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L112 11OZ LIQUID WRENCH PENETRATING OIL
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SAFETY DATA SHEET1. Identification Liquid Wrench Penetrating OilProduct identifierOther means of identification L112SDS number L106, L112, L112/4, L112/6, L103Part No. 3403.19.5000Tariff code Penetrating OilRecommended use None known.Recommended restrictionsManufacturer/Importer/Supplier/Distributor informationManufacturer2. Hazard(s) identification Category 2Flammable aerosolsPhysical hazards Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazardNot classified.Environmental hazards Not classified.OSHA defined hazardsLabel elementsSignal word DangerHazard statement Flammable aerosol. Harmful if swallowed. Contains gas under pressure; may explode if heated.Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Maycause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness.Toxic to aquatic life with long lasting effects.Precautionary statementPrevention Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an openflame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoidbreathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when usingthis product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must notbe allowed out of the workplace. Avoid release to the environment. Wear eye protection/faceprotection. 1 / 10Material name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 SDS USCompany nameAddressEmergency phone numberTelephoneWebsite Blaster LLC8500 Sweet Valley Drive Valley View, Ohio 44125 - USA T(216)901-5800F (216)901-5801www.blastercorp.comChemtrec (800) 424-9300 Response IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiouslywith water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. Rinse mouth. Do NOT induce vomiting. If on skin: Wash with plenty of water. IF INHALED:Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously withwater for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation or rash occurs: Getmedical advice/attention. If eye irritation persists: Get medical advice/attention. Take offcontaminated clothing and wash before reuse. Collect spillage.Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50?C/122?F.Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC) None known.Supplemental information 95.05% of the mixture consists of component(s) of unknown acute inhalation toxicity. 97.85% ofthe mixture consists of component(s) of unknown acute hazards to the aquatic environment.97.85% of the mixture consists of component(s) of unknown long-term hazards to the aquaticenvironment.NOTE: This product is a consumer product and is labeled in accordance with the US ConsumerProduct Safety Commission regulations which take precedence over OSHA HazardCommunication labeling. The container label may not include the OSHA label elements listed inthis document. Always carefully review the entire SDS and the product label prior to use in theworkplace.3. Composition/information on ingredientsMixtures CAS number %Chemical name Common name and synonyms 64742-53-6Hydrotreated Light NaphthenicDistillates Petroleum 80 - < 9025498-49-1Tripropylene Glycol MonomethylEther 5 - < 10124-38-9Carbon Dioxide 1 - < 357675-44-2Trimethylolpropane Trioleate 1 - < 39002-84-0Polytetrafluoroethylene (PTFE) < 0.21 - < 3Other components below reportable levels 10043-11-5Boron Nitride < 0.1*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poisoncenter or doctor/physician if you feel unwell.Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Getmedical advice/attention. Wash contaminated clothing before reuse.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.Ingestion Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Most importantsymptoms/effects, acute anddelayed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victimunder observation. Symptoms may be delayed.Indication of immediatemedical attention and specialtreatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.General information5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia 2 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 Contents under pressure. Pressurized container may explode when exposed to heat or flame.During fire, gases hazardous to health may be formed.Specific hazards arising fromthe chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipmentand precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled withwater to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hoseholder or monitor nozzles, if possible. If not, withdraw and let fire burn out.Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainers from fire area if you can do so without risk. In the event of fire and/or explosion do notbreathe fumes.Specific methods Flammable aerosol. Contents under pressure. Pressurized container may explode when exposedto heat or flame.General fire hazards6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapor. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Local authorities should be advised if significantspillages cannot be contained. For personal protection, see section 8 of the SDS.Personal precautions,protective equipment andemergency procedures Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so withoutrisk. Move the cylinder to a safe and open area if the leak is irreparable. Eliminate all ignitionsources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood,paper, oil, etc.) away from spilled material. Prevent entry into waterways, sewer, basements orconfined areas. Absorb in vermiculite, dry sand or earth and place into containers. Followingproduct recovery, flush area with water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. For waste disposal, see section 13 of the SDS.Methods and materials forcontainment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missingor defective. Do not spray on a naked flame or any other incandescent material. Do not smokewhile using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, orexpose containers to heat, flame, sparks, or other sources of ignition. All equipment used whenhandling the product must be grounded. Do not re-use empty containers. Do not taste or swallow.Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat,drink or smoke. Use only in well-ventilated areas. Wear appropriate personal protectiveequipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.Precautions for safe handling Level 3 Aerosol.Store locked up. Pressurized container. Protect from sunlight and do not expose to temperaturesexceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an openflame, heat or other sources of ignition. This material can accumulate static charge which maycause spark and become an ignition source. Store in tightly closed container. Store away fromincompatible materials (see Section 10 of the SDS).Conditions for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limitsThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) FormValueComponents TypePEL 9000 mg/m3Carbon Dioxide (CAS124-38-9) 5000 ppmPEL 5 mg/m3 Mist.Hydrotreated LightNaphthenic DistillatesPetroleum (CAS64742-53-6) 2000 mg/m3500 ppm 3 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 US. ACGIH Threshold Limit Values FormValueComponents TypeSTEL 30000 ppmCarbon Dioxide (CAS124-38-9) TWA 5000 ppmTWA 5 mg/m3 Inhalable fraction.Hydrotreated LightNaphthenic DistillatesPetroleum (CAS64742-53-6)US. NIOSH: Pocket Guide to Chemical Hazards FormValueComponents TypeSTEL 54000 mg/m3Carbon Dioxide (CAS124-38-9) 30000 ppmTWA 9000 mg/m35000 ppmCeiling 1800 mg/m3Hydrotreated LightNaphthenic DistillatesPetroleum (CAS64742-53-6) STEL 10 mg/m3 Mist.No biological exposure limits noted for the ingredient(s).Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station and safety shower.Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipmentFace shield is recommended. Wear safety glasses with side shields (or goggles).Eye/face protectionSkin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing.Other If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or anair-supplied respirator. Chemical respirator with organic vapor cartridge and full facepiece ifthreshold limits are exceeded. Dust & vapor respirator.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personalhygiene measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.General hygieneconsiderations9. Physical and chemical propertiesLiquid OpaqueAppearance Liquid.Physical state Aerosol.Form YellowColor FragranceOdorOdor threshold Not available.pH Not available.Melting point/freezing point Not available.Initial boiling point and boilingrange 446 ?F (230 ?C) estimatedFlash point 200.0 ?F (93.3 ?C) Tag Closed CupEvaporation rate Not available.Not applicable.Flammability (solid, gas) 4 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 Upper/lower flammability or explosive limitsFlammability limit - lower(%) Not available.Flammability limit - upper(%) Not available.Explosive limit - lower (%) Not available.Explosive limit - upper (%) Not available.Vapor pressure 0.0923 hPa estimatedVapor density Not available.Relative density Not available.Solubility(ies)Solubility (water) Not available.Partition coefficient(n-octanol/water) Not available.Auto-ignition temperature Not available.Decomposition temperature Not available.Viscosity Not available.Other informationDensity 7.26 lbs/galNot explosive.Explosive propertiesFlame extension > 18 inFlammability (flash back) NoFlammability class Combustible IIIB estimatedHeat of combustion (NFPA30B) 36.35 kJ/gNot oxidizing.Oxidizing propertiesPercent volatile 0.29 % estimatedSpecific gravity 0.87VOC 0 %10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardousreactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoidtemperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may beharmful.Skin contact Causes skin irritation.Eye contact Causes serious eye