SDS Repository

sds

Collection
Motor Medic
Description
Feb1 17OZ GUNK ENGINE CLEANER FOAMY
Tags
Search Tag
Filename
FEB1_EN.pdf
Source
 
Full Text
SAFETY DATA SHEET1. Identification Gunk Engine Cleaner - FoamyProduct identifierOther means of identification FEB1SDS number FEB1, FEB1/6Part No. 3402.20.5100Tariff code Engine CleanerRecommended use None known.Recommended restrictions2. Hazard(s) identification Classification not possibleFlammable aerosolsPhysical hazards Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 1BGerm cell mutagenicity Category 1ACarcinogenicity Category 1Aspiration hazard Category 3Hazardous to the aquatic environment, acutehazardEnvironmental hazards Category 3Hazardous to the aquatic environment,long-term hazardNot classified.OSHA defined hazardsLabel elementsSignal word DangerHazard statement Pressurized container: May burst if heated. May be fatal if swallowed and enters airways. Causesskin irritation. May cause an allergic skin reaction. May cause genetic defects. May cause cancer.Harmful to aquatic life. Harmful to aquatic life with long lasting effects.Precautionary statementPrevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Avoid breathing mist/vapor. Wash thoroughly after handling. Do not eat, drink orsmoke when using this product. Contaminated work clothing must not be allowed out of theworkplace. Avoid release to the environment. Wear protective gloves/protective clothing/eyeprotection/face protection. 1 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS USManufacturer/Importer/Supplier/Distributor informationManufacturerCompany nameAddressEmergency phone numberTelephoneWebsite Blaster LLC8500 Sweet Valley Drive Valley View, Ohio 44125 - USA T(216)901-5800F (216)901-5801www.blastercorp.comChemtrec (800) 424-9300 Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. Ifon skin: Wash with plenty of water. If exposed or concerned: Get medical advice/attention. If skinirritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and washbefore reuse.Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F.Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC) GHS Level 3 Non-flammable aerosol (version 7 - July 2017)Supplemental information NOTE: This product is a consumer product and is labeled in accordance with the US ConsumerProduct Safety Commission regulations which take precedence over OSHA HazardCommunication labeling. The container label may not include the OSHA label elements listed inthis document. Always carefully review the entire SDS and the product label prior to use in theworkplace.3. Composition/information on ingredientsMixtures CAS number %Chemical name Common name and synonyms 7732-18-5Water 70 - < 8068476-86-8Petroleum Gases, Liquefied,Sweetened 5 - < 1064742-94-5C9-15 Heavy AromaticHydrocarbons 3 - < 58008-20-6Kerosene 1 - < 3527-53-71,2,3,5-tetramethylbenzene < 1105-05-51,4-diethylbenzene < 1111-76-2Butoxyethanol < 1110-91-8Morpholine < 1112-80-1Oleic Acid < 131138-65-5Sodium Glucoheptonate < 198-06-6Tert-butylbenzene < 1488-23-31,2,3,4-tetramethylbenzene < 0.391-20-3Naphthalene < 0.3526-73-81,2,3-Trimethylbenzene < 0.295-63-61,2,4-Trimethylbenzene < 0.2496-11-71h-indene, 2,3-dihydro- < 0.21074-43-73-propyltoluene < 0.2102-71-6Triethanolamine < 0.2141-93-5Benzene, 1,3-diethyl- < 0.198-82-8Cumene < 0.1111-42-2Diethanolamine < 0.125340-17-4Diethylbenzene < 0.1107-15-3Ethylenediamine < 0.1109-86-4Methoxyethanol < 0.1100-74-3N-Ethylmorpholine < 0.1*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case ofeczema or other skin disorders: Seek medical attention and take along these instructions. Washcontaminated clothing before reuse.Skin contact Rinse with water. Get medical attention if irritation develops and persists.Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.Ingestion 2 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness andpain. May cause an allergic skin reaction. Dermatitis. Rash.Most importantsymptoms/effects, acute anddelayed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victimunder observation. Symptoms may be delayed.Indication of immediatemedical attention and specialtreatment needed IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice(show the label where possible). Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Show this safety data sheet to the doctor inattendance. Wash contaminated clothing before reuse.General information5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia Contents under pressure. Pressurized container may explode when exposed to heat or flame.During fire, gases hazardous to health may be formed.Specific hazards arising fromthe chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipmentand precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled withwater to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hoseholder or monitor nozzles, if possible. If not, withdraw and let fire burn out.Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainers from fire area if you can do so without risk. In the event of fire and/or explosion do notbreathe fumes.Specific methods6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapor. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Local authorities should be advised if significantspillages cannot be contained. For personal protection, see section 8 of the SDS.Personal precautions,protective equipment andemergency procedures Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so withoutrisk. Move the cylinder to a safe and open area if the leak is irreparable. Eliminate all ignitionsources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood,paper, oil, etc.) away from spilled material. Prevent product from entering drains. Absorb invermiculite, dry sand or earth and place into containers. Following product recovery, flush areawith water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. Put material in suitable, covered, labeled containers. For wastedisposal, see section 13 of the SDS.Methods and materials forcontainment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.Environmental precautions7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spraybutton is missing or defective. Do not spray on a naked flame or any other incandescent material.Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment usedwhen handling the product must be grounded. Do not re-use empty containers. Do not taste orswallow. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, donot eat, drink or smoke. Should be handled in closed systems, if possible. Use only inwell-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughlyafter handling. Avoid release to the environment. Observe good industrial hygiene practices.Precautions for safe handling Level 1 Aerosol.Store locked up. Pressurized container. Protect from sunlight and do not expose to temperaturesexceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an openflame, heat or other sources of ignition. This material can accumulate static charge which maycause spark and become an ignition source. Store in tightly closed container. Store away fromincompatible materials (see Section 10 of the SDS).Conditions for safe storage,including any incompatibilities 3 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US 8. Exposure controls/personal protectionOccupational exposure limitsThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents TypePEL 240 mg/m3Butoxyethanol (CAS111-76-2) 50 ppmPEL 400 mg/m3C9-15 Heavy AromaticHydrocarbons (CAS64742-94-5) 100 ppmPEL 245 mg/m3Cumene (CAS 98-82-8) 50 ppmPEL 25 mg/m3Ethylenediamine (CAS107-15-3) 10 ppmPEL 80 mg/m3Methoxyethanol (CAS109-86-4) 25 ppmPEL 70 mg/m3Morpholine (CAS 110-91-8) 20 ppmPEL 50 mg/m3Naphthalene (CAS 91-20-3) 10 ppmPEL 94 mg/m3N-Ethylmorpholine (CAS100-74-3) 20 ppmUS. ACGIH Threshold Limit Values FormValueComponents TypeTWA 25 ppm1,2,3-Trimethylbenzene(CAS 526-73-8) TWA 25 ppm1,2,4-Trimethylbenzene(CAS 95-63-6) TWA 20 ppmButoxyethanol (CAS111-76-2) TWA 200 mg/m3 Non-aerosol.C9-15 Heavy AromaticHydrocarbons (CAS64742-94-5) TWA 50 ppmCumene (CAS 98-82-8) TWA 1 mg/m3 Inhalable fraction andvapor.Diethanolamine (CAS111-42-2) TWA 10 ppmEthylenediamine (CAS107-15-3) TWA 200 mg/m3 Non-aerosol.Kerosene (CAS 8008-20-6) TWA 0.1 ppmMethoxyethanol (CAS109-86-4) TWA 20 ppmMorpholine (CAS 110-91-8) TWA 10 ppmNaphthalene (CAS 91-20-3) TWA 5 ppmN-Ethylmorpholine (CAS100-74-3) TWA 5 mg/m3Triethanolamine (CAS102-71-6) 4 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents TypeTWA 125 mg/m31,2,3-Trimethylbenzene(CAS 526-73-8) 25 ppmTWA 125 mg/m31,2,4-Trimethylbenzene(CAS 95-63-6) 25 ppmTWA 24 mg/m3Butoxyethanol (CAS111-76-2) 5 ppmTWA 245 mg/m3Cumene (CAS 98-82-8) 50 ppmTWA 15 mg/m3Diethanolamine (CAS111-42-2) 3 ppmTWA 25 mg/m3Ethylenediamine (CAS107-15-3) 10 ppmTWA 100 mg/m3Kerosene (CAS 8008-20-6) TWA 0.3 mg/m3Methoxyethanol (CAS109-86-4) 0.1 ppmSTEL 105 mg/m3Morpholine (CAS 110-91-8) 30 ppmTWA 70 mg/m320 ppmSTEL 75 mg/m3Naphthalene (CAS 91-20-3) 15 ppmTWA 50 mg/m310 ppmTWA 23 mg/m3N-Ethylmorpholine (CAS100-74-3) 5 ppmUS. Workplace Environmental Exposure Level (WEEL) Guides ValueComponents TypeTWA 5 ppm1,4-diethylbenzene (CAS105-05-5) TWA 5 ppmBenzene, 1,3-diethyl- (CAS141-93-5) TWA 5 ppmDiethylbenzene (CAS25340-17-4)Biological limit valuesACGIH Biological Exposure IndicesValueComponents Determinant Specimen Sampling Time200 mg/g Butoxyaceticacid (BAA),with hydrolysis Creatinine inurine *Butoxyethanol (CAS111-76-2) 1 mg/g 2-Methoxyacetic acid Creatinine inurine *Methoxyethanol (CAS109-86-4)* - For sampling details, please see the source document. 5 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Exposure guidelinesUS - California OELs: Skin designationButoxyethanol (CAS 111-76-2) Can be absorbed through the skin.Cumene (CAS 98-82-8) Can be absorbed through the skin.Diethanolamine (CAS 111-42-2) Can be absorbed through the skin.Methoxyethanol (CAS 109-86-4) Can be absorbed through the skin.Morpholine (CAS 110-91-8) Can be absorbed through the skin.Naphthalene (CAS 91-20-3) Can be absorbed through the skin.N-Ethylmorpholine (CAS 100-74-3) Can be absorbed through the skin.US - Minnesota Haz Subs: Skin designation appliesButoxyethanol (CAS 111-76-2) Skin designation applies.Cumene (CAS 98-82-8) Skin designation applies.Methoxyethanol (CAS 109-86-4) Skin designation applies.Morpholine (CAS 110-91-8) Skin designation applies.N-Ethylmorpholine (CAS 100-74-3) Skin designation applies.US - Tennessee OELs: Skin designationButoxyethanol (CAS 111-76-2) Can be absorbed through the skin.Cumene (CAS 98-82-8) Can be absorbed through the skin.Methoxyethanol (CAS 109-86-4) Can be absorbed through the skin.Morpholine (CAS 110-91-8) Can be absorbed through the skin.N-Ethylmorpholine (CAS 100-74-3) Can be absorbed through the skin.US ACGIH Threshold Limit Values: Skin designationC9-15 Heavy Aromatic Hydrocarbons (CAS 64742-94-5) Can be absorbed through the skin.Diethanolamine (CAS 111-42-2) Can be absorbed through the skin.Ethylenediamine (CAS 107-15-3) Can be absorbed through the skin.Kerosene (CAS 8008-20-6) Can be absorbed through the skin.Methoxyethanol (CAS 109-86-4) Can be absorbed through the skin.Morpholine (CAS 110-91-8) Can be absorbed through the skin.Naphthalene (CAS 91-20-3) Can be absorbed through the skin.N-Ethylmorpholine (CAS 100-74-3) Can be absorbed through the skin.US NIOSH Pocket Guide to Chemical Hazards: Skin designationButoxyethanol (CAS 111-76-2) Can be absorbed through the skin.Cumene (CAS 98-82-8) Can be absorbed through the skin.Methoxyethanol (CAS 109-86-4) Can be absorbed through the skin.Morpholine (CAS 110-91-8) Can be absorbed through the skin.N-Ethylmorpholine (CAS 100-74-3) Can be absorbed through the skin.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.Cumene (CAS 98-82-8) Can be absorbed through the skin.Methoxyethanol (CAS 109-86-4) Can be absorbed through the skin.Morpholine (CAS 110-91-8) Can be absorbed through the skin.N-Ethylmorpholine (CAS 100-74-3) Can be absorbed through the skin.Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station and safety shower.Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipmentChemical respirator with organic vapor cartridge and full facepiece.Eye/face protectionSkin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other Chemical respirator with organic vapor cartridge and full facepiece. Chemical respirator withorganic vapor cartridge and full facepiece if threshold limits are exceeded.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards Observe any medical surveillance requirements. When using do not smoke. Keep away from foodand drink. Always observe good personal hygiene measures, such as washing after handling thematerial and before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants. Contaminated work clothing should not be allowed out of theworkplace.General hygieneconsiderations 6 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US 9. Physical and chemical propertiesLiquid HazyAppearance Liquid.Physical state Aerosol.Form CreamColor Sweet. Aromatic.OdorOdor threshold Not available.pH 9 - 10Melting point/freezing point Not available.Initial boiling point and boilingrange Not available.Flash point > 201.0 ?F (> 93.9 ?C) Tag Closed CupEvaporation rate Not available.Not applicable.Flammability (solid, gas)Upper/lower flammability or explosive limitsFlammability limit - lower(%) Not available.Flammability limit - upper(%) Not available.Explosive limit - lower (%) Not available.Explosive limit - upper (%) Not available.Vapor pressure 348.27662 hPa estimatedVapor density Not available.Relative density Not available.Solubility(ies)Solubility (water) Not available.Partition coefficient(n-octanol/water) Not available.Auto-ignition temperature Not available.Decomposition temperature Not available.Viscosity Not available.Other informationDensity 8.17 lbs/galNot explosive.Explosive propertiesFlammability (flash back) NoFlammability class Combustible IIIB estimatedHeat of combustion (NFPA30B) 2.41 kJ/g estimatedNot oxidizing.Oxidizing propertiesPercent volatile 83.6 % estimatedSpecific gravity 0.85VOC 17.06 %10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardousreactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoidtemperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials 7 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US No hazardous decomposition products are known.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation Prolonged inhalation may be harmful.Skin contact Causes skin irritation. May cause an allergic skin reaction.Eye contact Direct contact with eyes may cause temporary irritation.Ingestion Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion orvomiting may cause a serious chemical pneumonia.Symptoms related to thephysical, chemical andtoxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness andpain. May cause an allergic skin reaction. Dermatitis. Rash.Information on toxicological effectsAcute toxicity May be fatal if swallowed and enters airways. Test ResultsComponents Species1,2,3-Trimethylbenzene (CAS 526-73-8)OralAcuteLD50 Rat 8970 mg/kg1,2,4-Trimethylbenzene (CAS 95-63-6)DermalAcuteLD50 Rabbit > 3160 mg/kgOralLD50 Rat 6 g/kgButoxyethanol (CAS 111-76-2)DermalAcuteLD50 Rabbit 1060 mg/kg, 24 HoursOralLD50 Rat 530 - 2800 mg/kgC9-15 Heavy Aromatic Hydrocarbons (CAS 64742-94-5)DermalAcuteLD50 Rabbit > 2000 mg/kg, 24 HoursInhalationLC50 Rat < 5.8 mg/l, 4 HoursOralLD50 Rat < 5000 mg/kg> 25 ml/kgCumene (CAS 98-82-8)DermalAcuteLD50 Rabbit > 3160 mg/kg, 24 HoursInhalationLC50 Mouse 10 mg/l, 7 HoursVaporOralLD50 Rat 2260 mg/kg 8 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Test ResultsComponents SpeciesDiethanolamine (CAS 111-42-2)OralAcuteLD50 Rat 710 mg/kgEthylenediamine (CAS 107-15-3)DermalAcuteLD50 Rabbit 560 mg/kg, 24 HoursInhalationLC50 Rat 7.35 mg/l, 8 HoursVaporOralLD50 Rat 500 mg/kgKerosene (CAS 8008-20-6)DermalAcuteLD50 Rabbit > 2000 mg/kg, 24 HoursInhalationLC50 Rat > 0.1 mg/l, 8 HoursVaporOralLD50 Rat > 5000 mg/kgMethoxyethanol (CAS 109-86-4)DermalAcuteLD50 Rabbit 1280 mg/kgOralLD50 Rat 2257 mg/kgMorpholine (CAS 110-91-8)OralAcuteLD50 Rat 1.05 g/kgNaphthalene (CAS 91-20-3)DermalAcuteLD50 