SECTION 1: Identification SECTION 2: Hazards identification ? 2.1 Classification of the substance or mixture ? Classification according to Regulation (EC) No 1272/2008 Classifications listed are applicable to the OSHA GHS Hazard Communication Standard (29CFR1910.1200). The following Hazard Statements are applicable only according to OSHA regulations within the United States. These Statements are not applicable for the CLP regulation (1272/2008/EC) in the EU: H317. Met. Corr.1 H290 May be corrosive to metals. Skin Corr. 1C H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. ? 2.2 Label elements ? Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the Globally Harmonized System within the United States. The product is classified and labelled according to the CLP regulation. ? Hazard pictograms GHS05 GHS07 ? Signal word Danger ? Hazard-determining components of labelling: disodium metasilicate pentahydrate (Cont'd. on page 2) 46.0. 4 SAFETY DATA SHEET GUNK Swab Concrete & Asphalt CleanerProduct identifier Other means of identification Part No. Tariff code SW4 / SW5 3405.40.0000 Concrete Cleaner None known. Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Address Emergency phone number Telephone Website E-mail Printing date: 18 December 2019 Revision: 27 March 2023 Blaster LLC 8500 Sweet Valley Drive Valley View, Ohio 44125 - USA T(216)901-5800 F (216)901-5801www.blastercorp.com Chemtrec (800) 424-9300 Page: 2/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 1) ? Hazard statements The following Hazard Statements are applicable only according to OSHA regulations within the United States. These Statements are not applicable for the CLP regulation (1272/2008/EC) in the EU: H317. H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. ? Precautionary statements The following Precautionary Statements are applicable only to the OSHA GHS regulations and not the EU CLP regulations: P272, P333+P313. P234 Keep only in original container. P260 Do not breathe mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P390 Absorb spillage to prevent material damage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ? NFPA ratings (scale 0 - 4) Health = 3 Fire = 0 Reactivity = 0 ? HMIS-ratings (scale 0 - 4) HEALTH 3 Health = 3 FIRE 0 Fire = 0 REACTIVITY 0 Reactivity = 0 ? 2.3 Other hazards There are no other hazards not otherwise classified that have been identified. ? Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. SECTION 3: Composition/information on ingredients (Cont'd. on page 3) 46.0.4 Pinus pumilio oil 0 3 0 SAFETY DATA SHEET Page: 3/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 2) ? 3.2 Mixtures ? Components: CAS: 10213-79-3 disodium metasilicate pentahydrate >75% EINECS: 229-912-9 Met. Corr.1, H290; Skin Corr. 1B, H314; Eye Dam. 1, H318 STOT SE 3, H335 CAS: 497-19-8 sodium carbonate 10-20% EINECS: 207-838-8 Eye Irrit. 2, H319 Index number: 011-005-00-2 Reg.nr.: 01-2119485498-19-XXXX CAS: 8000-26-8 Pinus pumilio oil <1% EINECS: 290-165-7 Flam. Liq. 3, H226 Reg.nr.: 01-2120110812-70-XXXX Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 ? Additional information: For the wording of the listed Hazard Statements refer to section 16. SECTION 4: First aid measures ? 4.1 Description of first aid measures ? After inhalation: Supply fresh air; consult doctor in case of complaints. ? After skin contact: Brush off loose particles from skin. Immediately remove any clothing soiled by the product. Immediately rinse with water. If skin irritation continues, consult a doctor. Seek immediate medical help for blistering or open wounds. ? After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. Then consult a doctor. ? After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. Coughing Gastric or intestinal disorders when ingested. Nausea in case of ingestion. Caustic effect on skin and mucous membranes. Allergic reactions ? Hazards: Causes serious eye damage. Danger of gastric perforation. If medical advice is needed, have product container or label at hand. (Cont'd. on page 4) 46.0.4 ? 4.2 Most important symptoms and effects, both acute and delayed ? 4.3 Indication of any immediate medical attention and special treatment needed SAFETY DATA SHEET Page: 4/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 3) SECTION 5: Firefighting measures ? 5.1 Extinguishing media ? Suitable extinguishing agents: The product is not flammable. Use fire extinguishing methods suitable to surrounding conditions. ? For safety reasons unsuitable extinguishing agents: None. Formation of toxic gases is possible during heating or in case of fire. ? Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. SECTION 6: Accidental release measures ? 6.1 Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Product forms slippery surface when combined with water. ? 6.3 Methods and material for containment and cleaning up Pick up mechanically. Send for recovery or disposal in suitable receptacles. Clean the affected area carefully; suitable cleaners are: Warm water See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage ? 7.1 Precautions for safe handling Prevent formation of dust. Any unavoidable deposit of dust must be regularly removed. Avoid contact with the eyes and skin. Avoid breathing dust. Open and handle receptacle with care. Keep out of reach of children. ? Information about fire - and explosion protection: No special measures required. ? 7.2 Conditions for safe storage, including any incompatibilities ? Requirements to be met by storerooms and receptacles: Protect from humidity and water. ? Information about storage in one common storage facility: Store away from foodstuffs. (Cont'd. on page 5) 46.0. 4 ? 5.2 Special hazards arising from the substance or mixture ? 5.3 Advice for firefighters ? 6.2 Environmental precautions Avoid release to the environment. ? 6.4 Reference to other sections SAFETY DATA SHEET Page: 5/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 4) ? Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. This product is hygroscopic. SECTION 8: Exposure controls/personal protection ? 8.1 Control parameters ? Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. ? DNELs: No further relevant information available. ? PNECs: No further relevant information available. ? 8.2 Exposure controls ? General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Avoid breathing dust. ? Respiratory protection: For spills, respiratory protection may be advisable. Use suitable respiratory protective device when high concentrations are present. ? Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. ? Eye protection: Safety glasses Follow relevant national guidelines concerning the use of protective eyewear. ? Body protection: Alkaline resistant protective clothing ? Limitation and supervision of exposure into the environment: No further relevant information available. ? Risk management measures: No further relevant information available. SECTION 9: Physical and chemical properties ? 9.1 Information on basic physical and chemical properties ? Appearance (Cont'd. on page 6) 46.0.4 Do not store together with oxidising and acidic materials. ? 7.3 Specific end use(s) No further relevant information available. SAFETY DATA SHEET Page: 6/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 5) Form: Powder Colour: Yellow ? Odour: Turpentine-like ? Odour threshold: Not determined. ? pH-value at 20 ?C (68 ?F): 11,5 - 12,5 ? Melting point/freezing point: Not determined. ? Initial boiling point and boiling range: Not determined. ? Flash point: Not applicable. ? Flammability (solid, gas): Not determined. ? Auto/Self-ignition temperature: Not determined. ? Decomposition temperature: Not determined. ? Explosive properties: Product does not present an explosion hazard. ? Explosion limits Lower: Not determined. Upper: Not determined. ? Oxidising properties Non-oxidising. ? Vapour pressure: Not applicable. ? Density: Relative density: 0.9-1.2 Vapour density: Not applicable. Evaporation rate: Not applicable. ? Solubility in / Miscibility with water: Soluble. ? Partition coefficient: n-octanol/water: Not determined. ? Viscosity Dynamic: Not applicable. Kinematic: Not applicable. SECTION 10: Stability and reactivity ? 10.1 Reactivity No further relevant information available. ? 10.2 Chemical stability ? Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. Reacts with strong acids and oxidising agents. Toxic fumes may be released if heated above the decomposition point. ? 10.5 Incompatible materials Strong acids. (Cont'd. on page 7) 46.0. 4 ? 9.2 Other information No further relevant information available. ? 10.3 Possibility of hazardous reactions ? 10.4 Conditions to avoid Moisture. SAFETY DATA SHEET Page: 7/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 6) SECTION 11: Toxicological information ? 11.1 Information on toxicological effects ? Acute toxicity: Based on available data, the classification criteria are not met. ? LD/LC50 values relevant for classification: None. ? Primary irritant effect ? Skin corrosion/irritation: Causes severe skin burns and eye damage. ? Serious eye damage/irritation: Causes serious eye damage. ? Respiratory or skin sensitisation: May cause an allergic skin reaction. ? Carcinogenic categories ? IARC (International Agency for Research on Cancer): None of the ingredients are listed. ? NTP (National Toxicology Program): None of the ingredients are listed. ? OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed. ? Probable routes of exposure: Skin contact. Eye contact. Inhalation. Ingestion. ? Repeated dose toxicity: Sensitising effect by skin contact is possible by prolonged exposure. ? Germ cell mutagenicity: Based on available data, the classification criteria are not met. ? Carcinogenicity: Based on available data, the classification criteria are not met. ? Reproductive toxicity: Based on available data, the classification criteria are not met. ? STOT-single exposure: May cause respiratory irritation. ? STOT-repeated exposure: Based on available data, the classification criteria are not met. ? Aspiration hazard: Based on available data, the classification criteria are not met. SECTION 12: Ecological information ? 12.1 Toxicity ? Aquatic toxicity: No further relevant information available. ? 12.3 Bioaccumulative potential No further relevant information available. ? 12.4 Mobility in soil No further relevant information available. ? Ecotoxical effects: ? Remark: After neutralisation a reduction of the harming action may be recognised. (Cont'd. on page 8) 46.0.4 ? 10.6 Hazardous decomposition products Carbon monoxide and carbon dioxide ? 12.2 Persistence and degradability No further relevant information available. SAFETY DATA SHEET Page: 8/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 7) ? General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. If the dilution of the use-level pH-value is considerably reduced, the aqueous waste, emptied into drains, is only low water-dangerous. ? PBT: Not applicable. ? vPvB: Not applicable. SECTION 13: Disposal considerations ? 13.1 Waste treatment methods ? Recommendation Small amounts may be diluted with plenty of water and washed away. Dispose of larger amounts in accordance with Local Authority requirements. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. ? Uncleaned packaging: ? Recommendation: Disposal must be made according to official regulations. ? Recommended cleansing agents: Water only. SECTION 14: Transport information ? 14.1 UN-Number ? DOT, ADR, IMDG, IATA UN3253 ? 14.2 UN proper shipping name ? DOT, IATA Disodium trioxosilicate ? ADR, IMDG DISODIUM TRIOXOSILICATE ? 14.3 Transport hazard class(es) ? DOT ? Class 8 Corrosive substances. ? Label 8 (Cont'd. on page 9) 46.0.4 ? Additional ecological information: ? 12.5 Results of PBT and vPvB assessment ? 12.6 Other adverse effects No further relevant information available. SAFETY DATA SHEET Page: 9/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 8) ? ADR ? Class 8 (C6) Corrosive substances. ? Label 8 ? IMDG, IATA ? Class 8 Corrosive substances. ? Label 8 ? 14.4 Packing group ? DOT, ADR, IMDG, IATA III ? 14.5 Environmental hazards: ? Marine pollutant: No ? 14.6 Special precautions for user Warning: Corrosive substances. ? Danger code (Kemler): 80 ? EMS Number: F-A,S-B ? Segregation groups Alkalis ? 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. ? Transport/Additional information: ? DOT Limited Quantity for packages less than 30 kg gross and inner packagings less than 5 kg each. ? ADR Limited Quantity for packages less than 30 kg gross and inner packagings less than 5 kg each. ? IMDG Limited Quantity for packages less than 30 kg gross and inner packagings less than 5 kg each. ? IATA (Cont'd. on page 10) 46.0. 4 SAFETY DATA SHEET Page: 10/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 9) Limited Quantity for packages less than 30 kg gross and inner packagings less than 1 kg each / 5 kg net. SECTION 15: Regulatory information ? 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture ? United States (USA) ? SARA ? Section 355 (extremely hazardous substances): None of the ingredients are listed. ? Section 313 (Specific toxic chemical listings): None of the ingredients are listed. ? TSCA (Toxic Substances Control Act): All ingredients are listed. ? Proposition 65 (California): ? Chemicals known to cause cancer: 125-35-3 | Beta-myrcene. (. 7-Methyl-3-methyleneocta-1, 6-diene) ? Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. ? Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. ? Chemicals known to cause developmental toxicity: None of the ingredients are listed. ? EPA (Environmental Protection Agency) None of the ingredients are listed. ? IARC (International Agency for Research on Cancer) None of the ingredients are listed. ? NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed. ? Canadian Domestic Substances List (DSL) All ingredients are listed. ? Other regulations, limitations and prohibitive regulations ? Substances of very high concern (SVHC) according to REACH, Article 57 None of the ingredients are listed. ? 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. (Cont'd. on page 11) 46.0. 4 SAFETY DATA SHEET Page: 11/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 10) SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ? Relevant phrases H226 Flammable liquid and vapour. H290 May be corrosive to metals. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. ? Abbreviations and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistant, Bio-accumulable, Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids ? Category 3 Met. Corr.1: Corrosive to metals ? Category 1 Skin Corr. 1B: Skin corrosion/irritation ? Category 1B Skin Corr. 1C: Skin corrosion/irritation ? Category 1C Skin Irrit. 2: Skin corrosion/irritation ? Category 2 Eye Dam. 1: Serious eye damage/eye irritation ? Category 1 Eye Irrit. 2: Serious eye damage/eye irritation ? Category 2 Skin Sens. 1: Skin sensitisation ? Category 1 STOT SE 3: Specific target organ toxicity (single exposure) ? Category 3 Asp. Tox. 1: Aspiration hazard ? Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard ? Category 2 Website, European Chemicals Agency (echa.europa.eu) Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/ overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org) Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: 978-0-470-07488-6 Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: 978-0-07-176923-5. Safety Data Sheets, Individual Manufacturers SDS Prepared by: (Cont'd. on page 12) 46.0. 4 ? Sources SAFETY DATA SHEET Page: 12/12 Printing date: 18 December 2019 Revision: 27 March 2023 Trade name: SWAB Powder Concrete Cleaner v.7 (Cont'd. from page 11) ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com SAFETY DATA SHEET 46.0.4