3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2023, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-9370-8 Version Number: 7.00 Issue Date: 04/03/23 Supercedes Date: 07/11/14 SECTION 1: Identification 1.1. Product identifier 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 1.2. Recommended use and restrictions on use Recommended use Abrasive Product, For industrial/occupational use only. Not for consumer sale or use. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Abrasive Systems Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200. 2.2. Label elements Signal word Not applicable. Symbols Not applicable. Pictograms Not applicable. 94% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Cloth Backing Mixture 25 - 65 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 2 of 10 Aluminum Oxide Mineral (non-fibrous) 1344-28-1 20 - 45 Cured Resin Mixture 15 - 35 Filler 471-34-1 < 20 Filler 1318-74-7 0.5 - 2 Carbon Black 1333-86-4 0.1 - 0.5 Titanium Dioxide 13463-67-7 0.3 - 0.5 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting. Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed No critical symptoms or effects. See Section 11.1, information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Observe precautions from other sections. 6.2. Environmental precautions Not applicable. 6.3. Methods and material for containment and cleaning up 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 3 of 10 Not applicable. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of dust created by sanding, grinding or machining. Combustible dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Aluminum, insoluble compounds 1318-74-7 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Aluminum Oxide Mineral (non- fibrous) 1344-28-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Particles (insoluble or poorly soluble) not otherwise specified, inhalable particles 1344-28-1 ACGIH TWA(inhalable particulates):10 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, respirable particles 1344-28-1 ACGIH TWA(respirable particles):3 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA(Respirable nanoscale particles):0.2 mg/m3;TWA(Respirable finescale particles):2.5 mg/m3 A3: Confirmed animal carcin. Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 CAS NO SEQ126498 471-34-1 OSHA TWA(as total dust):15 mg/m3 CAS NO SEQ126499 471-34-1 OSHA TWA(respirable fraction):5 mg/m3 DUST, INERT OR NUISANCE 471-34-1 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):5 mg/m3;TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3) Limestone 471-34-1 OSHA TWA(as total dust):15 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 4 of 10 mg/m3;TWA(respirable fraction):5 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, inhalable particles 471-34-1 ACGIH TWA(inhalable particulates):10 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, respirable particles 471-34-1 ACGIH TWA(respirable particles):3 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). 8.2.2. Personal protective equipment (PPE) Eye/face protection To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. Respiratory protection Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 5 of 10 Appearance Physical state Color Solid Red Odor Slight Polymeric Odor threshold Not Applicable pH Not Applicable Melting point Not Applicable Boiling Point Not Applicable Flash Point Not Applicable Evaporation rate Not Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Specific Gravity Not Applicable Solubility In Water Not Applicable Solubility- non-water Not Applicable Partition coefficient: n-octanol/ water Not Applicable Autoignition temperature Not Applicable Decomposition temperature Not Applicable Viscosity Not Applicable Hazardous Air Pollutants No Data Available Volatile Organic Compounds No Data Available Percent volatile No Data Available SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 6 of 10 present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Eye Contact: Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: No health effects are expected. Carcinogenicity: Ingredient CAS No. Class Description Regulation Carbon black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Titanium dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered. This product contains titanium dioxide. Cancer of the lungs has been observed in rats that inhaled high levels of titanium dioxide. No exposure to inhaled titanium dioxide is expected during the normal handling and use of this product. Titanium dioxide was not detected when air sampling was conducted during simulated use of similar products containing titanium dioxide. Therefore, the health effects associated with titanium dioxide are not expected during the normal use of this product. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Aluminum Oxide Mineral (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide Mineral (non-fibrous) Inhalation- Dust/Mist (4 hours) Rat LC50 > 2.3 mg/l Aluminum Oxide Mineral (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg Filler Dermal Rat LD50 > 2,000 mg/kg Filler Inhalation- Dust/Mist (4 hours) Rat LC50 3 mg/l Filler Ingestion Rat LD50 6,450 mg/kg 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 7 of 10 Filler Dermal LD50 estimated to be > 5,000 mg/kg Filler Ingestion Human LD50 > 15,000 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation Filler Rabbit No significant irritation Filler Professio nal judgeme nt No significant irritation Titanium Dioxide Rabbit No significant irritation Carbon Black Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation Filler Rabbit No significant irritation Filler Professio nal judgeme nt No significant irritation Titanium Dioxide Rabbit No significant irritation Carbon Black Rabbit No significant irritation Skin Sensitization Name Species Value Titanium Dioxide Human and animal Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Aluminum Oxide Mineral (non-fibrous) In Vitro Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Aluminum Oxide Mineral (non-fibrous) Inhalation Rat Not carcinogenic Filler Inhalation Multiple animal species Not carcinogenic Titanium Dioxide Ingestion Multiple animal Not carcinogenic 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 8 of 10 species Titanium Dioxide Inhalation Rat Carcinogenic Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Filler Ingestion Not classified for development Rat NOAEL 625 mg/kg/day premating & during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Filler Inhalation respiratory system Not classified Rat NOAEL 0.812 mg/l 90 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Aluminum Oxide Mineral (non-fibrous) Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aluminum Oxide Mineral (non-fibrous) Inhalation pulmonary fibrosis Not classified Human NOAEL Not available occupational exposure Filler Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Filler Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL NA occupational exposure Filler Inhalation pulmonary fibrosis Not classified Rat NOAEL Not available Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.01 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis Not classified Human NOAEL Not available occupational exposure Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not available occupational exposure Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 9 of 10 SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Not applicable Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Aluminum Oxide Mineral (non-fibrous) 1344-28-1 20 - 45 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements. Contact 3M for more information. 3M? Abrasive Products, 314D, Grades P80 - P400 Utility Cloth 04/03/23 __________________________________________________________________________________________ Page 10 of 10 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 0 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 19-9370-8 Version Number: 7.00 Issue Date: 04/03/23 Supercedes Date: 07/11/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com