Rabbit > 2 g/kgOralLD50 Rat 490 mg/kgN-Ethylmorpholine (CAS 100-74-3)OralAcuteLD50 Rat 1490 - 2120 mg/kgOleic Acid (CAS 112-80-1)DermalAcuteLD50 Guinea pig > 3000 mg/kgOralLD50 Rat 74 g/kg 9 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Test ResultsComponents SpeciesSodium Glucoheptonate (CAS 31138-65-5)DermalAcuteLD50 Rat > 2000 mg/kg, 24 HoursOralLD50 Rat > 4040 mg/kgTriethanolamine (CAS 102-71-6)DermalAcuteLD50 Rabbit > 2000 mg/kgOralLD50 Rat 6400 mg/kgCauses skin irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.May cause an allergic skin reaction.Skin sensitization May cause genetic defects.Germ cell mutagenicityCarcinogenicity May cause cancer.IARC Monographs. Overall Evaluation of CarcinogenicityButoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans.Diethanolamine (CAS 111-42-2) 2B Possibly carcinogenic to humans.Morpholine (CAS 110-91-8) 3 Not classifiable as to carcinogenicity to humans.Naphthalene (CAS 91-20-3) 2B Possibly carcinogenic to humans.Triethanolamine (CAS 102-71-6) 3 Not classifiable as to carcinogenicity to humans.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.US. National Toxicology Program (NTP) Report on CarcinogensCumene (CAS 98-82-8) Reasonably Anticipated to be a Human Carcinogen.Naphthalene (CAS 91-20-3) Reasonably Anticipated to be a Human Carcinogen.This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure Not classified.Specific target organ toxicity -repeated exposure Not classified.Aspiration hazard May be fatal if swallowed and enters airways.Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.12. Ecological information Harmful to aquatic life with long lasting effects.EcotoxicityComponents Test ResultsSpecies1,2,4-Trimethylbenzene (CAS 95-63-6)Aquatic LC50Fish 7.19 - 8.28 mg/l, 96 hoursFathead minnow (Pimephales promelas)1h-indene, 2,3-dihydro- (CAS 496-11-7)Aquatic LC50Fish 14 mg/l, 96 hoursFathead minnow (Pimephales promelas)Benzene, 1,3-diethyl- (CAS 141-93-5)Aquatic LC50Fish 4.05 - 4.25 mg/l, 96 hoursFathead minnow (Pimephales promelas) 10 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Components Test ResultsSpeciesButoxyethanol (CAS 111-76-2)Aquatic LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina)C9-15 Heavy Aromatic Hydrocarbons (CAS 64742-94-5)Aquatic EC50Crustacea 2.7 - 5.1 mg/l, 48 hoursWater flea (Daphnia pulex)LC50Fish 8.8 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) 8.8 mg/l, 96 hoursCumene (CAS 98-82-8)Aquatic EC50Crustacea 3.55 - 11.29 mg/l, 48 hoursBrine shrimp (Artemia sp.)LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)Diethanolamine (CAS 111-42-2)Aquatic EC50Crustacea 61.8 - 86.04 mg/l, 48 hoursWater flea (Ceriodaphnia dubia)LC50Fish 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)Ethylenediamine (CAS 107-15-3)Aquatic LC50Fish 98.6 - 131.6 mg/l, 96 hoursFathead minnow (Pimephales promelas)Methoxyethanol (CAS 109-86-4)Aquatic LC50Fish > 10000 mg/l, 96 hoursBluegill (Lepomis macrochirus)Morpholine (CAS 110-91-8)Aquatic LC50Fish > 1 mg/l, 96 hoursZebra danio (Danio rerio)Naphthalene (CAS 91-20-3)Aquatic EC50Crustacea 1.09 - 3.4 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 1.11 - 1.68 mg/l, 96 hoursPink salmon (Oncorhynchus gorbuscha)Oleic Acid (CAS 112-80-1)Aquatic LC50Fish 205 mg/l, 96 hoursFathead minnow (Pimephales promelas)Triethanolamine (CAS 102-71-6)Aquatic EC50Crustacea 565.2 - 658.3 mg/l, 48 hoursWater flea (Ceriodaphnia dubia)LC50Fish 10610 - 13010 mg/l, 96 hoursFathead minnow (Pimephales promelas)No data is available on the degradability of any ingredients in the mixture.Persistence and degradabilityBioaccumulative potentialPartition coefficient n-octanol / water (log Kow)1,4-diethylbenzene 4.45Benzene, 1,3-diethyl- 4.44Butoxyethanol 0.81 log Pow, at 25 ?CCumene 3.66Diethanolamine -1.43Ethylenediamine -2.04Methoxyethanol -0.77Morpholine -0.86Naphthalene 3.3Tert-butylbenzene 4.11Triethanolamine -1 11 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US No data available.Mobility in soilOther adverse effects The product contains