LOW VOC EPOXY PRIMER Not available. INFOTRAC - 800-535-5053 SAFETY DATA SHEET GHS product identifier Other means of identification Emergency telephone number (with hours of operation) Section 1. Identification : : : Supplier's details : AUTO PLUS AUTO PARTS 1155 Roberts Blvd Suite 175 Kennesaw, GA 30144 United States LOW VOC EPOXY PRIMER Relevant identified uses of the substance or mixture and uses advised against Not applicable. Product code : CXP4431G Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard statements : Highly flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Hazard pictograms : Precautionary statements Prevention : Obtain special instructions before use. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Avoid breathing vapor. Wash hands thoroughly after handling. GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 1/15 LOW VOC EPOXY PRIMER Section 2. Hazards identification Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients 4-CHLOROBENZOTRIFLUORIDE ?25 - ?50 98-56-6 BISPHENOL A/EPICHLOROHYDRIN POLY MN 700 -1200 G/MOL ?10 - ?25 - TITANIUM DIOXIDE ?10 13463-67-7 ACETONE ?10 67-64-1 N-BUTYL ALCOHOL <3 71-36-3 XYLENE ?3 1330-20-7 BISPHENOL-EPICHLOROHYDRIN TYPE POLYMER <700MW <1 25068-38-6 ETHYLBENZENE <1 100-41-4 TOLUENE ?0.3 108-88-3 CARBON BLACK ?0.3 1333-86-4 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation : : : Description of necessary first aid measures Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 2/15 LOW VOC EPOXY PRIMER Section 4. First aid measures Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 3/15 LOW VOC EPOXY PRIMER Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides phosphorus oxides halogenated compounds carbonyl halides metal oxide/oxides Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Precautions for safe handling Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 4/15 LOW VOC EPOXY PRIMER Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : 4-chloro-?,?,?-trifluorotoluene None. EPOXY RESIN None. titanium dioxide OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m? 8 hours. Form: Total dust OSHA PEL (United States, 5/2018). TWA: 15 mg/m? 8 hours. Form: Total dust CAL OSHA PEL (United States, 5/2018). TWA: 5 mg/m?, (as Ti) 8 hours. Form: respirable fraction TWA: 10 mg/m?, (as Ti) 8 hours. Form: total dust ACGIH TLV (United States, 1/2022). TWA: 2.5 mg/m? 8 hours. Form: respirable fraction, finescale particles acetone ACGIH TLV (United States, 1/2022). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 750 ppm 8 hours. TWA: 1800 mg/m? 8 hours. STEL: 1000 ppm 15 minutes. STEL: 2400 mg/m? 15 minutes. NIOSH REL (United States, 10/2020). TWA: 250 ppm 10 hours. TWA: 590 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m? 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 5/15 LOW VOC EPOXY PRIMER Section 8. Exposure controls/personal protection CAL OSHA PEL (United States, 5/2018). STEL: 1780 mg/m? 15 minutes. STEL: 750 ppm 15 minutes. C: 3000 ppm TWA: 1200 mg/m? 8 hours. TWA: 500 ppm 8 hours. Normal butyl alcohol ACGIH TLV (United States, 1/2022). TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? NIOSH REL (United States, 10/2020). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 300 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). Absorbed through skin. C: 150 mg/m? C: 50 ppm XYLENE OSHA PEL 1989 (United States, 3/1989). [Xylenes (o-, m-, p-isomers)] TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 655 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). [Xylenes (o-, m-, p-isomers)] TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). [xylene] STEL: 655 mg/m? 15 minutes. STEL: 150 ppm 15 minutes. C: 300 ppm TWA: 435 mg/m? 8 hours. TWA: 100 ppm 8 hours. ACGIH TLV (United States, 1/2022). [p- xylene and mixtures containing p-xylene] Ototoxicant. TWA: 20 ppm 8 hours. reaction product: bisphenol-A-(epichlorhydrin); epoxy resin None. ETHYLBENZENE ACGIH TLV (United States, 1/2022). Ototoxicant. TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 435 mg/m? 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 6/15 LOW VOC EPOXY PRIMER Section 8. Exposure controls/personal protection TWA: 435 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). STEL: 130 mg/m? 15 minutes. STEL: 30 ppm 15 minutes. TWA: 22 mg/m? 8 hours. TWA: 5 ppm 8 hours. TOLUENE OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 375 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 375 mg/m? 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. ACGIH TLV (United States, 1/2022). Ototoxicant. TWA: 20 ppm 8 hours. CAL OSHA PEL (United States, 5/2018). Absorbed through skin. STEL: 560 mg/m? 15 minutes. STEL: 150 ppm 15 minutes. C: 500 ppm TWA: 37 mg/m? 8 hours. TWA: 10 ppm 8 hours. carbon black, non respirable OSHA PEL 1989 (United States, 3/1989). TWA: 3.5 mg/m? 8 hours. NIOSH REL (United States, 10/2020). TWA: 3.5 mg/m? 10 hours. TWA: 0.1 mg of PAHs/cm? 10 hours. ACGIH TLV (United States, 1/2022). TWA: 3 mg/m? 8 hours. Form: Inhalable fraction OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m? 8 hours. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 7/15 LOW VOC EPOXY PRIMER Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Density Vapor density Solubility(ies) Liquid. Technically not possible to measure 1.58 g/cm? Not available. 1.8 kPa (13.5 mm Hg) Not available.Odor pH Gray.Color Evaporation rate Not available. Auto-ignition temperature Flash point 355?C (671?F) Closed cup: 0.6?C (33.1?F) Not applicable. Not applicable. Viscosity Not available. Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 56.1 to 3000?C (133 to 5432?F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.9% Upper: 10.5% Decomposition temperature : Not applicable. Solubility in water : Not available. cold water Partially soluble Media Result Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 8/15 LOW VOC EPOXY PRIMER Section 9. Physical and chemical properties Flow time (ISO 2431) : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 4-chloro-?,?,?-trifluorotoluene LD50 Oral Rat 13 g/kg - acetone LC50 Inhalation Vapor Rat 21 mg/l 4 hours LD50 Dermal Rabbit 2001 mg/kg - LD50 Oral Rat 5800 mg/kg - Normal butyl alcohol LC50 Inhalation Vapor Rat 24000 mg/m? 4 hours LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg - XYLENE LC50 Inhalation Gas. Rat 5000 ppm 4 hours LD50 Oral Rat 4300 mg/kg - ETHYLBENZENE LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - TOLUENE LC50 Inhalation Vapor Rat 49 g/m? 4 hours LD50 Dermal Rat 5001 mg/kg - LD50 Oral Rat 5001 mg/kg - TDLo Dermal Rat 26.4 mg/kg - carbon black, non respirable LD50 Oral Rat >15400 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion acetone Eyes - Mild irritant Human - 186300 ppm - Eyes - Mild irritant Rabbit - 10 uL - Eyes - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Severe irritant Rabbit - 20 mg - Skin - Mild irritant Rabbit - 395 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Normal butyl alcohol Eyes - Cornea opacity Rabbit 2.11 - 7 days Eyes - Severe irritant Rabbit - 0.005 Ml - Eyes - Severe irritant Rabbit - 24 hours 2 mg - Skin - Moderate irritant Rabbit - 24 hours 20 mg - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 9/15 LOW VOC EPOXY PRIMER Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. XYLENE Eyes - Mild irritant Rabbit - 87 mg - Eyes - Severe irritant Rabbit - 24 hours 5 mg - Skin - Mild irritant Rat - 8 hours 60 uL - Skin - Moderate irritant Rabbit - 100 % - Skin - Moderate irritant Rabbit - 24 hours 500 mg - reaction product: bisphenol-A- (epichlorhydrin); epoxy resin Eyes - Mild irritant Rabbit - 100 mg - Skin - Moderate irritant Rabbit - 24 hours 500 uL - Skin - Severe irritant Rabbit - 24 hours 2 mg - ETHYLBENZENE Skin - Mild irritant Rabbit - 24 hours 15 mg - TOLUENE Skin - Mild irritant Pig - 24 hours 250 uL - Skin - Mild irritant Rabbit - 435 mg - Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) 4-chloro-?,?,?