SAFETY DATA SHEET1. Identification Gunk Engine Protector - ShineProduct identifierOther means of identification CEB1SDS number CEB1Part No. 3814.00.1000Tariff code ProtectorRecommended use None known.Recommended restrictions2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Category 5Acute toxicity, oralHealth hazards Category 2ASerious eye damage/eye irritation Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Not classified.OSHA defined hazardsLabel elementsSignal word DangerHazard statement Extremely flammable aerosol. May be harmful if swallowed. May be fatal if swallowed and enters airways. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life.Precautionary statementPrevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist/vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear eye protection/face protection.Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F.Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. 1 / 10 Material name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 SDS US Manufacturer/Importer/Supplier/Distributor informationManufacturerCompany nameAddressEmergency phone numberTelephoneWebsite Blaster LLC8500 Sweet Valley DriveValley View, Ohio 44125 - USAT (216)901-5800 F (216)901-5801www.blastercorp.comChemtrec (800) 424-9300 Hazard(s) not otherwiseclassified (HNOC) None known.Supplemental information NOTE: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The container label may not include the OSHA label elements listed in this document. Always carefully review the entire SDS and the product label prior to use in the workplace.3. Composition/information on ingredientsMixtures CAS number %Chemical name Common name and synonyms 64742-53-6Hydrotreated Light Naphthenic Distillates Petroleum 20 - < 30 67784-80-9Soy Methyl Esters 20 - < 30 8001-22-7Soybean Oil 20 - < 30 94266-47-4Citrus Terpenes 5 - < 10 25498-49-1Tripropylene Glycol Monomethyl Ether 3 - < 5 124-38-9Carbon Dioxide 1 - < 3 57171-56-9Poly(oxyethylene) Sorbitol Hexaoleate 1 - < 3 26264-05-1Isopropylamine Dodecylbenzene Sulfonate < 1 57-55-6Propylene Glycol < 0.3 7732-18-5Water < 0.1 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Ingestion Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Most importantsymptoms/effects, acute anddelayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediatemedical attention and specialtreatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General information5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising fromthe chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipmentand precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods Extremely flammable aerosol.General fire hazards 2 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions,protective equipment andemergency procedures Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials forcontainment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Environmental precautions7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not taste or swallow. Avoid contact with eyes. Avoid prolonged exposure. When using, do not eat, drink or smoke. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in tightly closed container. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) FormValueComponents Type PEL 9000 mg/m3Carbon Dioxide (CAS 124-38-9) 5000 ppm PEL 5 mg/m3 Mist.Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6) 2000 mg/m3 500 ppm PEL 5 mg/m3 Respirable fraction.Soybean Oil (CAS 8001-22-7) 15 mg/m3 Total dust.US. ACGIH Threshold Limit Values FormValueComponents Type STEL 30000 ppmCarbon Dioxide (CAS 124-38-9) TWA 5000 ppm 3 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 US. ACGIH Threshold Limit Values FormValueComponents Type TWA 5 mg/m3 Inhalable fraction.Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6)US. NIOSH: Pocket Guide to Chemical Hazards FormValueComponents Type STEL 54000 mg/m3Carbon Dioxide (CAS 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm Ceiling 1800 mg/m3Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6) STEL 10 mg/m3 Mist. TWA 5 mg/m3 Respirable mist.Soybean Oil (CAS 8001-22-7) 10 mg/m3 Total mistUS. Workplace Environmental Exposure Level (WEEL) Guides FormValueComponents Type TWA 10 mg/m3 Aerosol.Propylene Glycol (CAS 57-55-6) No biological exposure limits noted for the ingredient(s).Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles). Applicable for industrial settings only. Eye/face protectionSkin protection Wear appropriate chemical resistant gloves. Applicable for industrial settings only.Hand protection Wear appropriate chemical resistant clothing. Applicable for industrial settings only.Other If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Chemical respirator with organic vapor cartridge and full facepiece if threshold limits are exceeded. Dust & vapor respirator. Applicable for industrial settings only. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygieneconsiderations9. Physical and chemical properties Liquid Clear. Aerosol.Appearance Liquid.Physical state Aerosol.Form Yellow-orange.Color MildOdorOdor threshold Not available.pH Not available.Melting point/freezing point Not available. 4 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 Initial boiling point and boilingrange Not available.Flash point 172.0 ?F (77.8 ?C) Tag Closed CupEvaporation rate Not available. Not applicable.Flammability (solid, gas)Upper/lower flammability or explosive limitsFlammability limit - lower(%) Not available.Flammability limit - upper(%) Not available.Explosive limit - lower (%) Not available.Explosive limit - upper (%) Not available.Vapor pressure 0.1 hPa estimatedVapor density Not available.Relative density Not available.Solubility(ies)Solubility (water) Not available.Partition coefficient(n-octanol/water) Not available.Auto-ignition temperature Not available.Decomposition temperature Not available.Viscosity Not available.Other informationDensity 7.42 lbs/gal Not explosive.Explosive propertiesFlame extension > 30 inFlammability (flash back) NoFlammability class Combustible IIIA estimatedHeat of combustion (NFPA30B) > 30 kJ/g Not oxidizing.Oxidizing propertiesRefractive index 1.46Specific gravity 0.89VOC 7.410. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardousreactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful.Skin contact No adverse effects due to skin contact are expected.Eye contact Causes serious eye irritation. 5 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 Ingestion May be harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.Symptoms related to thephysical, chemical andtoxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision.Information on toxicological effectsAcute toxicity May be fatal if swallowed and enters airways. Test ResultsComponents Species Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6)DermalAcute LD50 Rabbit > 2000 mg/kg, 24 HoursInhalation LC50 Rat > 3.9 mg/l, 4 HoursOral LD50 Rat > 2000 mg/kg Propylene Glycol (CAS 57-55-6)DermalAcute LD50 Rabbit > 2000 mg/kg, 24 HoursOral LD50 Rat 22000 mg/kg Tripropylene Glycol Monomethyl Ether (CAS 25498-49-1)DermalAcute LD50 Rabbit 15440 mg/kg, 24 HoursOral LD50 Rat 3400 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicityCarcinogenicity Not classifiable as to carcinogenicity to humans.IARC Monographs. Overall Evaluation of Carcinogenicity Not listed.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated.US. National Toxicology Program (NTP) Report on Carcinogens Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6) Known To Be Human Carcinogen. This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure May cause drowsiness and dizziness.Specific target organ toxicity -repeated exposure Not classified.Aspiration hazard May be fatal if swallowed and enters airways.Chronic effects Prolonged inhalation may be harmful. 6 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 12. Ecological information Toxic to aquatic life.EcotoxicityComponents Test ResultsSpecies Propylene Glycol (CAS 57-55-6)Aquatic EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 710 mg/l, 96 hoursFathead minnow (Pimephales promelas) No data is available on the degradability of any ingredients in the mixture.Persistence and degradabilityBioaccumulative potentialPartition coefficient n-octanol / water (log Kow) Propylene Glycol -0.92 No data available.Mobility in soilOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unusedproducts Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging14. Transport informationDOT UN1950UN number Aerosol, flammable, MARINE POLLUTANT, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesMarine pollutantEnvironmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for userIATA UN1950UN number Aerosol, flammable, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesEnvironmental hazards 9LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargoaircraftOther information Allowed with restrictions.Cargo aircraft onlyIMDG UN1950UN number 7 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 AEROSOLS, FLAMMABLE, MARINE POLLUTANT (Citrus Terpenes), Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesMarine pollutantEnvironmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Citrus Terpenes Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC CodeDOT; IMDGIATAMarine pollutant IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant.General information15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.CERCLA Hazardous Substance List (40 CFR 302.4) Not listed.SARA 304 Emergency release notification Not regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. 8 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 SARA 302 Extremely hazardous substanceSuperfund Amendments and Reauthorization Act of 1986 (SARA) Not listed.SARA 313 (TRI reporting) Not regulated.Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act(SDWA)US state regulationsCalifornia Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov.US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,subd. (a)) Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6)International InventoriesCountry(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).16. Other information, including date of preparation or last revision 05-21-2015Issue dateRevision dateVersion #HMIS? ratings 02-16-202308 Health: 3 Flammability: 4 Physical hazard: 0 Health: 2 Flammability: 4 Instability: 0 NFPA ratingsNFPA ratings 02 4 9 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer Physical & Chemical Properties: Multiple PropertiesRevision information 10 / 10 SDS USMaterial name: Gunk Engine Protector - Shine CEB1 Version #: 08 Revision date: 02-16-2023 Issue date: 05-21-2015