Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 1/12 SAFETY DATA SHEET 1. Identification Product identifier: RAIN X AUTOMOTIVE GLASS CLEANER Other means of identification SKU number: 630016;630175;630175W Recommended restrictions Product Use: Cleaner Restrictions on use: Not known. Manufacturer/Importer/Distributor Information Manufacturer Company Name: ITW GLOBAL BRANDS Address: 16200 PARK ROW DRIVE, SUITE 120 HOUSTON,TX 77084 Telephone: 1-713-797-2180 Fax: Emergency telephone number: 1-866-836-8855 2. Hazard(s) identification Hazard Classification Physical Hazards Gases under pressure Compressed gas Hazard Symbol: Signal Word: Warning Hazard Statement: Contains gas under pressure; may explode if heated. Precautionary Statements Storage: Protect from sunlight. Store in a well-ventilated place. Hazard(s) not otherwise classified (HNOC): None. Label Elements Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 2/12 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* Ethanol 64-17-5 1 - <5% Propane 74-98-6 1 - <5% Butane 106-97-8 1 - <5% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Rinse mouth thoroughly. Inhalation: Move to fresh air. Skin Contact: Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Eye contact: Rinse immediately with plenty of water. Most important symptoms/effects, acute and delayed Symptoms: No data available. Hazards: No data available. Indication of immediate medical attention and special treatment needed Treatment: No data available. 5. Fire-fighting measures General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a protected location. Move containers from fire area if you can do so without risk. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical: Vapors may travel considerable distance to a source of ignition and flash back. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available. Special protective equipment for fire-fighters: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 3/12 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Ventilate closed spaces before entering them. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep upwind. Methods and material for containment and cleaning up: Stop the flow of material, if this is without risk. Absorb with sand or other inert absorbent. Notification Procedures: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Conditions for safe storage, including any incompatibilities: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Aerosol Level 1 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Source Ethanol REL 1,000 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 1,000 ppm 1,900 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 1,000 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 1,000 ppm US. ACGIH Threshold Limit Values (2009) Propane REL 1,000 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Butane REL 800 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) STEL 1,000 ppm US. ACGIH Threshold Limit Values (03 2018) TWA 800 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Ethanol, 2-butoxy- TWA 20 ppm US. ACGIH Threshold Limit Values (2008) REL 5 ppm 24 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 50 ppm 240 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 25 ppm 120 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Ethanol, 2-amino- STEL 6 ppm 15 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 3 ppm 6 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) STEL 6 ppm 15 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) REL 3 ppm 8 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 3 ppm 8 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 6 ppm US. ACGIH Threshold Limit Values (2008) TWA 3 ppm US. ACGIH Threshold Limit Values (2008) 2-Propanol, 2-methyl- STEL 150 ppm 450 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 100 ppm 300 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 4/12 PEL 100 ppm 300 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 100 ppm US. ACGIH Threshold Limit Values (2008) STEL 150 ppm 450 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) REL 100 ppm 300 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) Ethanol, 2,2'-iminobis- REL 3 ppm 15 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 3 ppm 15 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Ethanol, 2,2'-iminobis- - Inhalable fraction and vapor. TWA 1 mg/m3 US. ACGIH Threshold Limit Values (2009) Ethylene Oxide Ceil_Time 5 ppm 9 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 1 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) STEL 5 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) OSHA_AC T 0.5 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) REL 0.1 ppm 0.18 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 1 ppm US. ACGIH Threshold Limit Values (2008) TWA 1 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 5 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) 1,4-Dioxane TWA 25 ppm 90 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Ceil_Time 1 ppm 3.6 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 20 ppm US. ACGIH Threshold Limit Values (2008) PEL 100 ppm 360 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Acetic acid STEL 15 ppm 37 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 10 ppm 25 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 10 ppm 25 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) REL 10 ppm 25 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 10 ppm US. ACGIH Threshold Limit Values (2008) STEL 15 ppm US. ACGIH Threshold Limit Values (2008) Biological Limit Values Chemical Identity Exposure Limit Values Source Ethanol, 2-butoxy- (Butoxyacetic acid (BAA), with hydrolysis: Sampling time: End of shift.) 200 mg/g (Creatinine in urine) ACGIH BEL (03 2013) Ethylene Oxide (S-(2-hydroxyethyl) mercapturic acid (HEMA): Sampling time: End of shift.) 5 ?g/g (Creatinine in urine) ACGIH BEL (03 2018) Ethylene Oxide (N-(2-hydroxyethyl)-valine (HEV) hemoglobin adducts: Sampling time: Not critical.) 5000 pmol/g (Hemoglobin adducts) ACGIH BEL (03 2018) Appropriate Engineering Controls No data available. Individual protection measures, such as personal protective equipment General information: Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection: Wear goggles/face shield. Skin Protection Hand Protection: No data available. Other: No data available. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Hygiene measures: When using do not smoke. Observe good industrial hygiene practices. Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 5/12 9. Physical and chemical properties Appearance Physical state: liquid Form: Spray Aerosol Color: No data available. Odor: No data available. Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available. Initial boiling point and boiling range: No data available. Flash Point: Not applicable Evaporation rate: No data available. Flammability (solid, gas): Non-flammable Aerosol Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): No data available. Flammability limit - lower (%): No data available. Explosive limit - upper (%): No data available. Explosive limit - lower (%): No data available. Vapor pressure: 517 - 654 hPa (20 ?C) 1,103 - 1,241 hPa (50 ?C) Vapor density: No data available. Density: No data available. Relative density: No data available. Solubility(ies) Solubility in water: No data available. Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity: No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of hazardous reactions: No data available. Conditions to avoid: Avoid heat or contamination. Incompatible Materials: No data available. Hazardous Decomposition Products: No data available. 11. Toxicological information Information on likely routes of exposure Inhalation: No data available. Skin Contact: No data available. VOC: 8.0 Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 6/12 Eye contact: No data available. Ingestion: No data available. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: No data available. Skin Contact: No data available. Eye contact: No data available. Ingestion: No data available. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: Not classified for acute toxicity based on available data. Specified substance(s): Ethanol LD 50 (Rat): 10,470 mg/kg Dermal Product: Not classified for acute toxicity based on available data. Specified substance(s): Ethanol LD 50 (Rabbit): 17,100 mg/kg Inhalation Product: Not classified for acute toxicity based on available data. Specified substance(s): Ethanol LC 50 (Rat): 124.7 mg/l LC 50: > 5 mg/l Propane LC 50: > 100 mg/l LC 50: > 100 mg/l Butane LC 50: > 100 mg/l LC 50: > 100 mg/l Repeated dose toxicity Product: No data available. Specified substance(s): Ethanol NOAEL (Rat(Male), Oral, 7 - 14 Weeks): 10 %(m) Oral Experimental result, Key study Propane NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation Experimental result, Key study LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation Experimental result, Key study Butane LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation Experimental result, Key study NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation Experimental result, Key study Skin Corrosion/Irritation Product: No data available. Specified substance(s): Ethanol in vivo (Rabbit): Not irritant Experimental result, Key study Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 7/12 Serious Eye Damage/Eye Irritation Product: No data available. Specified substance(s): Ethanol Rabbit, 1 - 24 hrs: Not irritating Respiratory or Skin Sensitization Product: No data available. Specified substance(s): Ethanol Skin sensitization:, in vivo (Guinea pig): Non sensitising Carcinogenicity Product: No data available. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: No data available. Specific Target Organ Toxicity - Single Exposure Product: No data available. Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Aspiration Hazard Product: No data available. Other effects: No data available. 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Ethanol LC 50 (Pimephales promelas, 96 h): 15.3 g/l Experimental result, Key study Propane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study Butane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 8/12 Aquatic Invertebrates Product: No data available. Specified substance(s): Ethanol LC 50 (Ceriodaphnia dubia, 48 h): 5,012 mg/l Experimental result, Key study Butane LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key study Chronic hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Ethanol NOAEL (Oryzias latipes): 7,900 mg/l Read-across from supporting substance (structural analogue or surrogate), Supporting study Aquatic Invertebrates Product: No data available. Specified substance(s): Ethanol LC 50 (Daphnia magna): 454 mg/l Experimental result, Key study NOAEL (Daphnia magna): 9.6 mg/l Experimental