FOUR SEASONS MINERAL OIL 55 GL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 08/20/2013 : Version: 22/08/2013 EN (English US) 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : FOUR SEASONS MINERAL OIL 55 GL Product code : 859600010 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Follow Label Directions 1.3. Details of the supplier of the safety data sheet FOUR SEASONS MFG CO. 1801 WATERS RIDGE DR. LEWISVILLE, TX 75057 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Inhalation:dust,mist) H332 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H332 - Harmful if inhaled Precautionary statements (GHS-US) : P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P271 - Use only outdoors or in a well-ventilated area P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER/doctor/?/if you feel unwell 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substances Name : HC REFRIGERATION OIL CAS No : EC no : EC index no : Name Product identifier % Classification (GHS-US) distillates (petroleum), hydrotreated heavy naphthenic (CAS No) 64742-52-5 100 Acute Tox. 4 (Inhalation:dust,mist), H332 Full text of H-phrases: see section 16 3.2. Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. FOUR SEASONS MINERAL OIL 55 GL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 22/08/2013 EN (English US) 2/6 First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? Inhalable fraction 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. FOUR SEASONS MINERAL OIL 55 GL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 22/08/2013 EN (English US) 3/6 Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Molecular mass : 420 g/mol Color : Colourless to light yellow. Odor : characteristic. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : -33 ?C Freezing point : No data available Boiling point : > 332 ?C Flash point : > 204 ?C Self ignition temperature : > 343 ?C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.0001 mm Hg @20C Relative vapor density at 20 ?C : No data available Relative density : 0.908 Solubility : Insoluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 8.42 cSt @ 100c Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 2.53 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if inhaled. distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) LD50 oral rat > 5000 ml/kg FOUR SEASONS MINERAL OIL 55 GL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 22/08/2013 EN (English US) 4/6 distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classifiedBased on available data, the classification criteria are not met Carcinogenicity : Not classified Reproductive toxicity : Not classifiedBased on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classifiedBased on available data, the classification criteria are not met Aspiration hazard : Not classifiedBased on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Harmful if inhaled. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. SECTION 12: Ecological information 12.1. Toxicity distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) EC50 Daphnia 1 > 1000 mg/l 48 HOURS 12.2. Persistence and degradability FOUR SEASONS MINERAL OIL 55 GL Persistence and degradability Not established. distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) Persistence and degradability Not established. 12.3. Bioaccumulative potential FOUR SEASONS MINERAL OIL 55 GL Bioaccumulative potential Not established. distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA US DOT (ground): Not regulated, ICAO/IATA (air): Not regulated, IMO/IMDG (water): Not regulated, Not applicable 14.2. UN proper shipping name DOT Proper Shipping Name : Not regulated 14.3. Additional information Other information : No supplementary information available. FOUR SEASONS MINERAL OIL 55 GL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 22/08/2013 EN (English US) 5/6 Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations FOUR SEASONS MINERAL OIL 55 GL SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations CANADA distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) Listed on the Canadian DSL (Domestic Substances List) inventory. EU-Regulations distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) substances. Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations distillates (petroleum), hydrotreated heavy naphthenic (64742-52-5) Listed on the AICS (the Australian Inventory of Chemical Substances) Listed on Inventory of Existing Chemical Substances (IECSC) Listed on the Korean ECL (Existing Chemical List) inventory. Listed on New Zealand - Inventory of Chemicals (NZIoC) Listed on Inventory of Chemicals and Chemical Substances (PICCS) 15.3. US State regulations No additional information available SECTION 16: Other information Indication of changes : Revision - See : *. Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ H332 Harmful if inhaled NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. FOUR SEASONS MINERAL OIL 55 GL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 22/08/2013 EN (English US) 6/6 HMIS III Rating Health : 0 Minimal Hazard - No significant risk to health Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard SDS US (GHS HazCom 2012) - Technical Chemical The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product exess_bm01__NO_RELEVANT_DATA