Revision date: 1/31/2023 Revision: 3 SAFETY DATA SHEET Acid Mag Wheel Cleaner According to Appendix D, OSHA Hazard Communication Standard 29 CFR ?1910.1200 1. Identification Product identifier Product name Acid Mag Wheel Cleaner Product number 105 Recommended use of the chemical and restrictions on use Application Car maintenance product. Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer 3D International LLC 20724 Centre Pointe Pkwy Unit 1 Santa Clarita, CA 91350 888-999-7627 Emergency telephone number Emergency telephone CHEMTREC 1-800-424-9300 (US and Canada) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Not Classified Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H332 Skin Corr. 1A - H314 Eye Dam. 1 - H318 Environmental hazards Not Classified Label elements Hazard symbols Signal word Danger Hazard statements H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. 1/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Precautionary statements P260 Do not breathe vapor/ spray. P261 Avoid breathing vapor/ spray. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301+P312 If swallowed: Call a poison center/ doctor if you feel unwell. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/ doctor. P321 Specific treatment (see medical advice on this label). P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/ container in accordance with national regulations. Contains Sulphuric Acid sol, ammonium bifluoride Other hazards This product does not contain any substances classified as PBT or vPvB. 3. Composition/information on ingredients Mixtures Sulphuric Acid Solution 10-30% CAS number: 7664-93-9 Classification Skin Corr. 1A - H314 Eye Dam. 1 - H318 ammonium bifluoride 5-10% CAS number: 1341-49-7 Classification Acute Tox. 3 - H301 Skin Corr. 1B - H314 Eye Dam. 1 - H318 propan-2-ol 1-5% CAS number: 67-63-0 Classification Flam. Liq. 2 - H225 Eye Irrit. 2A - H319 STOT SE 3 - H336 The full text for all hazard statements is displayed in Section 16. 4. First-aid measures Description of first aid measures General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel. Chemical burns must be treated by a physician. 2/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention. Place unconscious person on their side in the recovery position and ensure breathing can take place. Ingestion Rinse mouth thoroughly with water. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Never give anything by mouth to an unconscious person. Place unconscious person on their side in the recovery position and ensure breathing can take place. Keep affected person under observation. Get medical attention if symptoms are severe or persist. Skin Contact It is important to remove the substance from the skin immediately. Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes and get medical attention. Chemical burns must be treated by a physician. Eye contact Rinse immediately with plenty of water. Do not rub eye. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention. Protection of first aiders It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Severe irritation of nose and throat. Symptoms following overexposure may include the following: Corrosive to the respiratory tract. Ingestion May cause chemical burns in mouth, esophagus and stomach. Symptoms following overexposure may include the following: Severe stomach pain. Nausea, vomiting. Skin contact Causes severe burns. Symptoms following overexposure may include the following: Pain or irritation. Redness. Blistering may occur. Eye contact Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. This product is toxic. Severe corrosive hazard. Water used for fire extinguishing, which has been in contact with the product, may be corrosive. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Very toxic or corrosive gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. 3/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Special protective equipment for firefighters Regular protection may not be safe. Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk. Do not touch or walk into spilled material. Avoid inhalation of vapors and spray/mists. Use suitable respiratory protection if ventilation is inadequate. Avoid contact with skin and eyes. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Methods and material for containment and cleaning up Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Do not use sawdust or other combustible material. This product is corrosive. Provide adequate ventilation. If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Neutralize with alkali. Caution. May generate heat. Following dilution and neutralization, discharge to the sewer with plenty of water may be permitted. The requirements of the local water authority must be complied with if contaminated water is flushed directly to the sewer. For waste disposal, see Section 13. Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. This product is corrosive. Immediate first aid is imperative. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Store away from the following materials: Alkalis. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Storage class Corrosive storage. Specific end uses(s) Specific end use(s) The identified uses for this product are detailed in Section 1. 