SAFETY DATA SHEET 1. Identification Product number 1048 Product identifier Blast Out Fresh & Clean Odor Bomb Revision date 07-03-2014 Company information Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-630-628-3000 Emergency telephone US 1-866-836-8855 Emergency telephone outside US 1-952-852-4646 Version # 02 Supersedes date 09-03-2013 Recommended use Air Freshener Recommended restrictions None known. 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Category 2ASerious eye damage/eye irritationHealth hazards Category 3 narcotic effectsSpecific target organ toxicity, single exposure Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness. Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Not classified.Hazard(s) not otherwise classified (HNOC) Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Supplemental information Hazard statement Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Prevention Avoid release to the environment. Response Collect spillage. 30% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 30% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 1 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US SP248 HD ODOR ELIMINATOR 3D INTERNATIONAL LLC 20724 CENTRE POINTE PARKWAY UNIT 1 SANTA CLARITA, CA 91350 United States 1-888-999-7627 3. Composition/information on ingredients Mixtures Hazardous components CAS number %Chemical name Common name and synonyms 67-64-1Acetone 60 - 80 106-97-8Butane 10 - 20 74-98-6Propane Other components below reportable levels 2.5 - 10 10 - 20 #: This substance has workplace exposure limit(s). *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Most important symptoms/effects, acute and delayed Irritation of eyes and mucous membranes. May cause drowsiness or dizziness. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Powder. Alcohol resistant foam. Water. Carbon dioxide (CO2). Unsuitable extinguishing media None known. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the MSDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Collect spillage. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the MSDS. Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 2 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Observe good industrial hygiene practices. Wash hands thoroughly after handling. Do not empty into drains. Conditions for safe storage, including any incompatibilities Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store away from incompatible materials (see Section 10 of the MSDS). Level 3 Aerosol. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 2400 mg/m3Acetone (CAS 67-64-1) 1000 ppm PEL 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 750 ppmAcetone (CAS 67-64-1) TWA 500 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 590 mg/m3Acetone (CAS 67-64-1) 250 ppm TWA 1900 mg/m3Butane (CAS 106-97-8) 800 ppm TWA 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 50 mg/l Acetone Urine *Acetone (CAS 67-64-1) * - For sampling details, please see the source document. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear eye/face protection. Wear safety glasses with side shields (or goggles). Hand protection Wear protective gloves. Other Wear appropriate chemical resistant clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Color Not available. Form Aerosol. Physical state Gas. 3 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US Flash point -156.00 ?F (-104.44 ?C) Propellant estimated Melting point/freezing point Not available. Odor Not available. pH Not available. Solubility(ies) Not available. Vapor density Not available. Vapor pressure 50.47 psig @70F estimated Viscosity Not available. Other information Specific gravity 0.147 estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Narcotic effects. Skin contact Not available. Eye contact Causes serious eye irritation. Symptoms related to the physical, chemical and toxicological characteristics Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity Narcotic effects. Test ResultsProduct Species Blast Out Fresh & Clean Odor Bomb (CAS Mixture) LD50 Rabbit Dermal Acute 28569.4688 mg/kg, estimated 28.5695 ml/kg, estimated LC50 Mouse Inhalation 5787.2568 mg/l, 2 Hours, estimated Rat 10889.4551 mg/l, 15 Minutes, estimated 5600.0225 mg/l, 4 Hours, estimated 2632.0105 mg/l/4h, estimated 71.5665 mg/l, 8 Hours, estimated LD50 Mouse Oral 4285.4204 mg/kg, estimated Rabbit 7628.0483 mg/kg, estimated Rat 8285.1465 mg/kg, estimated LD50 Mouse Other 1852.7301 mg/kg, estimated Rat 7856.604 mg/kg, estimated 4 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US Test ResultsComponents Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20000 mg/kg 20 ml/kg LC50 Rat Inhalation 76 mg/l, 4 Hours 50.1 mg/l, 8 Hours LD50 Mouse Oral 3000 mg/kg Rabbit 5340 mg/kg Rat 5800 mg/kg LD50 Mouse Other 1297 mg/kg Rat 5500 mg/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 680 mg/l, 2 Hours Rat 658 mg/l, 4 Hours Propane (CAS 74-98-6) LC50 Rat Inhalation Acute > 1442.847 mg/l, 15 Minutes 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Not applicable. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Narcotic effects. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Test ResultsSpecies Blast Out Fresh & Clean Odor Bomb (CAS Mixture) EC50Crustacea 7367.7803 mg/l, 48 hours, estimatedDaphnia LC50Fish 12050.4434 mg/l, 96 hours, estimatedFish Components Test ResultsSpecies Acetone (CAS 67-64-1) Aquatic EC50Crustacea 21.6 - 23.9 mg/l, 48 hoursWater flea (Daphnia magna) 5 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US Components Test ResultsSpecies * Estimates for product may be based on additional component data not shown. LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Propane 2.36 Butane 2.89 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. US RCRA Hazardous Waste U List: Reference Acetone (CAS 67-64-1) U002 Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number Aerosols, flammableUN proper shipping name 2.1Transport hazard class(es) Not available.Subsidiary class(es) Not available.Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 2.1Labels required N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950UN number Aerosols, flammableUN proper shipping name 2.1Transport hazard class(es) -Subsidiary class(es) Not available.Packaging group YesEnvironmental hazards 2.1Labels required 10LERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTYPackaging Exceptions IMDG UN1950UN number AEROSOLS, MARINE POLLUTANTUN proper shipping name 2.1Transport hazard class(es) 6 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US -Subsidiary class(es) Not available.Packaging group YesMarine pollutant Environmental hazards 2.1Labels required F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTYPackaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. DOT IATA; IMDG Marine pollutant 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No 7 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US SARA 311/312 Hazardous chemical No Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 % weight/volumn DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Food and Drug Administration (FDA) Not regulated. US state regulations US. New Jersey Worker and Community Right-to-Know Act Butane (CAS 106-97-8) 500 lbs Propane (CAS 74-98-6) 500 lbs US. Pennsylvania RTK - Hazardous Substances Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 09-03-2013 Revision date 07-03-2014 Version # 02 Further information Not available. Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 8 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US Revision Information Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Regulatory Information: United States GHS: Classification 9 / 9 Product name: Blast Out Fresh & Clean Odor Bomb Product #: 248, 1048_248 Version #: 02 Revision date: 07-03-2014 Issue date: 09-03-2013 SDS US