irritation.Ingestion Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion orvomiting may cause a serious chemical pneumonia.Symptoms related to thephysical, chemical andtoxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Information on toxicological effects 5 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 Acute toxicity May be fatal if swallowed and enters airways. Test ResultsComponents SpeciesHydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6)DermalAcuteLD50 Rabbit > 2000 mg/kg, 24 HoursInhalationLC50 Rat > 3.9 mg/l, 4 HoursOralLD50 Rat > 2000 mg/kgTrimethylolpropane Trioleate (CAS 57675-44-2)DermalAcuteLD50 Rabbit > 2000 mg/kg, 24 HoursOralLD50 Rat > 2000 mg/kgTripropylene Glycol Monomethyl Ether (CAS 25498-49-1)DermalAcuteLD50 Rabbit 15440 mg/kg, 24 HoursOralLD50 Rat 3400 mg/kgCauses skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicityCarcinogenicity Not classifiable as to carcinogenicity to humans.IARC Monographs. Overall Evaluation of CarcinogenicityPolytetrafluoroethylene (PTFE) (CAS 9002-84-0) 3 Not classifiable as to carcinogenicity to humans.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.US. National Toxicology Program (NTP) Report on CarcinogensHydrotreated Light Naphthenic Distillates Petroleum(CAS 64742-53-6) Known To Be Human Carcinogen.This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure May cause drowsiness and dizziness.Specific target organ toxicity -repeated exposure Not classified.Aspiration hazard May be fatal if swallowed and enters airways.Chronic effects Prolonged inhalation may be harmful.12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.Ecotoxicity No data is available on the degradability of any ingredients in the mixture.Persistence and degradabilityBioaccumulative potentialPartition coefficient n-octanol / water (log Kow)Trimethylolpropane Trioleate 24.73, at 22 C 6 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 No data available.Mobility in soilOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordancewith local/regional/national/international regulations.Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).Waste from residues / unusedproducts Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers.Contaminated packaging14. Transport informationDOT UN1950UN number Aerosols, flammable, (each not exceeding 1 L capacity), Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk 2.1Label(s) Not available.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulkIATA UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesEnvironmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargoaircraftOther information Allowed with restrictions.Cargo aircraft onlyIMDG UN1950UN number Aerosols, flammable, MARINE POLLUTANT (Petroleum Distillates), Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesMarine pollutantEnvironmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for userPetroleum Distillates 7 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC CodeDOT; IMDGIATAMarine pollutant IMDG Regulated Marine Pollutant.General information15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.TSCA Chemical Action Plans, Chemicals of ConcernPolytetrafluoroethylene (PTFE) (CAS 9002-84-0) Long-Chain Perfluorinated Chemicals (PFCs) Action PlanCERCLA Hazardous Substance List (40 CFR 302.4)Not listed.SARA 304 Emergency release notificationNot regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.SARA 302 Extremely hazardous substanceSuperfund Amendments and Reauthorization Act of 1986 (SARA)Not listed. YesSARA 311/312 Hazardouschemical 8 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 Flammable (gases, aerosols, liquids, or solids)Acute toxicity (any route of exposure)Skin corrosion or irritationSerious eye damage or eye irritationSpecific target organ toxicity (single or repeated exposure)Aspiration hazardClassified hazardcategoriesSARA 313 (TRI reporting)Not regulated.Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated. Not regulated.Safe Drinking Water Act(SDWA)US state regulationsCalifornia Proposition 65US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,subd. (a))Hydrotreated Light Naphthenic Distillates Petroleum (CAS 64742-53-6)International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS) NoTaiwan Taiwan Chemical Substance Inventory (TCSI) NoUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).16. Other information, including date of preparation or last revision04-27-2015Issue dateRevision dateVersion #HMIS? ratings 11-7-202217Health: 2 Flammability: 1 Physical hazard: 0Health: 2 Flammability: 1 Instability: 0NFPA ratingsNFPA ratings 02 1 9 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.Disclaimer Hazard(s) identification: Supplemental informationPhysical & Chemical Properties: Multiple PropertiesRevision information 10 / 10SDS USMaterial name: Liquid Wrench Penetrating OilL106, L112, L112/4, L112/6, L103 Version #: 17 Revision date: 11-7-2022 Issue date: 04-27-2015