8. Exposure controls/Personal protection Control parameters Occupational exposure limits Sulphuric Acid Solution 4/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Long-term exposure limit (8-hour TWA): OSHA 1 mg/m? Long-term exposure limit (8-hour TWA): ACGIH 0.2 mg/m? thoracic fraction A2 propan-2-ol Long-term exposure limit (8-hour TWA): OSHA 400 ppm 980 mg/m? Long-term exposure limit (8-hour TWA): ACGIH 200 ppm 492 mg/m? Short-term exposure limit (15-minute): ACGIH 400 ppm 984 mg/m? A4 OSHA = Occupational Safety and Health Administration. ACGIH = American Conference of Governmental Industrial Hygienists. A2 = Suspected Human Carcinogen. A4 = Not Classifiable as a Human Carcinogen. Sulphuric Acid Solution (CAS: 7664-93-9) Immediate danger to life and health 15 mg/m? propan-2-ol (CAS: 67-63-0) Immediate danger to life and health 2000 ppm Exposure controls Protective equipment Appropriate engineering controls Provide adequate ventilation. Eye/face protection Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resist degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended. Other skin and body protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Keep container tightly sealed when not in use. Avoid release to the environment. 9. Physical and chemical properties Information on basic physical and chemical properties Appearance Colored liquid. Color Brownish. Odor Acidic. Odor threshold No information available. pH pH (concentrated solution): 2-3 Melting point No information available. 5/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Initial boiling point and range No information available. Flash point No information available. Evaporation rate No information available. Evaporation factor No information available. Flammability (solid, gas) No information available. Upper/lower flammability or explosive limits No information available. Other flammability No information available. Vapor pressure No information available. Vapor density No information available. Relative density ~ 1.17 Bulk density No information available. Solubility(ies) Soluble in water. Partition coefficient No information available. Auto-ignition temperature No information available. Decomposition Temperature No information available. Viscosity No information available. Other information None. 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions No potentially hazardous reactions known. Conditions to avoid There are no known conditions that are likely to result in a hazardous situation. Materials to avoid Alkalis. Amines. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Corrosive gases or vapors. 11. Toxicological information Information on toxicological effects Acute toxicity - oral Summary Harmful if swallowed. ATE oral (mg/kg) 1,308.9 Acute toxicity - dermal Summary Based on available data the classification criteria are not met. Acute toxicity - inhalation Summary Harmful if inhaled. ATE inhalation (dusts/mists mg/l) 1.5 Skin corrosion/irritation 6/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Summary Causes severe skin burns and eye damage. Extreme pH Moderate pH ( > 2 and < 11.5). Serious eye damage/irritation Summary Causes serious eye damage. Respiratory sensitization Summary Based on available data the classification criteria are not met. Skin sensitization Summary Based on available data the classification criteria are not met. Germ cell mutagenicity Summary Based on available data the classification criteria are not met. Carcinogenicity Summary Based on available data the classification criteria are not met. IARC carcinogenicity Contains a substance which may be potentially carcinogenic. IARC Group 3 Not classifiable as to its carcinogenicity to humans. Reproductive toxicity Summary Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure Summary Based on available data the classification criteria are not met. Specific target organ toxicity - repeated exposure Summary Based on available data the classification criteria are not met. Aspiration hazard Summary Based on available data the classification criteria are not met. General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation Corrosive to the respiratory tract. Symptoms following overexposure may include the following: Severe irritation of nose and throat. Ingestion May cause chemical burns in mouth, esophagus and stomach. Symptoms following overexposure may include the following: Severe stomach pain. Nausea, vomiting. Skin Contact Causes severe burns. Symptoms following overexposure may include the following: Pain or irritation. Redness. Blistering may occur. Eye contact Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness. Route of exposure Ingestion Inhalation Skin and/or eye contact Target Organs No specific target organs known. 12. Ecological information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment. Acute aquatic toxicity Summary Based on available data the classification criteria are not met. Chronic aquatic toxicity Summary Based on available data the classification criteria are not met. Persistence and degradability 7/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility The product is water-soluble and may spread in water systems. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. 14. Transport information General For limited quantity packaging/limited load information, consult the relevant modal documentation using the data shown in this section. UN Number UN No. (TDG) 3264 UN No. (IMDG) 3264 UN No. (ICAO) 3264 UN proper shipping name Proper shipping name (TDG) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Proper shipping name (IMDG) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Proper shipping name (ICAO) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Transport hazard class(es) TDG class 8 TDG label(s) 8 IMDG Class 8 ICAO class/division 8 Transport labels Packing group TDG Packing Group II IMDG packing group II ICAO packing group II 8/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Environmental hazards Environmentally Hazardous Substance No. Special precautions for user Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. IMDG Code segregation group 1. Acids EmS F-A, S-B 15. Regulatory information Regulatory References OSHA Hazard Communication Standard 29 CFR ?1910.1200 US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities The following ingredients are listed or exempt: Sulphuric Acid Solution EPCRA 302 TPQ 1000 lbs Tier II TPQ 500 lbs CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) The following ingredients are listed or exempt: ammonium bifluoride Final CERCLA RQ: 100(45.4) pounds (Kilograms) Sulphuric Acid Solution Final CERCLA RQ: 1000(454) pounds (Kilograms) SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting The following ingredients are listed or exempt: ammonium bifluoride 1.0 % Sulphuric Acid Solution 1.0 % CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories Acute toxicity (any route of exposure) Serious eye damage or eye irritation Skin corrosion or irritation OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins None of the ingredients are listed or exempt. 9/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner California Air Toxics "Hot Spots" (A-I) The following ingredients are listed or exempt: Sulphuric Acid Solution propan-2-ol California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. California Directors List of Hazardous Substances The following ingredients are listed or exempt: ammonium bifluoride Sulphuric Acid Solution propan-2-ol Massachusetts "Right To Know" List The following ingredients are listed or exempt: ammonium bifluoride Sulphuric Acid Solution propan-2-ol Rhode Island "Right To Know" List The following ingredients are listed or exempt: Sulphuric Acid Solution propan-2-ol Minnesota "Right To Know" List The following ingredients are listed or exempt: Sulphuric Acid Solution propan-2-ol New Jersey "Right To Know" List The following ingredients are listed or exempt: ammonium bifluoride Sulphuric Acid Solution propan-2-ol Pennsylvania "Right To Know" List The following ingredients are listed or exempt: ammonium bifluoride Sulphuric Acid Solution propan-2-ol Inventories US - TSCA All the ingredients are listed or exempt. US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information 10/11 Revision date: 1/31/2023 Revision: 3 Acid Mag Wheel Cleaner Abbreviations and acronyms used in the safety data sheet TDG: The transport of dangerous goods act IATA: International air transport association. ICAO: Technical instructions for the safe transport of dangerous goods by air. IMDG: International maritime dangerous goods. CAS: Chemical abstracts service. ATE: Acute toxicity estimate. LC??: Lethal concentration to 50 % of a test population. LD??: Lethal dose to 50% of a test population (median lethal dose). EC??: 50% of maximal effective concentration. PBT: Persistent, bioaccumulative and toxic substance. vPvB: Very persistent and very bioaccumulative. Classification abbreviations and acronyms Acute Tox. = Acute toxicity Eye Dam. = Serious eye damage Skin Corr. = Skin corrosion Training advice Read and follow manufacturer's recommendations. Revision date 1/31/2023 Revision 3 SDS No. 4825 Hazard statements in full H225 Highly flammable liquid and vapor. H301 Toxic if swallowed. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. End of safety data sheet. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 11/11 SAFETY DATA SHEET - Acid Mag Wheel Cleaner 1. Identification Product identifier Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Emergency telephone number 2. Hazard(s) identification Classification of the substance or mixture Label elements Other hazards 3. Composition/information on ingredients Mixtures 4. First-aid measures Description of first aid measures Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Extinguishing media Special hazards arising from the substance or mixture Advice for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Specific end uses(s) 8. Exposure controls/Personal protection Control parameters Exposure controls 9. Physical and chemical properties Information on basic physical and chemical properties 10. Stability and reactivity 11. Toxicological information Information on toxicological effects 12. Ecological information Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Waste treatment methods 14. Transport information UN Number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user 15. Regulatory information 16. Other information