-trifluorotoluene Category 3 - Respiratory tract irritation acetone Category 3 - Narcotic effects Normal butyl alcohol Category 3 - Respiratory tract irritation Category 3 Narcotic effects XYLENE Category 3 - Respiratory tract irritation TOLUENE Category 3 - Narcotic effects Name Category Name Category ETHYLBENZENE Category 2 - - TOLUENE Category 2 - - Route of exposure Target organs Route of exposure Target organs Classification 4-chloro-?,?,?-trifluorotoluene - 2B - titanium dioxide - 2B - XYLENE - 3 - ETHYLBENZENE - 2B - TOLUENE - 3 - carbon black, non respirable - 2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 10/15 LOW VOC EPOXY PRIMER Section 11. Toxicological information Not available. Information on the likely routes of exposure Inhalation : May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Aspiration hazard Name Result XYLENE ASPIRATION HAZARD - Category 1 ETHYLBENZENE ASPIRATION HAZARD - Category 1 TOLUENE ASPIRATION HAZARD - Category 1 : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 11/15 LOW VOC EPOXY PRIMER Section 11. Toxicological information Fertility effects : Suspected of damaging fertility. Numerical measures of toxicity Acute toxicity estimates Oral 17522.34 mg/kg Dermal 11006.62 mg/kg Inhalation (gases) 151353.75 ppm Route ATE value Section 12. Ecological information There are no data available on the product itself. The product should not be allowed to enter drains or watercourses waterways. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 II PAINT 3 II PAINT UN1263 3 II UN1263 UN1263 Reportable quantity 4618.3 lbs / 2096.7 kg [350.56 gal / 1327 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. DOT Classification UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. Yes. Yes. The environmentally hazardous substance mark is not required. UN1263 PAINT 3 II No. UN1263 PAINT 3 II No. DOT Classification : TDG Classification Mexico Classification IMDG IATA Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 12/15 LOW VOC EPOXY PRIMER Section 14. Transport information The marine pollutant mark is not required when transported in sizes of ?5 L or ?5 kg. The environmentally hazardous substance mark may appear if required by other transportation regulations. Special precautions for user Transport in bulk according to IMO instruments Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). TDG Classification IMDG IATA : : : The actual shipping description for this product may vary based several factors including, but not limited to, the volume of material, size of the container, mode of transport and use of exemptions or exceptions found in the applicable regulations. The information provided in Section 14 is one possible shipping description for this product. Consult your shipping specialist or supplier for appropriate assignment information. Section 15. Regulatory information SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. trizinc bis(orthophosphate) 7779-90-0 ?10 butan-1-ol 71-36-3 <3 XYLENE 1330-20-7 ?3 ZINC OXIDE 1314-13-2 ?3 ETHYLBENZENE 100-41-4 <1 trizinc bis(orthophosphate) 7779-90-0 ?10 butan-1-ol 71-36-3 <3 XYLENE 1330-20-7 ?3 ZINC OXIDE 1314-13-2 ?3 ETHYLBENZENE 100-41-4 <1 Form R - Reporting requirements Supplier notification Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed SARA 304 RQ : Not applicable. Inventory list Canada : All components are listed or exempted. United States : All components are listed or exempted. SARA 311/312 Classification : FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 13/15 LOW VOC EPOXY PRIMER Section 16. Other information 11/2/2023 History Date of printing Date of issue/Date of revision Version Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations 11/2/2023 4/28/2023 19 Hazardous Material Information System (U.S.A.) 2 3 0 0 3 3 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 14/15 LOW VOC EPOXY PRIMER Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision : 11/2/2023 Date of previous issue : 4/28/2023 Version : 19 15/15