TECH SELECT POE OIL CHARGE 6/4oz Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 09/16/2013 : Version: 16/09/2013 EN (English US) 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixtures Product name. : TECH SELECT POE OIL CHARGE 6/4oz Product code : 40059026 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : FOLLOW LABEL DIRECTIONS 1.3. Details of the supplier of the safety data sheet FOUR SEASONS MFG CO. 1801 WATERS RIDGE DR. LEWISVILLE, TX 75057 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Compressed gas H280 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated Precautionary statements (GHS-US) : P410+P403 - Protect from sunlight. Store in a well-ventilated place P251 - Pressurized container: Do not pierce or burn, even after use P412 - Do not expose to temperatures exceeding 50?C / 122?F 2.3. Other hazards Other hazards not contributing to the classification : Contact with liquid may cause cold burns/frostbite. Contains gas under pressure; may explode if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification (GHS-US) 1,1,1,2-tetrafluoroethane (CAS No) 811-97-2 50 - 70 Compressed gas, H280 Zerol Ester 68 (CAS No) Proprietary 30 - 50 Not classified PROPRIETARY INHIBITOR PACKAGE (CAS No) Proprietary 5 - 10 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. TECH SELECT POE OIL CHARGE 6/4oz Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 16/09/2013 EN (English US) 2/6 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : NFPA Aerosol Level 1. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas TECH SELECT POE OIL CHARGE 6/4oz Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 16/09/2013 EN (English US) 3/6 Appearance : Gas. Molecular mass : 102.03 g/mol Color : Colourless. Odor : Ether-like odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : -101 ?C Freezing point : No data available Boiling point : -26 ?C LOWEST COMPONENT Flash point : > 149 ?C Critical temperature : 101 ?C Self ignition temperature : > 743 ?C Decomposition temperature : 368 ?C Flammability (solid, gas) : No data available Vapor pressure : 5720 hPa Critical pressure : 40560 hPa Relative vapor density at 20 ?C : 3.52 (20 ?C) Relative density : 1.2 (-27 ?C) Density : 1206 kg/m? (-27 ?C) Solubility : Poorly soluble in water. Soluble in ethanol. Soluble in ether. Soluble in hexane. Water: 0.15 g/100ml (25 ?C) Log Pow : 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 0 % Gas group : Compressed gas SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 1,1,1,2-tetrafluoroethane (811-97-2) LC50 inhalation rat (mg/l) > 2000 mg/l/4h (Rat) LC50 inhalation rat (ppm) > 359300 ppm/4h (Rat) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified TECH SELECT POE OIL CHARGE 6/4oz Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 16/09/2013 EN (English US) 4/6 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classifiedBased on available data, the classification criteria are not met Carcinogenicity : Not classified Reproductive toxicity : Not classifiedBased on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classifiedBased on available data, the classification criteria are not met Aspiration hazard : Not classifiedBased on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity 1,1,1,2-tetrafluoroethane (811-97-2) LC50 fish 1 450 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 980 mg/l (48 h; Daphnia magna) 12.2. Persistence and degradability TECH SELECT POE OIL CHARGE 6/4oz Persistence and degradability Not established. Zerol Ester 68 (Proprietary) Persistence and degradability Not established. PROPRIETARY INHIBITOR PACKAGE (Proprietary) Persistence and degradability Not established. 1,1,1,2-tetrafluoroethane (811-97-2) Persistence and degradability Not readily biodegradable in water. 12.3. Bioaccumulative potential TECH SELECT POE OIL CHARGE 6/4oz Log Pow 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Bioaccumulative potential Not established. Zerol Ester 68 (Proprietary) Bioaccumulative potential Not established. PROPRIETARY INHIBITOR PACKAGE (Proprietary) Bioaccumulative potential Not established. 1,1,1,2-tetrafluoroethane (811-97-2) BCF other aquatic organisms 1 5 - 58 (Estimated value) Log Pow 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. TECH SELECT POE OIL CHARGE 6/4oz Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 16/09/2013 EN (English US) 5/6 SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA US DOT (ground): UN1078, Refrigerant gases, n.o.s., 2.2, Limited Quantity ICAO/IATA (air): UN1078, Refrigerant gases, n.o.s., 2.2, Limited Quantity IMO/IMDG (water): UN1078, Refrigerant gases, n.o.s., 2, Limited Quantity Special Provisions: T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. Not applicable 14.2. UN proper shipping name DOT Proper Shipping Name : Refrigerant gases, n.o.s. Department of Transportation (DOT) Hazard Classes : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : 2.2 - Non-flammable compressed gas DOT Symbols : G - Identifies PSN requiring a technical name DOT Special Provisions (49 CFR 172.102) : T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : 304 DOT Packaging Bulk (49 CFR 173.xxx) : 314;315 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 75 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations TECH SELECT POE OIL CHARGE 6/4oz SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Sudden release of pressure hazard 1,1,1,2-tetrafluoroethane (811-97-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Sudden release of pressure hazard 15.2. International regulations CANADA TECH SELECT POE OIL CHARGE 6/4oz WHMIS Classification Class A - Compressed Gas EU-Regulations No additional information available TECH SELECT POE OIL CHARGE 6/4oz Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 16/09/2013 EN (English US) 6/6 Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Indication of changes : Revision - See : *. Other information : None. Full text of H-phrases: see section 16: ------ Compressed gas Gases under pressure Compressed gas ------ H280 Contains gas under pressure; may explode if heated NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard Physical : 2 Moderate Hazard SDS US (GHS HazCom 2012) - Technical Chemical The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product exess_bm01__NO_RELEVANT_DATA