result, Key study Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: No data available. Specified substance(s): Ethanol 95 % Detected in water. Experimental result, Key study Propane 100 % (385.5 h) Detected in water. Experimental result, Key study 50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study Butane 100 % (385.5 h) Detected in water. Experimental result, Key study BOD/COD Ratio Product: No data available. Bioaccumulative potential Bioconcentration Factor (BCF) Product: No data available. Specified substance(s): Ethanol Cyprinus carpio, Bioconcentration Factor (BCF): 4.5 Aquatic sediment Read- across from supporting substance (structural analogue or surrogate), Supporting study Partition Coefficient n-octanol / water (log Kow) Product: No data available. Mobility in soil: No data available. Known or predicted distribution to environmental compartments Ethanol No data available. Propane No data available. Butane No data available. Other adverse effects: No data available. Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 9/12 13. Disposal considerations Disposal instructions: Wash before disposal. Dispose to controlled facilities. Contaminated Packaging: No data available. 14. Transport information DOT UN Number: UN 1950 UN Proper Shipping Name: Aerosols, non-flammable Transport Hazard Class(es) Class: 2.2 Label(s): ? Packing Group: II Marine Pollutant: No Environmental Hazards: No Marine Pollutant No Special precautions for user: Not regulated. IMDG UN Number: UN 1950 UN Proper Shipping Name: Aerosols, non-flammable Transport Hazard Class(es) Class: 2 Label(s): ? EmS No.: Packing Group: ? Environmental Hazards: No Marine Pollutant No Special precautions for user: Not regulated. IATA UN Number: UN 1950 Proper Shipping Name: Aerosols, non-flammable Transport Hazard Class(es): Class: 2.2 Label(s): ? Packing Group: ? Environmental Hazards: No Marine Pollutant No Special precautions for user: Not regulated. Cargo aircraft only: Allowed. 15. Regulatory information US Federal Regulations Restrictions on use: Not known. Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 10/12 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Chemical Identity OSHA hazard(s) Ethylene Oxide Eye irritation respiratory tract irritation Skin irritation Skin sensitization Acute toxicity Cancer Central nervous system Reproductive toxicity Mutagenicity Flammability CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Reportable quantity Ethanol lbs. 100 Propane lbs. 100 Butane lbs. 100 2-Propanol, 2-methyl- lbs. 100 Ethanol, 2,2'-iminobis- lbs. 100 Ethylene Oxide lbs. 10 1,4-Dioxane lbs. 100 Acetic acid lbs. 5000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Not listed. SARA 302 Extremely Hazardous Substance Chemical Identity Reportable quantity Threshold Planning Quantity Ethylene Oxide lbs. 10 lbs. 1000 SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Ethanol lbs. 100 Propane lbs. 100 Butane lbs. 100 Ethanol, 2-butoxy- 2-Propanol, 2-methyl- lbs. 100 Ethanol, 2,2'-iminobis- lbs. 100 Ethylene Oxide lbs. 10 1,4-Dioxane lbs. 100 Acetic acid lbs. 5000 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Ethylene Oxide lbs Ethanol 10000 lbs Propane 10000 lbs Butane 10000 lbs Ethanol, 2-butoxy- 10000 lbs Ethanol, 2-amino- 10000 lbs 2-Propanol, 2-methyl- 10000 lbs Ethanol, 2,2'-iminobis- 10000 lbs 1,4-Dioxane 10000 lbs Acetic acid 10000 lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 11/12 Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Ethanol, 2,2'-iminobis- Carcinogenic. 07 2012 Ethylene Oxide Female reproductive toxin. 03 2008 Ethylene Oxide Carcinogenic. 05 2011 Ethylene Oxide Male reproductive toxin. 08 2009 Ethylene Oxide Developmental toxin. 08 2009 1,4-Dioxane Carcinogenic. 05 2011 US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Ethanol Propane Butane Ethanol, 2-butoxy- US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances Chemical Identity Ethanol Propane Butane US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. International regulations Montreal protocol Not applicable Stockholm convention Not applicable Rotterdam convention Not applicable Kyoto protocol Not applicable Version: 1.0 Revision Date: 02/20/2020 SDS_US - RE1000043396 12/12 Inventory Status: Australia AICS: On or in compliance with the inventory Canada DSL Inventory List: On or in compliance with the inventory EINECS, ELINCS or NLP: Not in compliance with the inventory. Japan (ENCS) List: Not in compliance with the inventory. Canada NDSL Inventory: Not in compliance with the inventory. Philippines PICCS: On or in compliance with the inventory US TSCA Inventory: On or in compliance with the inventory New Zealand Inventory of Chemicals: On or in compliance with the inventory Japan ISHL Listing: Not in compliance with the inventory. Japan Pharmacopoeia Listing: Not in compliance with the inventory. Mexico INSQ: Not in compliance with the inventory. Ontario Inventory: Not in compliance with the inventory. Taiwan Chemical Substance Inventory: On or in compliance with the inventory China Inv. Existing Chemical Substances: On or in compliance with the inventory Korea Existing Chemicals Inv. (KECI): On or in compliance with the inventory 16.Other information, including date of preparation or last revision Issue Date: 02/21/2020 Revision Information: No data available. Version #: 1.0 Further Information: No data available. Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment.