con- centration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : No data available Odour : No data available Odour Threshold : No data available pH : 4.4 SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 6 / 15 Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : estimated > 93.4 ?C Evaporation rate : No data available Upper explosion limit / Upper flammability limit : No data available Lower explosion limit / Lower flammability limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 1.0633 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : No data available Decomposition temperature : No data available Viscosity Viscosity, kinematic : No data available Molecular weight : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reac- tions : No decomposition if stored and applied as directed. Conditions to avoid : No data available Incompatible materials : Strong oxidizing agents Not applicable Hazardous decomposition products : Carbon oxides Hazardous decomposition products : SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 7 / 15 SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate: 22.51 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Components: Citric acid: Acute oral toxicity : LD50 (Mouse): 6,730 mg/kg Tetrasodium EDTA: Acute oral toxicity : LD50 (Rat, female): 1,780 mg/kg Acute inhalation toxicity : LC50 (Rat): > 1 - 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Potassium dodecylbenzene sulfonate: Acute oral toxicity : LD50 (Rat): 1,080 - 1,980 mg/kg Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Remarks: Information given is based on data obtained from similar substances. 2-Butoxyethanol: Acute oral toxicity : LD50 (Guinea pig): 1,200 mg/kg SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 8 / 15 Acute inhalation toxicity : LC50 (Guinea pig): > 633 ppm Exposure time: 1 h Test atmosphere: dust/mist Assessment: The component/mixture is moderately toxic after short term inhalation. Acute dermal toxicity : LD50 (Guinea pig): > 2,000 mg/kg Assessment: The component/mixture is moderately toxic after single contact with skin. N-Methylpyrrolidone: Acute oral toxicity : LD50 (Rat): 4,150 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.1 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD50 (Rabbit): 8,000 mg/kg Trisodium nitrilotriacetate: Acute oral toxicity : LD50 (Rat, male and female): 1,740 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC0 (Rat): 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: No adverse effect has been observed in acute dermal toxicity tests. Skin corrosion/irritation Causes skin irritation. Product: Remarks: May cause skin irritation in susceptible persons. Components: Citric acid: Result: Possibly irritating to skin Tetrasodium EDTA: Species: Rabbit Result: No skin irritation Potassium dodecylbenzene sulfonate: Result: Corrosive after 1 to 4 hours of exposure SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 9 / 15 Remarks: Information given is based on data obtained from similar substances. 2-Butoxyethanol: Method: Directive 67/548/EEC, Annex V, B.4. Result: Irritating to skin. N-Methylpyrrolidone: Assessment: Irritating to skin. Result: irritating Trisodium nitrilotriacetate: Result: Possibly irritating to skin Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks: May cause irreversible eye damage. Components: Citric acid: Result: Irritating to eyes. Tetrasodium EDTA: Result: Irritating to eyes. Potassium dodecylbenzene sulfonate: Result: Corrosive Method: OECD Test Guideline 405 Remarks: Information given is based on data obtained from similar substances. 2-Butoxyethanol: Result: Irritating to eyes. Method: OECD Test Guideline 405 N-Methylpyrrolidone: Result: Irritation to eyes, reversing after 7 to 21 days Assessment: Irritating to eyes. Trisodium nitrilotriacetate: Result: Irritating to eyes. Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 10 / 15 Respiratory sensitisation Not classified based on available information. Components: Tetrasodium EDTA: Test Type: Maximisation Test Species: Guinea pig Assessment: Does not cause skin sensitisation. Method: OECD Test Guideline 406 Remarks: Information given is based on data obtained from similar substances. Potassium dodecylbenzene sulfonate: Exposure routes: Dermal Species: Humans Assessment: Does not cause skin sensitisation. Remarks: Information given is based on data obtained from similar substances. 2-Butoxyethanol: Species: Guinea pig Method: OECD Test Guideline 406 Result: Not a skin sensitizer. N-Methylpyrrolidone: Assessment: Does not cause skin sensitisation. Result: Did not cause sensitisation on laboratory animals. Trisodium nitrilotriacetate: Test Type: Maximisation Test Species: Guinea pig Assessment: Did not cause sensitisation on laboratory animals. Method: OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Components: Tetrasodium EDTA: Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative Potassium dodecylbenzene sulfonate: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Result: negative Remarks: Information given is based on data obtained from similar substances. SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 11 / 15 2-Butoxyethanol: Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative N-Methylpyrrolidone: Genotoxicity in vitro : Remarks: In vitro tests did not show mutagenic effects Genotoxicity in vivo : Test Type: Micronucleus test Species: Mouse Application Route: Oral Result: negative Test Type: Chinese hamster Application Route: Oral Result: negative Trisodium nitrilotriacetate: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Method: Mutagenicity (Salmonella typhimurium - reverse mu- tation assay) Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster fibroblasts Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Genotoxicity in vivo : Test Type: Micronucleus test Species: Mouse (male) Application Route: Oral Method: OECD Test Guideline 474 Result: negative Carcinogenicity Suspected of causing cancer. Components: Trisodium nitrilotriacetate: Carcinogenicity - Assess- ment : Limited evidence of carcinogenicity in animal studies IARC Group 2B: Possibly carcinogenic to humans Trisodium nitrilotriacetate 5064-31-3 OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 12 / 15 NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity May damage fertility or the unborn child. Components: N-Methylpyrrolidone: Reproductive toxicity - As- sessment : Clear evidence of adverse effects on sexual function and fertil- ity, and/or on development, based on animal experiments STOT - single exposure Not classified based on available information. Components: N-Methylpyrrolidone: Exposure routes: Inhalation Target Organs: Nose Assessment: May cause respiratory irritation. STOT - repeated exposure May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if in- haled. Components: Tetrasodium EDTA: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: The substance or mixture is classified as specific target organ toxicant, repeated exposure, category 2. Repeated dose toxicity Components: N-Methylpyrrolidone: Species: Rat NOAEL: 169 mg/kg Application Route: Ingestion Exposure time: N11.00322330 Species: Rat NOAEL: 0.5 mg/l Application Route: Inhalation Test atmosphere: dust/mist Exposure time: N11.00322330 Species: Rabbit NOAEL: 826 mg/kg Application Route: Skin contact SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 13 / 15 Exposure time: N11.00322320 Aspiration toxicity Not classified based on available information. Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Toxicity Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated below) may not reflect quantity, end-use, or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. International Regulations IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good 49 CFR Not regulated as a dangerous good SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 14 / 15 SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium hydroxide 1310-73-2 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Carcinogenicity Reproductive toxicity Specific target organ toxicity (single or repeated exposure) Skin corrosion or irritation Serious eye damage or eye irritation SARA 313 : The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: 2-Butoxyethanol 111-76-2 >= 1 - < 5 % N-Methylpyrrolidone 872-50-4 >= 1 - < 5 % California Prop. 65 WARNING: This product can expose you to chemicals including N-Methylpyrrolidone, which is/are known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. SAFETY DATA SHEET MOTOR MEDIC? SUPER HEAVY DUTY RADIATOR FLUSH Version 2.2 Revision Date: 03/29/2023 SDS Number: 600000001496 Date of last issue: 05/11/2021 Date of first issue: 07/30/2018 15 / 15 SECTION 16. OTHER INFORMATION Further information NFPA: Revision Date : 03/29/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN Flammability H e a lt h In s ta b ility 2 1 0 Special hazard