Revision date: 1/5/2023 Revision: 4 SAFETY DATA SHEET Gum N Tar According to Appendix D, OSHA Hazard Communication Standard 29 CFR ?1910.1200 1. Identification Product identifier Product name Gum N Tar Product number 806 Recommended use of the chemical and restrictions on use Application Car maintenance product. Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer 3D International LLC 20724 Centre Pointe Pkwy Unit 1 Santa Clarita, CA 91350 888-999-7627 Emergency telephone number Emergency telephone CHEMTREC 1-800-424-9300 (US and Canada) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Flam. Liq. 3 - H226 Health hazards Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Repr. 2 - H361d STOT RE 2 - H373 Asp. Tox. 1 - H304 Environmental hazards Not Classified Label elements Hazard symbols Signal word Danger Hazard statements H226 Flammable liquid and vapor. H332 Harmful if inhaled. H315 Causes skin irritation. H361d Suspected of damaging the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H304 May be fatal if swallowed and enters airways. 1/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames and hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/ bond container and receiving equipment. P241 Use explosion-proof electrical equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe vapor/ spray. P261 Avoid breathing vapor/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301+P310 If swallowed: Immediately call a poison center/ doctor. P302+P352 If on skin: Wash with plenty of water. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P308+P313 If exposed or concerned: Get medical advice/ attention. P312 Call a poison center/ doctor if you feel unwell. P314 Get medical advice/ attention if you feel unwell. P321 Specific treatment (see medical advice on this label). P331 Do NOT induce vomiting. P332+P313 If skin irritation occurs: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container in accordance with national regulations. Contains Distillates (petroleum), hydrotreated light, xylene, ethylbenzene, toluene Other hazards This product does not contain any substances classified as PBT or vPvB. 3. Composition/information on ingredients Mixtures Distillates (petroleum), hydrotreated light 60-100% CAS number: 64742-47-8 Classification Flam. Liq. 4 - H227 Asp. Tox. 1 - H304 xylene 10-30% CAS number: 1330-20-7 Classification Flam. Liq. 3 - H226 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 2/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar ethylbenzene 5-10% CAS number: 100-41-4 Classification Flam. Liq. 2 - H225 Acute Tox. 4 - H332 STOT RE 2 - H373 Asp. Tox. 1 - H304 toluene <1% CAS number: 108-88-3 Classification Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 Repr. 2 - H361d STOT SE 3 - H336 STOT RE 2 - H373 Asp. Tox. 1 - H304 The full text for all hazard statements is displayed in Section 16. Composition comments The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR 1910.1200. Ingredient notes The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR 1910.1200. 4. First-aid measures Description of first aid measures General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel. Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention. Place unconscious person on their side in the recovery position and ensure breathing can take place. Ingestion Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately. Skin Contact Rinse with water. Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical attention if any discomfort continues. Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Headache. Exhaustion and weakness. Ingestion May cause irritation. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Skin contact Redness. Irritating to skin. Eye contact May be slightly irritating to eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. 5. Fire-fighting measures 3/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar Extinguishing media Suitable extinguishing media The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Flammable liquid and vapour. Vapors may be ignited by a spark, a hot surface or an ember. Vapors may form explosive mixtures with air. Fire-water run-off in sewers may create fire or explosion hazard. This product is toxic. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Toxic gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk. Do not touch or walk into spilled material. Evacuate area. Provide adequate ventilation. No smoking, sparks, flames or other sources of ignition near spillage. Promptly remove any clothing that becomes contaminated. Avoid inhalation of vapors and spray/mists. Use suitable respiratory protection if ventilation is inadequate. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Methods and material for containment and cleaning up Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Eliminate all ignition sources if safe to do so. No smoking, sparks, flames or other sources of ignition near spillage. Do not allow material to enter confined spaces, due to the risk of explosion. Provide adequate ventilation. Absorb small quantities with paper towels and evaporate in a safe place. Once evaporation is complete, place paper in a suitable waste disposal container and seal securely. Large Spillages: If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Neutralize with acid. Caution. May generate heat. Following dilution and neutralization, discharge to the sewer with plenty of water may be permitted. The requirements of the local water authority must be complied with if contaminated water is flushed directly to the sewer. For waste disposal, see Section 13. Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling 4/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. The product is flammable. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Keep away from oxidizing materials, heat and flames. Store away from the following materials: Acids. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Storage class Flammable liquid storage. Specific end uses(s) Specific end use(s) The identified uses for this product are detailed in Section 1. 8. Exposure controls/Personal protection Control parameters Occupational exposure limits xylene Long-term exposure limit (8-hour TWA): OSHA 100 ppm 435 mg/m? Long-term exposure limit (8-hour TWA): ACGIH 100 ppm 434 mg/m? Short-term exposure limit (15-minute): ACGIH 150 ppm 651 mg/m? A4 ethylbenzene Long-term exposure limit (8-hour TWA): ACGIH 20 ppm A3 Long-term exposure limit (8-hour TWA): OSHA 100 ppm 435 mg/m? toluene Long-term exposure limit (8-hour TWA): ACGIH 20 ppm A4 Long-term exposure limit (8-hour TWA): OSHA 200 ppm Ceiling exposure limit: OSHA 300 ppm OSHA = Occupational Safety and Health Administration. ACGIH = American Conference of Governmental Industrial Hygienists. A3 = Confirmed Animal Carcinogen with Unknown Relevance to Humans. A4 = Not Classifiable as a Human Carcinogen. ethylbenzene (CAS: 100-41-4) Immediate danger to life and health 800 ppm toluene (CAS: 108-88-3) Immediate danger to life and health 500 ppm Exposure controls Protective equipment 5/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar Appropriate engineering controls Provide adequate ventilation. Eye/face protection Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resist degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended. Other skin and body protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Keep container tightly sealed when not in use. Avoid release to the environment. 9. Physical and chemical properties Information on basic physical and chemical properties Appearance Liquid. Color Clear. Odor Solvent. Odor threshold No information available. pH pH (concentrated solution): 9 Melting point No information available. Initial boiling point and range No information available. Flash point No information available. Evaporation rate No information available. Evaporation factor No information available. Flammability (solid, gas) No information available. Upper/lower flammability or explosive limits No information available. Other flammability No information available. Vapor pressure No information available. Vapor density No information available. Relative density ~ 0.85 Bulk density No information available. Solubility(ies) Insoluble in water. Partition coefficient No information available. Auto-ignition temperature No information available. Decomposition Temperature No information available. Viscosity No information available. Other information No information required. 6/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions The following materials may react strongly with the product: Oxidizing agents. Conditions to avoid Avoid heat, flames and other sources of ignition. Containers can burst violently or explode when heated, due to excessive pressure build-up. Static electricity and formation of sparks must be prevented. Materials to avoid Acid anhydrides. Acids. Phenols, cresols. Oxidizing materials. Acids - oxidizing. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Toxic gases or vapors. 11. Toxicological information Information on toxicological effects Acute toxicity - oral Summary Based on available data the classification criteria are not met. Acute toxicity - dermal Summary Based on available data the classification criteria are not met. ATE dermal (mg/kg) 3,978.3 Acute toxicity - inhalation Summary Harmful if inhaled. ATE inhalation (dusts/mists mg/l) 4.33 Skin corrosion/irritation Summary Causes skin irritation. Extreme pH Moderate pH ( > 2 and < 11.5). Serious eye damage/irritation Summary Based on available data the classification criteria are not met. Respiratory sensitization Summary Based on available data the classification criteria are not met. Skin sensitization Summary Based on available data the classification criteria are not met. Germ cell mutagenicity Summary Based on available data the classification criteria are not met. Carcinogenicity Summary Based on available data the classification criteria are not met. IARC carcinogenicity Contains a substance which may be potentially carcinogenic. IARC Group 2B Possibly carcinogenic to humans. Reproductive toxicity Summary Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure Summary Based on available data the classification criteria are not met. Target organs Respiratory system, lungs Specific target organ toxicity - repeated exposure 7/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar Summary Based on available data the classification criteria are not met. Aspiration hazard Summary May be fatal if swallowed and enters airways. Pneumonia may be the result if vomited material containing solvents reaches the lungs. General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Headache. Exhaustion and weakness. Ingestion May cause irritation. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Skin Contact Redness. Irritating to skin. Eye contact May be slightly irritating to eyes. Route of exposure Ingestion Inhalation Skin and/or eye contact Target Organs No specific target organs known. 12. Ecological information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment. Acute aquatic toxicity Summary Based on available data the classification criteria are not met. Chronic aquatic toxicity Summary Based on available data the classification criteria are not met. Persistence and degradability Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility The product is water-soluble and may spread in water systems. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. 14. Transport information General For limited quantity packaging/limited load information, consult the relevant modal documentation using the data shown in this section. 8/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar UN Number UN No. (TDG) 1307 UN No. (IMDG) 1307 UN No. (ICAO) 1307 UN No. (DOT) UN1307 UN proper shipping name Proper shipping name (TDG) XYLENES Proper shipping name (IMDG) XYLENES Proper shipping name (ICAO) XYLENES Proper shipping name (DOT) XYLENES Transport hazard class(es) DOT hazard class 3 DOT hazard label 3 TDG class 3 TDG label(s) 3 IMDG Class 3 ICAO class/division 3 Transport labels DOT transport labels Packing group TDG Packing Group II IMDG packing group II ICAO packing group II DOT packing group II Environmental hazards Environmentally Hazardous Substance No. Special precautions for user Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. EmS F-E, S-D 15. Regulatory information Regulatory References OSHA Hazard Communication Standard 29 CFR ?1910.1200 US Federal Regulations 9/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) The following ingredients are listed or exempt: xylene Final CERCLA RQ: 100(45.4) pounds (Kilograms) ethylbenzene Final CERCLA RQ: 1000(454) pounds (Kilograms) toluene Final CERCLA RQ: 1000(454) pounds (Kilograms) SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting The following ingredients are listed or exempt: xylene 1.0 % ethylbenzene 0.1 % toluene 1.0 % CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories Acute toxicity (any route of exposure) Aspiration hazard Flammable (gases, aerosols, liquids or solids) Reproductive toxicity Skin corrosion or irritation Specific target organ toxicity (single or repeated exposure) OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins The following ingredients are listed or exempt: ethylbenzene Carcinogen. toluene Developmental toxin. California Air Toxics "Hot Spots" (A-I) The following ingredients are listed or exempt: xylene ethylbenzene 10/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar toluene California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. California Directors List of Hazardous Substances The following ingredients are listed or exempt: xylene ethylbenzene toluene Massachusetts "Right To Know" List The following ingredients are listed or exempt: xylene ethylbenzene toluene Rhode Island "Right To Know" List The following ingredients are listed or exempt: xylene ethylbenzene toluene Minnesota "Right To Know" List The following ingredients are listed or exempt: xylene ethylbenzene toluene New Jersey "Right To Know" List The following ingredients are listed or exempt: xylene ethylbenzene toluene Pennsylvania "Right To Know" List The following ingredients are listed or exempt: xylene ethylbenzene toluene Inventories US - TSCA All the ingredients are listed or exempt. US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information 11/12 Revision date: 1/5/2023 Revision: 4 Gum N Tar Abbreviations and acronyms used in the safety data sheet TDG: The transport of dangerous goods act IATA: International air transport association. ICAO: Technical instructions for the safe transport of dangerous goods by air. IMDG: International maritime dangerous goods. CAS: Chemical abstracts service. ATE: Acute toxicity estimate. LC??: Lethal concentration to 50 % of a test population. LD??: Lethal dose to 50% of a test population (median lethal dose). EC??: 50% of maximal effective concentration. PBT: Persistent, bioaccumulative and toxic substance. vPvB: Very persistent and very bioaccumulative. Classification abbreviations and acronyms Flam. Liq. = Flammable liquid Acute Tox. = Acute toxicity Asp. Tox. = Aspiration hazard Skin Irrit. = Skin irritation Training advice Read and follow manufacturer's recommendations. Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision date 1/5/2023 Revision 4 SDS No. 4718 Hazard statements in full H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H373 May cause damage to organs (Hearing organs) through prolonged or repeated exposure. End of safety data sheet. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 12/12 SAFETY DATA SHEET - Gum N Tar 1. Identification Product identifier Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Emergency telephone number 2. Hazard(s) identification Classification of the substance or mixture Label elements Other hazards 3. Composition/information on ingredients Mixtures 4. First-aid measures Description of first aid measures Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Extinguishing media Special hazards arising from the substance or mixture Advice for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Specific end uses(s) 8. Exposure controls/Personal protection Control parameters Exposure controls 9. Physical and chemical properties Information on basic physical and chemical properties 10. Stability and reactivity 11. Toxicological information Information on toxicological effects 12. Ecological information Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Waste treatment methods 14. Transport information UN Number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user 15. Regulatory information 16. Other information