SAFETY DATA SHEET Revision Date 06-May-2020 Version 1 1. IDENTIFICATION Product identifier Product Name Rain-X Glass Water Repellent Aerosol Other means of identification Product Code 620255 Document 630168; 630168W Recommended use of the chemical and restrictions on use Recommended Use Aerosol Water repellent Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-855-888-1988 24-hour emergency phone number (CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.) (RMPDC) 1-877-504-9352 (U.S.) E-mail address: This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 1B Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Supplier Address ITW Global Brands 16200 Park Row, Suite 120 Houston, TX 77084 Manufacturer Address Manufactured and Distributed by: Distributor May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable aerosols Category 1 Gases under pressure Compressed gas Signal word Danger Causes serious eye irritation May cause genetic defects May cause respiratory irritation May cause drowsiness or dizziness Extremely flammable aerosol _____________________________________________________________________________________________ Page 1 / 8 Contains gas under pressure; may explode if heated _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Harmful to aquatic life. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Isopropanol 67-63-0 40 - 70 Acetone 67-64-1 10 - 30 Liquefied Petroleum Gas 68476-86-8 7 - 13 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Appearance Clear Concentrate Physical state Extremely flammable aerosol Odor No information available _____________________________________________________________________________________________ Page 2 / 8 _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Use dry chemical, Foam Unsuitable extinguishing media None Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use personal protective equipment as required. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE _____________________________________________________________________________________________ Page 3 / 8 _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Isopropanol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Acetone 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors. (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical state Extremely flammable aerosol Appearance Clear Concentrate Odor No information available _____________________________________________________________________________________________ Page 4 / 8 _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Color Colorless Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC content <75 Density No information available Bulk density No information available SADT (self-accelerating decomposition temperature) No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range No information available Flash point -104 ?C / -155 ?F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Relative density No information available Water solubility No information available Solubility(ies) No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available No information available _____________________________________________________________________________________________ Page 5 / 8 _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Isopropanol 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h Acetone 67-64-1 = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Isopropanol 67-63-0 - Group 3 - X IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 16906 mg/kg ATEmix (dermal) 5735 mg/kg ATEmix (inhalation-dust/mist) 397.6 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 0.117 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient Isopropanol 67-63-0 0.05 Acetone 67-64-1 -0.24 Liquefied Petroleum Gas 68476-86-8 <=2.8 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 6 / 8 _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number No information available This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Isopropanol 67-63-0 Toxic Ignitable Acetone 67-64-1 Ignitable 14. TRANSPORT INFORMATION DOT UN/ID No UN 1950 Proper shipping name Aerosols, Flammable, Limited Quantity (LQ) Hazard Class 2.1 IATA Proper shipping name Do Not Ship By Air IMDG UN/ID No UN 1950 Proper shipping name Aerosols, Flammable, Limited Quantity (LQ) Hazard Class 2.1 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Complies KECL Does not comply PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations _____________________________________________________________________________________________ Page 7 / 8 SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 _____________________________________________________________________________________________ 620255 - Rain-X Glass Water Repellent Aerosol Revision Date 06-May-2020 Chemical Name SARA 313 - Threshold Values % Isopropanol - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Acetone 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Isopropanol 67-63-0 X X X Acetone 67-64-1 X X X Methanol 67-56-1 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 06-May-2020 Disclaimer Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled. However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness of the information. User is responsible for evaluating whether such information or this product is fit for a particular purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc. disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web site. End of Safety Data Sheet NFPA Health hazards 2 Instability 0 - HMIS Health hazards 2 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 8 / 8