Revision date: 4/26/2021 Revision: 2 SAFETY DATA SHEET Glass Polish According to Appendix D, OSHA Hazard Communication Standard 29 CFR ?1910.1200 1. Identification Product identifier Product name Glass Polish Product number 521 Recommended use of the chemical and restrictions on use Application Glass Polish Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer 3D International LLC 20724 Centre Pointe Pkwy Unit 1 Santa Clarita, CA 91350 888-999-7627 Emergency telephone number Emergency telephone CHEMTREC 1-800-424-9300 (US and Canada) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Not Classified Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 STOT SE 3 - H335 Asp. Tox. 1 - H304 Environmental hazards Not Classified Label elements Hazard symbols Signal word Danger Hazard statements H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. 1/9 Revision date: 4/26/2021 Revision: 2 Glass Polish Precautionary statements P261 Avoid breathing vapor/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, eye and face protection. P301+P310 If swallowed: Immediately call a poison center/ doctor. P302+P352 If on skin: Wash with plenty of water. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a poison center/ doctor if you feel unwell. P331 Do NOT induce vomiting. P332+P313 If skin irritation occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/ container in accordance with national regulations. Contains Distillates (petroleum), hydrotreated middle Other hazards This product does not contain any substances classified as PBT or vPvB. 3. Composition/information on ingredients Mixtures Water 30-60% CAS number: 7732-18-5 Cerium Oxide 10-30% CAS number: 1306-38-3 Distillates (petroleum), hydrotreated middle 10-30% CAS number: 64742-46-7 Polyoxyehtylene Undecyl Ether <3% CAS number: 34398-01-1 Composition comments Components listed, if any, are present above their levels of disclosure. Ingredient notes The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR 1910.1200. 4. First-aid measures Description of first aid measures General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel. Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention. Place unconscious person on their side in the recovery position and ensure breathing can take place. Ingestion Rinse mouth thoroughly with water. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Never give anything by mouth to an unconscious person. Place unconscious person on their side in the recovery position and ensure breathing can take place. Keep affected person under observation. Get medical attention if symptoms are severe or persist. Skin Contact Rinse with water. 2/9 Revision date: 4/26/2021 Revision: 2 Glass Polish Eye contact Rinse with water. Do not rub eye. Remove any contact lenses and open eyelids wide apart. Get medical attention if any discomfort continues. Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Irritation of nose, throat and airway. Difficulty in breathing. Coughing. Prolonged or repeated exposure may cause the following adverse effects: May cause cancer. Ingestion May cause irritation. Prolonged or repeated exposure may cause the following adverse effects: May cause cancer. Skin contact Redness. Irritating to skin. Prolonged or repeated exposure may cause the following adverse effects: May cause cancer. Eye contact Irritating to eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk. Do not touch or walk into spilled material. Avoid inhalation of vapors and spray/mists. Use suitable respiratory protection if ventilation is inadequate. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Methods and material for containment and cleaning up 3/9 Revision date: 4/26/2021 Revision: 2 Glass Polish Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Neutralize with acid. Caution. May generate heat. Dangerous for the environment. Do not empty into drains. For waste disposal, see Section 13. Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. May cause cancer. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Store away from the following materials: Acids. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Storage class Acid-reactive storage. Specific end uses(s) Specific end use(s) The identified uses for this product are detailed in Section 1. 8. Exposure controls/Personal protection Exposure controls Protective equipment Appropriate engineering controls Provide adequate ventilation. Eye/face protection Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resist degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended. Other skin and body protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Keep container tightly sealed when not in use. Avoid release to the environment. 4/9 Revision date: 4/26/2021 Revision: 2 Glass Polish 9. Physical and chemical properties Information on basic physical and chemical properties Appearance Creamy liquid. Color White. Odor Characteristic. pH pH (concentrated solution): 8 Melting point No information available. Initial boiling point and range No information available. Flash point No information available. Evaporation rate No information available. Evaporation factor No information available. Vapor pressure No information available. Vapor density No information available. Relative density ~ 0.98 Bulk density No information available. Solubility(ies) Soluble in water. Partition coefficient No information available. Decomposition Temperature No information available. Viscosity No information available. Explosive properties No information available. Other information No information required. 10. Stability and reactivity Reactivity There are no known reactivity hazards associated with this product. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions No potentially hazardous reactions known. Conditions to avoid There are no known conditions that are likely to result in a hazardous situation. Materials to avoid Acid anhydrides. Acids. Phenols, cresols. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. 11. Toxicological information Information on toxicological effects Acute toxicity - oral Summary Based on available data the classification criteria are not met. ATE oral (mg/kg) 12,500.0 Acute toxicity - dermal Summary Based on available data the classification criteria are not met. 5/9 Revision date: 4/26/2021 Revision: 2 Glass Polish Acute toxicity - inhalation Summary Based on available data the classification criteria are not met. ATE inhalation (dusts/mists mg/l) 6.0 Skin corrosion/irritation Summary Causes skin irritation. Extreme pH Moderate pH ( > 2 and < 11.5). Serious eye damage/irritation Summary Causes serious eye irritation. Respiratory sensitization Summary Based on available data the classification criteria are not met. Skin sensitization Summary Based on available data the classification criteria are not met. Germ cell mutagenicity Summary Based on available data the classification criteria are not met. Carcinogenicity Summary May cause cancer. IARC carcinogenicity None of the ingredients are listed or exempt. Reproductive toxicity Summary Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure Summary May cause respiratory irritation. Target organs Respiratory system, lungs Specific target organ toxicity - repeated exposure Summary Based on available data the classification criteria are not met. Aspiration hazard Summary Based on available data the classification criteria are not met. General information May cause cancer after repeated exposure. Risk of cancer depends on duration and level of exposure. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Irritation of nose, throat and airway. Difficulty in breathing. Coughing. Ingestion May cause irritation. Skin Contact Redness. Irritating to skin. Eye contact Irritating to eyes. Route of exposure Ingestion Inhalation Skin and/or eye contact Target Organs Respiratory system, lungs 12. Ecological information Chronic aquatic toxicity Summary Based on available data the classification criteria are not met. Persistence and degradability Persistence and degradability The degradability of the product is not known. 6/9 Revision date: 4/26/2021 Revision: 2 Glass Polish Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility The product is water-soluble and may spread in water systems. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. 14. Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, DOT). UN Number UN No. (International) Not applicable. UN No. (DOT) Not applicable. UN proper shipping name Proper shipping name (International) Not applicable. Proper shipping name (DOT) Not applicable. Transport hazard class(es) Transport Labels (International) No transport warning sign required. DOT transport labels No transport warning sign required. Packing group Packing group (International) Not applicable. DOT packing group Not applicable. Environmental hazards Environmentally Hazardous Substance No. Special precautions for user Not applicable. DOT reportable quantity Not applicable. DOT TIH Zone Not applicable. 7/9 Revision date: 4/26/2021 Revision: 2 Glass Polish Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. 15. Regulatory information Regulatory References OSHA Hazard Communication Standard 29 CFR ?1910.1200 US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) None of the ingredients are listed or exempt. SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting None of the ingredients are listed or exempt. CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories Carcinogenicity Serious eye damage or eye irritation Skin corrosion or irritation Specific target organ toxicity (single or repeated exposure) OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-I) None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. California Directors List of Hazardous Substances None of the ingredients are listed or exempt. Massachusetts "Right To Know" List None of the ingredients are listed or exempt. Rhode Island "Right To Know" List None of the ingredients are listed or exempt. Minnesota "Right To Know" List None of the ingredients are listed or exempt. 8/9 Revision date: 4/26/2021 Revision: 2 Glass Polish New Jersey "Right To Know" List None of the ingredients are listed or exempt. Pennsylvania "Right To Know" List None of the ingredients are listed or exempt. Inventories US - TSCA The following ingredients are listed or exempt: Water Polyoxyehtylene Undecyl Ether Distillates (petroleum), hydrotreated middle US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information Abbreviations and acronyms used in the safety data sheet TDG: The transport of dangerous goods act IATA: International air transport association. ICAO: Technical instructions for the safe transport of dangerous goods by air. IMDG: International maritime dangerous goods. CAS: Chemical abstracts service. ATE: Acute toxicity estimate. LC??: Lethal concentration to 50 % of a test population. LD??: Lethal dose to 50% of a test population (median lethal dose). EC??: 50% of maximal effective concentration. PBT: Persistent, bioaccumulative and toxic substance. vPvB: Very persistent and very bioaccumulative. Classification abbreviations and acronyms Carc. = Carcinogenicity Eye Irrit. = Eye irritation Skin Irrit. = Skin irritation STOT SE = Specific target organ toxicity-single exposure Aquatic Acute = Hazardous to the aquatic environment (acute) Training advice Read and follow manufacturer's recommendations. Revision date 4/26/2021 Revision 2 SDS No. 4799 Hazard statements in full H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. End of safety data sheet. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 9/9 SAFETY DATA SHEET - Glass Polish 1. Identification Product identifier Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Emergency telephone number 2. Hazard(s) identification Classification of the substance or mixture Label elements Other hazards 3. Composition/information on ingredients Mixtures 4. First-aid measures Description of first aid measures Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Extinguishing media Special hazards arising from the substance or mixture Advice for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Specific end uses(s) 8. Exposure controls/Personal protection Exposure controls 9. Physical and chemical properties Information on basic physical and chemical properties 10. Stability and reactivity 11. Toxicological information Information on toxicological effects 12. Ecological information Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Waste treatment methods 14. Transport information UN Number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user 15. Regulatory information 16. Other information