Product Name: RPAG 150 Revision Date: 30 May 2015 Page 1 of 11 GHS and other International SAFETY DATA SHEET SECTION 2: HAZARDS IDENTIFICATION HEALTH HAZARDS Classification of the substance or mixture This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. GHS label elements Hazard pictograms None Required Signal word None Require Precautionary Statement: Avoid contact with skin and eyes. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. Storage Not applicable. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Other hazards which do not result in classification None known. Note : This information is based on test data from similar products. This product is not formulated to contain ingredients which have exposure limits established by regulatory agencies. It is not hazardous to health as defined by the European Union Dangerous Substances/Preparations Directives. Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Please see Section 3 and 15 for country specific classification information, and Section 11 for additional details. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: Product Description: Intended Use: RPAG 150 Synthetic Base Stock and Additives Lubricant, Compressor Lubricant COMPANY IDENTIFICATION Supplier BVA Inc. 48845 West Rd. Wixom, MI 48393 USA +1-248-348-4920 Emergency telephone numbers USA ? Chemtrec: 800-424-9300 All Others ? Chemtrec: +1-703-527-3887 Product Name: RPAG 150 Revision Date: 30 May 2015 Page 2 of 11 GHS and other International SECTION 4 : FIRST AID MEASURES Description of first aid measures Eye: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs. Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth- to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin Contact: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Most important symptoms/effects, acute and delayed Potential acute health effects Eye Contact No known significant effects or critical hazards. Inhalation Harmful if inhaled SECTION 3: COMPONENT INFORMATION Substance/mixture Mixture Other means of identification Not available. CAS number/other identifiers CAS number Not applicable. EC number Mixture Product code Not Available Hazardous Substance(s) or Complex Substance(s) required for disclosure No Hazardous Substance(s) or Complex Substance(s) required for disclosure Ingredient Name CAS # EC # Percent (% wt) Symbols /Risk Phrases None Required There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. INGREDIENT COMMENTS If no EU or no CAS numbers are given for classified components the raw material supplier has applied for / will apply for exemption, have not sent the complete information yet , or there could be no obligation to give the EU or CAS numbers. As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph (i). Product Name: RPAG 150 Revision Date: 30 May 2015 Page 3 of 11 GHS and other International Skin Contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards Over-exposure signs/symptoms Eye Contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin Contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) SECTION 5 : FIRE FIGHTING PROCEDURES Extinguishing Media Suitable extinguishing media Unsuitable extinguishing media Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. None Known Special hazards arising from the substance or mixture None Known Hazardous thermal decomposition products Smoke, Fume, Carbon Dioxide, Carbon Monoxide, Aldehydes, Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Special protective actions for fire-fighters No special protection is required. Additional Information FLAMMABILITY PROPERTIES Flash Point ASTM D92 (open cup) oC (oF) 220 (428) typical Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 : ACCUDENTAL RELEASE MEASURES (SPILL OR LEAK HANDLING PROCEDURES) Personal precautions, protective equipment and emergency procedures: For non-emergency personnel No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Product Name: RPAG 150 Revision Date: 30 May 2015 Page 4 of 11 GHS and other International Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. SECTION 7 : HANDLING AND STORAGE Precautions for safe handling Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Additional Information Storage Do not store in open or unlabeled containers. Store in the following material(s): 316 stainless steel. Carbon steel. Glass-lined container. Polypropylene. Polyethylene-lined container. Stainless steel. Teflon. This material may soften and lift certain paint and surface coatings. Use product promptly after opening. Store in original unopened container. Unopened containers of material stored beyond the recommended shelf life should be retested against the sales specifications before use. Additional storage and handling information on this product may be obtained by calling your sales or customer service contact. Shelf life: Use within 24 Months Specific end uses See the technical data sheet on this product for further information. SECTION 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Limits No exposure limit value known. Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m? - ACGIH TLV, 10 mg/m? - ACGIH STEL. Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s) Recommended monitoring Procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective Product Name: RPAG 150 Revision Date: 30 May 2015 Page 5 of 11 GHS and other International equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Appropriate engineering controls Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Product Name: RPAG 150 Revision Date: 30 May 2015 Page 6 of 11 GHS and other International SECTION 9 : PHYSICAL & CHEMICAL PROPERTIES Information on basic physical and chemical properties General Information (Health Safety and Environmental Information) Physical State Liquid Flash Point typical ?C (?F) > 220 (428)), See Section 5 Color Clear colorless to pale yellow Flammable Limits Lower: No test data available Upper: No test data available Odor Characteristic Flammability (solid, gas) Not applicable to liquids Odor Threshold ND Autoignition Temperature: ND Other Information Vapor Density (Air=1) > 2 at 101 kPa Melting Point No Data Vapor Pressure < 0.013 kPa (0.1 mm Hg) at 20?C Freezing Point ND (See Pour Point) Decomposition Temperature ND Boiling Point ?C (?F) .>250 (482) calculated Organic Volatiles 0.0 g/l EPA 24 method Density at 20oC 1.045-1.055 Evaporation Rate (N-Butyl Acetate = 1): ND Viscosity cSt at 40C +/- 10% 145 pH 5.5 ? 7.5 ASTM E70 (10% in water) Octanol-Water Partition Coefficient (Kow) No data (<3 typical) Solubility in Water 100% at 20?C Oxidizing Properties See Sections 3, 15, 16. Pour Point ?C (?F) -34 (-29) SECTION 10 : STABILITY & REACTIVITY Reactivity No specific test data related to reactivity available for this product or its ingredients. No dangerous reaction known under conditions of normal use. Chemical stability The Product is stable Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to Avoid: No specific data. Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems. High energy sources of ignition. Incompatible Materials: Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Product Name: RPAG 150 Revision Date: 30 May 2015 Page 7 of 11 GHS and other International SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity Product/ingredient name Result Species Dose Exposure Polyalkylene Glycol mixture LC50 Inhalation Vapor LD50 Dermal LD50 Oral Rat Rabbit Rat 5.01 mg/L 8000 mg/kg 8,639 mg/kg 4 hours - - Prolonged skin contact is unlikely to result in absorption of harmful amounts. Harmful effects not anticipated from swallowing small amounts. Sensitization Skin : There is no data available. Respiratory : There is no data available. Mutagenicity There is no data available. Carcinogenicity There is no data available. Reproductive toxicity There is no data available. Teratogenicity There is no data available. Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure) There is no data available. Aspiration hazard There is no data available. Information on the likely routes of exposure Routes of entry anticipated: Oral, Dermal, Inhalation. Potential acute health effects Eye contact No known significant effects or critical hazards. Inhalation Harmful if inhaled. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards Symptoms related to the physical, chemical and toxicological characteristics Eye contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure No known significant effects or critical hazards. Potential immediate effects No known significant effects or critical hazards. Potential delayed effects No known significant effects or critical hazards. Long term exposure No known significant effects or critical hazards. Potential immediate effects No known significant effects or critical hazards. Potential delayed effects No known significant effects or critical hazards. Product Name: RPAG 150 Revision Date: 30 May 2015 Page 8 of 11 GHS and other International Potential chronic health effects General No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. SECTION 12 : ECOLOGICAL INFORMATION Toxicity There is no data available. Persistence and degradability There is no data available. Bioaccumulative potential There is no data available. Mobility in soil Soil/water partition coefficient (KOC) There is no data available. Other adverse effects No known significant effects or critical hazards. The information provided below is based on data available for the material, the components of the material, and similar materials. TOXICITY Material -- Not expected to be harmful to aquatic organisms. Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50 greater than 100 mg/L in most sensitive species). Fish Acute & Prolonged Toxicity ? Typical for the polyalkylene glycol LC50, fathead minnow (Pimephales promelas), static test, 96 Hour, 24,500 mg/l, OECD Test Guideline 203 or Equivalent Aquatic Invertebrate Acute Toxicity EC50, Daphnia magna (Water flea), static test, 48 Hour, 21,000 mg/l, OECD Test Guideline 202 or Equivalent Toxicity to Micro-organisms Toxicity to bacteria IC50, Bacteria, static test, 16 Hour, Growth inhibition, 32,000 mg/l, OECD 209 Test PERSISTENCE and DEGRADABILITY Biodegradability: Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions. 10-day Window: Fail Product Name: RPAG 150 Revision Date: 30 May 2015 Page 9 of 11 GHS and other International Biodegradation: 45 % Exposure time: 28 d Method: OECD Test Guideline 301B or Equivalent 10-day Window: Fail Biodegradation: 44 % Exposure time: 28 d Method: OECD Test Guideline 301F or Equivalent BIOACCUMULATION POTENTIAL Base oil component -- Potential to bioaccumulate is low because of the relatively high water solubility. MOBILITY IN SOIL Base oil component -- No Data. Expected to remain in water or migrate through soil. RESULTS of PBT and vPvB ASSESMENT This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT). OTHER ADVERSE EFFECTS This substance is not in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer. SECTION 13 : DISPOSAL CONSIDERATIONS Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. ADDITIONAL REGULATORY DISPOSAL INFORMATION (Europe) European Waste Code: 13 02 06 NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. ADDITIONAL INFORMATION: Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Product Name: RPAG 150 Revision Date: 30 May 2015 Page 10 of 11 GHS and other International SECTION 14 : TRANSPORT INFORMATION DOT IMDG IATA UN number Not regulated. Not regulated. Not regulated. UN proper shipping name - - - Transport hazard class(es) - - - Packing group - - - Environmental hazards No No No Special precautions for user Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Additional information - - - Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not available. Consult IMO regulations before transporting ocean bulk SECTION 15: REGULATORY INFORMATION United States Safety, health and environmental regulations/legislation specific for the substance or mixture Clean Air Act Section 602 Class I Substances Not listed Clean Air Act Section 602 Class II Substances Not listed DEA List I Chemicals (Precursor Chemicals) Not listed DEA List II Chemicals (Essential Chemicals) Not listed State Regulations Massachusetts None of the components are listed. New York None of the components are listed. New Jersey None of the components are listed. Pennsylvania None of the components are listed. California Prop. 65 No products were found. Detail U.S. Regulations US INVENTORY (TSCA 8b): Listed on inventory. SARA Title III Section 302 Extremely Hazardous Substances (40 CFR Part 355):: This product is not regulated under Section 302 of SARA and 40 CFR Part 355. SARA Title III Sections 311/312 Hazardous Categorization (40 CFR Part 370):: Defined as non-hazardous by OSHA under 29 CFR 1910.1200(d). SARA 313 toxic chemical notification and release reporting: No products were found. CERCLA Sections 102a/103 Hazardous Substances (40 CFR Part 302.4):: This material is not regulated under CERCLA Sections 103 and 107. Canada WHMIS (Canadian Workplace Hazardous Materials Information System) This product when tested as a whole is not a controlled substance within the meaning of the Hazardous Products Act. Product Name: RPAG 150 Revision Date: 30 May 2015 Page 11 of 11 GHS and other International Europe Material is not dangerous as defined by the EU Dangerous Substances/Preparations Directives. EU LABELING: Not regulated according to EC Directives Germany: Water Hazardous Class (WGK): 1 (special considerations ? soluble) Complies with the following national/regional chemical inventory requirements: AICS, IECSC, DSL, EINECS, ENCS, KECI, PICCS, TSCA Chemical Safety Assessment Not applicable. SECTION 16: OTHER INFORMATION This product safety data sheet was prepared in compliance Conforms to HazCom 2012/United States. Certain elements refer to Commission Directive 2001/58/EC , 91/155/EEC, 67/548/EEC and 1999/45/EC for reference, as well as their relevant amendments, on the approximation of laws, regulations and administrative provisions relative to the classification, packaging and labeling of dangerous substances and preparations. History Date of issue: 30 May 2015 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: 16 Oct 2014 GHS compliance updates 30 May 2015 Oral Hazard classification updated to not hazardous ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations N/D = Not determined, N/A = Not applicable KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): U.S.A. Hazardous Material Information System and National Fire Protection Association (U.S.A.) Degree of Hazard NFPA HMIS HAZARD RATINGS Health 1 1 0 Insignificant Fire 1 1 1 Slight Reactivity 0 0 2 Moderate Personal Protection B 3 High The information and recommendations contained herein are, to the best of our knowledge and belief, accurate and reliable as of the date issued. You can contact us to insure that this document is the most current available. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted.