SAFETY DATA SHEET Revision Date 06-Oct-2021 Version 8 1. IDENTIFICATION Product identifier Product Name Rain-X Original Glass Treatment Other means of identification Product Code 11890 Document SKU: 800002242, 800002243, 800002245, 800002250, 630045, 630045W Recommended use of the chemical and restrictions on use Recommended Use Glass Treatment Consumer Use Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-855-888-1988 24-hour emergency phone number (CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.) (RMPDC) 1-877-504-9352 (U.S.) E-mail address: This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Supplier Address ITW Global Brands 16200 Park Row, Suite 120 Houston, TX 77084 Manufacturer Address Manufactured and Distributed by: Distributor May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable liquids Category 2 Signal word Danger Causes serious eye irritation May cause drowsiness or dizziness Highly flammable liquid and vapor _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% ETHANOL 64-17-5 30 - 60 ACETONE 67-64-1 10 - 30 Isopropanol 67-63-0 10 - 30 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Appearance Clear Colorless Physical state Liquid Odor Alcohol _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO2, sand, earth, water spray or regular foam Unsuitable extinguishing media CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient Do not use a solid water stream as it may scatter and spread fire Specific hazards arising from the chemical Flammable vapors may be present even at temperatures below the flash point. Explosion data Sensitivity to Mechanical Impact No information available. Sensitivity to Static Discharge May be ignited by heat, sparks or flames. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and inhalation of vapors. Use personal protective equipment as required. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Environmental precautions Environmental precautions See section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use personal protective equipment as required. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep out of the reach of children. Incompatible materials None known 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 ACETONE 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors. (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 Isopropanol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses or goggles if splashing is likely to occur. Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear Colorless Odor Alcohol _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available Density 0.806 - 0.808 g/cm3 Bulk density No information available SADT (self-accelerating decomposition temperature) No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Excessive heat. Incompatible materials None known Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May be harmful if inhaled. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Property Values Remarks ? Method pH 1.5 - 2.5 Melting point / freezing point No information available Boiling point / boiling range No information available Flash point -3 ?C / 27 ?F Setaflash Closed Cup Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Relative density 0.810 - 0.812 Water solubility Soluble in water Solubility(ies) No information available Partition coefficient No information available Autoignition temperature No information available Hyphen No information available Kinematic viscosity No information available Dynamic viscosity No information available Stable under normal use _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. May be harmful if swallowed. Chemical name Oral LD50 Dermal LD50 Inhalation LC50 ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 116.9 mg/L ( Rat ) 4 h = 133.8 mg/L ( Rat ) 4 h ACETONE 67-64-1 = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h Isopropanol 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) > 10000 ppm ( Rat ) 6 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical name ACGIH IARC NTP OSHA ETHANOL 64-17-5 A3 Group 1 Known X Isopropanol 67-63-0 - Group 3 - X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3 - Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target organ effects Blood, Central nervous system, Eyes, Liver, Reproductive system, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 9100 mg/kg ATEmix (dermal) 27060 mg/kg ATEmix (inhalation-dust/mist) 120.1 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 0.75 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility Disperses in water. Chemical name Partition coefficient ETHANOL 64-17-5 -0.32 _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 ACETONE 67-64-1 -0.24 Isopropanol 67-63-0 0.05 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Recover or recycle if possible. This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001, D002 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable ACETONE 67-64-1 Ignitable Isopropanol 67-63-0 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID No UN 1987 Proper shipping name (Alcohols, N.O.S.), Limited Quantity (LQ) Transport hazard class(es) 3 Packing Group II IATA UN number or ID number UN 1987 Proper shipping name (Alcohols, N.O.S.), Limited Quantity (LQ) Transport hazard class(es) 3 Packing group II IMDG UN number or ID number UN 1987 Proper shipping name (Alcohols, N.O.S), Limited Quantity (LQ), Flash point -3C degrees c.c Transport hazard class(es) 3 Packing Group II 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Complies KECL Complies _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical name SARA 313 - Threshold Values % Isopropanol - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Ethanol is only considered a Proposition 65 developmental hazard when it is ingested as a alcoholic beverage. Chemical name California Proposition 65 ETHANOL 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania ETHANOL 64-17-5 X X X ACETONE 67-64-1 X X X Isopropanol 67-63-0 X X X WATER 7732-18-5 - - X Sulfuric Acid 7664-93-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable _____________________________________________________________________________________________ Page 8 / 9 WHMIS Hazard Class _____________________________________________________________________________________________ 11890 - Rain-X Original Glass Treatment Revision Date 06-Oct-2021 D2A - Very toxic materials, B2 - Flammable liquid, D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 06-Oct-2021 Revision Note 4 Disclaimer Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled. However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness of the information. User is responsible for evaluating whether such information or this product is fit for a particular purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc. disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web site. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 1 Personal protection B _____________________________________________________________________________________________ Page 9 / 9