GHS SAFETY DATA SHEET Yellow Degreaser 106 Section 2 Hazards Identification Chemical Name: % IN PRODUCTCAS NUMBER 1310-73-2 <3Sodium Hydroxide EDTA - Biodegradable Sodium Metasilicate Ethoxylated Alcohol 64-02-8 6834-92-0 68439-46-3 <3 <3 3 to 5 Section 3 Composition/Information on ingredients: Classification of the Substance or Mixture: 1)ACUTE TOXICITY:ORAL,SKIN and INHALATION Category4. 2)SKIN CORROSION/IRRITATION Category2. 3) EYE DAMAGE/EYE IRRITATION Category2A GHS label elements: Signal Word: Warning Hazard Statement: 1)H302 Harmful if swallowed. 2) H315 Causes skin irritation. 3)H319 Causes serious eye irritation Precautionary Statements: Prevention : P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves and eye protection Response : P301 + P312 IF SWALLOWED: Call a POISON CENTER or a doctor/physician if you feel unwell. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P321 Use Moisturizing cream. Storage: Keep closed and away from children. Keep away from heat or flame. Substance/Mixture: Mixture Product Description: Degreaser Emergency Telephone Number: CHEMTREC 1-800-424-9300 (US and Canada) All other locations 01-707-703-527-3887 Company Name and Address: 3D INTERNATIONAL 20724 Centre Pointe Parkway, Santa Clarita CA 91350 Section 1 Identification Product Code and Name: 106 Yellow Degreaser There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8 Page 1 of 5 Business Phone: 888-999-7627 P332 + P313 If skin irritation occurs: Get medical attention. P362 Take off contaminated clothing and wash before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical attention. GHS SAFETY DATA SHEET Yellow Degreaser 106 Section 5 Fire Fighting Measures Extinguishing Media Regular Foam, Waterfog, Carbon Dioxide, or Dry Chemicals Hazardous Decomposition: Oxides of carbon or traces of hydrocarbons may be formed in small amounts. Special Fire Fighting Procedures: Clear fire area of personnel. Do not enter confined fire area without full bunker gear and positive pressure breathing apparatus. Unusual Fire / Explosion Hazards: Not Listed Can cause severe irritation, redness, tearing, and blurred vision. Any contact can cause moderate irritation Fine mist may cause irritation of the nose and throat. Gastrointestinal irritation. Section 4 First Aid Measures: Eye contact : Wash eyes immediately with large amounts of water. Skin contact: Wash contacted areas with mild soap and water. Inhalation: Move person to fresh air at once. If breathing has stopped, get medical attention immediately. Ingestion: Do not induce vomiting. If person is conscious, give water. Get medical attention. Special Hazar Description of necessary first aid measures Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact: Inhalation: Skin contact: Ingestion: Over-exposure signs/Symptoms Eye contact: Inhalation: Skin contact: Ingestion: Adverse symptoms may include the following: Adverse symptoms may include the following: Adverse symptoms may include the following: Adverse symptoms may include the following: Indication of immediate medical attention and special treatment needed, if necessary Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled Specific treatments: No specific treatment Protection of first -aiders: No action should be taken involving any personal risk or without suitable training. Wash contaminated clothing throughly with water before removing it. Irritation No significant effect Irritation Gastrointestinal irritation Suitable extinguishing media Unsuitable extinguishing media None known Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. Hazardous thermal decomposition products Special protective actionsfor fire-fighters If there is a fire, Promptly isolate the scene by removing all persons from the vicinity of the incident.. Special protective equipment for fire-fighters Fire-fighters shoud wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page 2 of 5 Yellow Degreaser SAFETY DATA SHEET 106 Section 8: Exposure Controls/personal protection Section 6 Accidental Release Measures Use Gloves, Goggles, Boots and Breathing Mask. Small amounts do not need special measures.Clean up with water. For large spills remove all sources of ignition. Ventilate area. Absorb with an inert absorbent material. Avoid runoff into drains and sewers.All used and unused product should be disposed of in conformance with local, state, and federal regulations Section 7 Handling and Storage Store materials tightly closed and away from sunlight, warm confined spaces, heat and open flame. Never weld on or near containers either empty or full. Secure all chemicals out of the reach of children. Control parameters Occupational exposure limits Ingredient name 2mg/Cubic M PEL/OSHA TLV-ACGIH 2mg /Cubic M EDTA - Biodegradable 50 ppm 25 ppm Sodium Metasilicate Ethoxylated Alcohol 3 Mg/Cubic M Not Applicable 3 Mg/Cubic M Not Applicable Personal precautions, protective equipment and emergency procedures For non-emergency personel: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flares in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in for "For non-emergency personnel". Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental polllution (sewers, waterways, soil or air) Methods and materials for containment and cleaning up Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose via a licensed waste disposal contractor. Large spill: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment.Dispose via a licensed waste contractor. Contaminated absorbent material may pose the same hazard as Precautions for safe handling: Put on appropriate protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Keep in the original container or an approved alternate made from a compatible material, keep tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Do not reuse container. Wash throughly after use. Conditions for safe storage: Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Do not store in unlabeled Appropriate engineering controls No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants Individual protection measures Hygiene Measures: Wash hands forearms and face throughly after handling chemical products Eye/face protection: Skin protection: Respiratory protection: Page?3?of?5 CAS?# 1310-73-2 64-02-8 6834-92-0 68439-46-3 Sodium Hydroxide Wear?chemical?safety?goggles Avoid?skin?contact.?Wear?chemical?resistant?impermeable?gloves None Yellow Degreaser SAFETY DATA SHEET 106 Section 9: Physical and chemical properties Physical state Boiling Point: >211 'F Yellow Liquid, Sour Od Color: Yellow Odor: Sour pH: 12 Flash point: None Specific Gravity: 1.02 Vapor Pressure: <1(low volatile) Volatiles: 98% Vapor Density: >1 Fall in air Solubility: 100% Evaporation Rate: <=Water Volatile Organic Compound (VOC) content for Consumer Products Applications Percent by weight: 0% Section 10. Stability and reactivity Reactivity: No specific test data related to reactivity available for this product or its ingredients Chemical stability: The product is stable Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur Conditions of instability: When exposed to high temperatures vcolors may fade and bottles may panel Conditions to avoid: Hazardous decomposition products: Under normal conditions of storage and use, hahardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Irritation/corrosion Eyes Irritation Skin Irritation Inhalation No significant effect Ingestion Gastrointestinal irritation Sensitazion There is no data available Mutagenecity There is no data available Carcinogenicity There is no data available Reproductive toxicity There is no data available Teratogenecity There is no data available Specific target organ toxicity (single exposure) There is no data available Specific target organ toxicity (repeated exposure) There is no data available Aspiration hazard There is no data available Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Not available Potential delayed effects Not available Long term exposure Potential immediate effects Not available Potential delayed effects Not available Potential Chronic health effects General Not known significant effects or critical hazards Carcinogenicity Not known significant effects or critical hazards Mutagenicity Teragenicity Developmental effects Fertility effects Not known significant effects or critical hazards Not known significant effects or critical hazards Not known significant effects or critical hazards Page?4?of?5 Not classified Not known significant effects or critical hazards Yellow Degreaser GHS SAFETY DATA SHEET 106 Section 12. Ecological information Toxicity: Not available Persistance and degradability: Not available Bioacumulative potential Not available Mobility in soil: soil/water partition coefficient (Koc): Not available Other adverse effects: No known significant effects or critical hazards Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the sewer but processes in a suitable effluent treatment plant. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal ligislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This materialand its container must be disposed of in a safe way.Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containersw unless they have been cleaned throughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information DOT IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Aditional information Special precautions for user Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Not regulated Not regulated Not regulated None None None Not classified as Hazardous for Transport Not classified as Hazardous for Transport Not classified as Hazardous for Transport No No No Not available Not applicable Not applicable Not applicable Not available Not available Section 15. Regulatory information Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Not listed Clean Air Act Section 602 Class I Substances Not listed Clean Air Act Section 602 Class II Substances Not listed DEA List I Chemicals (Precursor Chemicals) Not listed DEA List II Chemicals (Essential Chemicals) Not listed SARA 302/304/311/312 extremely hazardous substances: Not applicable SARA 302/304 emergency planning and notification: Not Applicable SARA 302/304/311/312 hazardous chemicals: No products were found Section 16. Other information Version Nov8/2011 Date of issue 5/27/2015 Page 5 of 5 Disclaimer of Liability: The information contained herein is based on data considered to be accurate. However, the information is provided without any warranty, expressed or implied, regarding its correctness. The Conditions or methods of handeling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of this product. Health 1NFPA Ratings: Flammability 0 Reactivity 0 106 Yellow Degreaser 1 106 Yellow Degreaser 2 106 Yellow Degreaser 3