volatile organic compounds which have a photochemical ozone creationpotential.13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).Waste from residues / unusedproducts Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers.Contaminated packaging14. Transport informationDOT UN1950UN number Aerosols, flammable, Limited Quantity, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for userIATA UN1950UN number Aerosols, Flammable, Limited Quantity, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for userIMDG UN1950UN number Aerosols, Flammable, Limited Quantity (Petroleum Distillates), Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group No.Marine pollutantEnvironmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for userPetroleum Distillates Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code 12 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US DOT; IMDGIATA15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Methoxyethanol (CAS 109-86-4) 1.0 % One-Time Export Notification only.Sodium Glucoheptonate (CAS 31138-65-5) 1.0 % One-Time Export Notification only.CERCLA Hazardous Substance List (40 CFR 302.4)Butoxyethanol (CAS 111-76-2) Listed.Cumene (CAS 98-82-8) Listed.Diethanolamine (CAS 111-42-2) Listed.Ethylenediamine (CAS 107-15-3) Listed.Methoxyethanol (CAS 109-86-4) Listed.Morpholine (CAS 110-91-8) Listed.Naphthalene (CAS 91-20-3) Listed.N-Ethylmorpholine (CAS 100-74-3) Listed.SARA 304 Emergency release notificationEthylenediamine (CAS 107-15-3) 5000 LBSOSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.SARA 302 Extremely hazardous substanceSuperfund Amendments and Reauthorization Act of 1986 (SARA)Chemical name CAS number Reportablequantity(pounds) Thresholdplanning quantity(pounds) Thresholdplanning quantity,lower value(pounds) Thresholdplanning quantity,upper value(pounds)Ethylenediamine 107-15-3 5000 10000YesSARA 311/312 Hazardouschemical Acute toxicity (any route of exposure)Skin corrosion or irritationGerm cell mutagenicityCarcinogenicityAspiration hazardClassified hazardcategoriesSARA 313 (TRI reporting)Chemical name % by wt.CAS numberButoxyethanol < 1111-76-2Naphthalene < 0.391-20-3 13 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListCumene (CAS 98-82-8)Diethanolamine (CAS 111-42-2)Methoxyethanol (CAS 109-86-4)Naphthalene (CAS 91-20-3)Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Ethylenediamine (CAS 107-15-3)Not regulated.Safe Drinking Water Act(SDWA)US state regulationsCalifornia Proposition 65California Proposition 65 - CRT: Listed date/Carcinogenic substanceCumene (CAS 98-82-8) Listed: April 6, 2010Diethanolamine (CAS 111-42-2) Listed: June 22, 2012Naphthalene (CAS 91-20-3) Listed: April 19, 2002California Proposition 65 - CRT: Listed date/Developmental toxinMethoxyethanol (CAS 109-86-4) Listed: January 1, 1989California Proposition 65 - CRT: Listed date/Male reproductive toxinMethoxyethanol (CAS 109-86-4) Listed: January 1, 1989US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,subd. (a))1,2,3-Trimethylbenzene (CAS 526-73-8)1,2,4-Trimethylbenzene (CAS 95-63-6)Butoxyethanol (CAS 111-76-2)Cumene (CAS 98-82-8)Diethanolamine (CAS 111-42-2)Ethylenediamine (CAS 107-15-3)Kerosene (CAS 8008-20-6)Methoxyethanol (CAS 109-86-4)Naphthalene (CAS 91-20-3)Petroleum Gases, Liquefied, Sweetened (CAS 68476-86-8)Tert-butylbenzene (CAS 98-06-6)International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).16. Other information, including date of preparation or last revision05-29-2015Issue date 011-17-2022Revision dateVersion # 07 14 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 07 Revision date: 11-17-2022 Issue date: 05-29-2015 SDS US Health: 3*Flammability: 0Physical hazard: 0HMIS? ratings Health: 2Flammability: 0Instability: 0NFPA ratingsNFPA ratings 02 0The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.Disclaimer Physical & Chemical Properties: Multiple PropertiesRevision information 15 / 15Material name: Gunk Engine Cleaner - FoamyFEB1, FEB1/6 Version #: 06 Revision date: 03-23-2020 Issue date: 05-29-2015 SDS US